Cocklebur (Xanthium strumarium L.) seed oil and its properties as an alternative biodiesel source

Öz   Cocklebur (Xanthium strumarium L.) seed oil is available for biodiesel production as a wild plant species. In the present study, the cocklebur seeds collected from Muslubelen, Yozgat, Turkey, at 1440 m in 2014 were sown in the Bozok University Agriculture Faculty Topçu Research Area during 2015 and 2016. The maximum crude oil ratio was obtained as 35%. Oleic and linoleic acid contents of cocklebur seed oil were determined as 11.37% and 76.97%, respectively. Some important fuel properties such as density, flash point, water content, copper strip corrosion, iodine value, linolenic acid, methyl ester, and sulfated ash content values were measured and compared to the EN 14214 and ASTM D6751 standards. These values were found to be within the standard ranges. Cost analysis of the cocklebur plant was also performed and compared to other field crops. According to our results, it seems that agronomic production of cocklebur will be possible in marginal areas because its genetic properties enable cocklebur to grow in dry areas. Therefore, production of cocklebur as an industrial plant may contribute to energy shortages without competing with food production. In areas devoid of sufficient irrigation possibilities, agriculture based on grain and cereal decreases the biodiversity. Production of drought-tolerant plants such as cocklebur in these areas will have positive effects on conservation and development of biodiversity in the ecosystem.

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Anand K, Sharma RP, Mehta PSA (2011). Comprehensive approach for estimating thermo-physical properties of biodiesel fuels. Appl Ther Eng 31: 235-242.

Atabani AE, Badruddin IA, Masjuki HH, Chong WT, Lee KT (2015). Pangium edule Reinw: a promising non-edible oil feedstock for biodiesel production. Arab J Sci Technol 40: 583-594.

Auld BA, McRae CF, Say MM (1988). Possible control of Xanthium spinosum by a fungus. Agric Ecosyst Environ 21: 219-223.

Azam MM, Waris A, Nahar NM (2005). Prospects and potential of fatty acid methyl esters of some non-traditional seed oils for use as biodiesel in India. Biomass Bioenergy 29: 293-302.

Balabanlı C, Albayrak S, Türk M, Yüksel O (2006). Türkiye çayır meralarında bulunan bazı zararlı bitkiler ve hayvanlar üzerindeki etkileri. SDÜ Orman Fakültesi Dergisi 2: 89-96 (in Turkish).

Bastante JS, Garcia PF, Saavedra M, Bellido LL, Dorado MP, Pinzi S (2016). Evaluation of Sinapis alba as feedstock for biodiesel production in Mediterranean climate. Fuel 184: 656-664.

Baydar H, Erbaş S. (2014). Yağ Bitkileri Bilimi ve Teknolojisi. Yayın No 97. Isparta, Turkey: Süleyman Demirel Üniversitesi Yayınları (in Turkish).

Byrd JD Jr, Coble HD (1991). Interference of common cocklebur ( Xanthium strumarium ) and cotton ( Gossypium hirsutum ). Weed Technol 5: 270-278.

Caius JF (1986). Medicinal and Poisonous Plants of India. Jodhpur, India: Scientific Publishers. Chang F, Hanna MA, Zhang DJ, Li H, Zhou Q, Song BA, Yang S (2013). Production of biodiesel from non-edible herbaceous vegetable oil: Xanthium sibiricum Patr. Bioresour Technol 140: 435-438.

Chang F, Zhou Q, and Zhou L (2017). Novel supramolecular alkaline ionic liquids–catalyzed heterogeneous transesterification of Xanthium sibiricum Patr oil to biodiesel. Energ Source Part A 39: 1377-1382.

Chen WH, Liu WJ, Wang Y, Song XP, Chen GY (2015). A new naphthoquinone and other antibacterial constituents from the roots of Xanthium sibiricum . Nat Prod Res 29: 739-744.

Eryilmaz T, Yesilyurt MK (2016). Influence of blending ratio on the physicochemical properties of safflower oil methyl ester- safflower oil, safflower oil methyl ester-diesel and safflower oil- diesel. Renew Energ 95: 233-247.

Eryilmaz T, Yesilyurt MK, Cesur C, Gokdogan O (2016). Biodiesel production potential from oil seeds in Turkey. Renew Sust Energ Rev 58: 842-851.

Gokdogan O, Eryilmaz T, Yesilyurt MK (2015). Thermophysical properties of castor oil ( Ricinus communis L.) biodiesel and its blends. CTF - Cienc Tecn Fut 6: 95-128.

Hasheminejad M, Tabatabaei M, Mansourpanah Y, Khatami Far M, Javani A (2011). Upstream and downstream strategies to economize biodiesel production. Bioresour Technol 102: 461- 468.

Hsu FL, Chen YC, Cheng JT (2000). Caffeic acid as active principle from the fruit of Xanthium strumarium to lower plasma glucose in diabetic rats. Planta Med 66: 228-230.

Kim YS, Kim JS, Park SH, Choi SU, Lee CO, Kim SK, Kim YK, Kim SH, Ryu SY (2003). Two cytotoxic sesquiterpene lactones from the leaves of Xanthium strumarium and their in vitro inhibitory activity on farnesyltransferase. Planta Med 69: 375-377.

Koh MY, Ghazi TIM (2015). A review of biodiesel production from Jatropha curcas L. oil. Renew Sust Energy Rev 15: 2240-2251.

Lee JM, Owen MDK (2003). Dry matter yield differences of five common cocklebur ( Xanthium strumarium ) biotypes grown at a common site. Weed Sci 2: 186-190.

Lovato L, Pelegrini BL, Rodrigues J, José A, Oliveira B, Cristina I, Ferreira P (2014). Seed oil of Sapindus saponaria L. (Sapindaceae) as potential C16 to C22 fatty acids resource. Biomass Bioenergy 60: 247-251.

Pinho RS, Oliveira AFM, Silva SI (2009). Potential oilseed crops from the semiarid region of northeastern Brazil. Bioresour Technol 100: 6114-6117.

Rozina, Asif S, Ahmad M, Zafar M, Ali N (2017). Prospects and potential of fatty acid methyl esters of some non-edible seed oils for use as biodiesel in Pakistan. Renew Sust Energy Rev 74: 687-702.

Scholz V, Silva JN (2008). Prospect and risks of the use of castor oil as a fuel. Biomass Bioenergy 32: 95-100.

Serim AT, Asav U, Türkseven S (2015). Ankara ili aspir ( Carthamus tinctorius L.) ekiliş alanlarında bulunan yabancı otların tespiti. Türkiye Herboloji Dergisi 18: 19-23 (in Turkish).

Ulug E, Kadıoglu İ, Uremis İ (1993). Türkiye’nin Yabancı Otları ve Bazı Özellikleri. Yayın No 78. Adana, Turkey: T.C. Tarım ve Köy İşleri Bakanlığı, Zirai Mücadele Araştırma Enstitüsü Müdürlüğü Yayınları (in Turkish).

Wassom JJ, Knepp AW, Tranel PJ, Wax LM (2003). Variability in photosynthetic rates and accumulated biomass among greenhouse-grown common cocklebur ( Xanthium strumarium ) accessions. Weed Technol 17: 84-88.

Wen D, Jiang H, Zhang K (2009). Supercritical fluid technology for clean biofuel production. Prog Nat Sci 19: 273-84.

Turkish Journal of Agriculture and Forestry-Cover
  • ISSN: 1300-011X
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK