Effect of sodium carboxymethyl cellulose (Na-CMC) added to urea-formaldehyde resin on particleboard properties
Effect of sodium carboxymethyl cellulose (Na-CMC) added to urea-formaldehyde resin on particleboard properties
This study investigated the effect of sodium carboxymethyl cellulose (Na-CMC) added to urea-formaldehyde (UF) resin on particleboard production and its effects on the properties of the boards. The Na-CMC/UF was prepared at the selected blending levels of 0/100, 5/95, 10/90, 15/85, 20/80, 25/75, 30/70, 35/65, 40/60, 45/55, and 50/50. In the production of test panels, 55% coniferous and 45% broadleaved wood chips were used. The physical and mechanical properties of the particleboard panels were determined and evaluated. According to the results, the addition of Na-CMC at the level of between 5% and 20% improved the internal bond (IB) strength by 6%– 40%. The best IB strength (0.63 N/mm2) was found in the panels with the 20% Na-CMC admixture. Although an increase in bending strength (modulus of rupture-MOR) was observed with an increase in the amount of Na-CMC used, it was found that the bending modulus of elasticity (MOE) was reduced in comparison with the control sample. The lowest MOE was determined as 1451 N/mm2 in the 50% Na-CMC-doped test panels. It was determined that the use of Na-CMC negatively affected the water absorption and thickness swelling values. As a result, it was concluded that UF resin containing up to 20% Na-CMC solution can be used in particleboards produced for applications in which the physical properties are not important.
___
- Basta AH, El-Saied H, Gobran RH (2004). Formaldehyde-free environmentally friendly composites based on agricultural waste. I. Novel adhesive system. Polymer-Plastics Technology and Engineering 43(3): 745-777. doi: 10.1081/PPT-120038063
- Cao Y, Li H, Xu X (2001). Influence of block structure on conformation and properties of carboxymethyl cellulose series of polymeric surfactants. Acta Polymerica Sinica, 1(1): 3-7.
- Colombo P, Bettini R, Santi P, Peppas NA (2000). Swellable matrices for controlled drug delivery: Gel-layer behaviour, mechanisms and optimal performance. Pharmaceutical Science & Technology Today 3(6): 198-204. doi: 10.1016/S1461- 5347(00)00269-8
- Eroğlu H, Usta M (2000). Lif Levha Üretim Teknolojisi. Trabzon: Karadeniz Teknik Üniversitesi, Orman Fakültesi, Genel Yayın No: 200, Fakülte Yayın No: 30 (in Turkish).
- Hematabadi H, Behrooz R, Shakibi A, Arabi M (2012). The reduction of indoor air formaldehyde from wood based composites using urea treatment for building materials. Construction and Building Materials 28: 743-746. doi: 10.1016/j. conbuildmat.2011.09.018
- Istek A, Siradag H (2013). The effect of density on particleboard properties. In: International Caucasian Forestry Symposium, 24-26 October 2013; Artvin, Turkey. pp. 932-938.
- İstek A, Özlüsoylu İ, Onat SM, Özlüsoylu Ş (2018). Formaldehyde emission problems and solution recommendations on woodbased boards: A review. Journal of Bartın Faculty of Forestry 20(2): 382-387.
- Kevin EI, Ochanya OM, Olukemi AM, Bwanhot STN, Uche I (2018). Mechanical Properties of Urea Formaldehyde Particleboard Composite. American Journal of Chemical and Biochemical Engineering 2 (1): 10-15. doi: 10.11648/j.ajcbe.20180201.12
- Kono H (2014). Characterization and properties of carboxymethyl cellulose hydrogels crosslinked by polyethylene glycol. Carbohydrate Polymers 106: 84-93. doi: 10.1016/j. carbpol.2014.02.020
- Mamza PA, Ezeh EC, Gimba EC, Arthur DE (2014). Comparative study of phenol formaldehyde and urea formaldehyde particleboards from wood waste for sustainable environment. International Journal of Scientific & Technology Research 3(9): 53-61.
- Özlüsoylu İ, İstek A (2018). Sodyum karboksimetil selüloz (Na-CMC) takviyeli üre formaldehit tutkalının yonga levha özellikleri ve formaldehit emisyonuna etkisi. Turkish Journal of Forestry 19(3): 317-322 (in Turkish). doi: 10.18182/tjf.402355
- Park BD, Causin V (2013). Crystallinity and domain size of cured urea–formaldehyde resin adhesives with different formaldehyde/urea mole ratios. European Polymer Journal 49 (2): 532-537. doi: 10.1016/j.eurpolymj.2012.10.029
- Qiao Z, Gu J, Zuo Y, Tan H, Zhang Y (2014). The effect of carboxymethyl cellulose addition on the properties of starchbased wood adhesive. BioResources 9(4): 6117-6129.
- Rocket FH (1997). Encyclopaedia of Science and Technology. 8th ed. Volume 4. Boston, USA: McGraw-Hill Inc., pp. 257.
- TS EN 310 (1999). Wood- Based panels-Determination of modulus of elasticity in bending and of bending strength. Ankara, Turkey.
- TS EN 312 (2012). Particleboards-Specification. Ankara, Turkey.
- TS EN 317 (1999). Particleboards and fibreboards- Determination of swelling in thickness after immersion in water. Ankara, Turkey.
- TS EN 319 (1999). Particleboards and fibreboards- Determination of tensile strength perpendicular to the plane of the board. Ankara, Turkey.
- TS EN 323 (1999). Wood- Based panels-Determination of density. Ankara, Turkey.
- TS EN 325 (2012). Wood-based panels-Determination of dimensions of test pieces. Ankara, Turkey.
- TS EN 326-1 (1999). Wood- Based panels- Sampling, cutting and inspection- Part 1: Sampling test pieces and expression of test results. Ankara, Turkey.
- TS 4894 EN 120 (1999). Wood based panels- Determination of formaldehyde content- Extraction method called the perforator method. Ankara, Turkey.
- Ugwoke MI, Kaufmann G, Verbeke N, Kinget R (2000). Intranasal bioavailability of apomorphine from carboxymethylcellulosebased drug delivery systems. International Journal of Pharmaceutics 202(1-2): 125-131. doi: 10.1016/S0378- 5173(00)00434-8
- Zhang J, Li JZ, Zhang SF (2011). Properties of particleboard manufactured with modified urea-formaldehyde resin. Advanced Materials Research 150-151: 1135-1138. doi: 10.4028/www.scientific.net/AMR.150-151.1135
- Zhu X, Xu E, Lin R, Wang X, Gao Z (2014). Decreasing the formaldehyde emission in urea-formaldehyde using modified starch by strongly acid process. Journal of Applied Polymer Science 13.