Nigar MERDAN, Dilek KUT, Habip DAYIOĞLU, Mehmet KILINÇ, Seyda EYÜPOĞLU

THE EFFECT OF PLASMA TREATMENT ON THE DYEABILITY OF SILK FABRIC BY USING PHYTOLACCA DECANDRA L. NATURAL DYE EXTRACT

Bu çalışmanın amacı ipek kumaşa plazma uygulamasının, ipek kumaşın doğal boya ile boyanabilirlik özelliklerine etkisinin incelenmesidir. Bu amaçla, bu çalışmada, ipek kumaş Phytolacca Decandra bitkisinden elde edilen doğal boya ile konvansiyonel yönteme göre boyanmıştır. Boyama işleminden önce, ipek kumaşın serisini giderilmiş ve ardından numuneler oksijen ve azot gazı ile düşük frekansta 1, 5 ve 10 dakika plazma işlemine tabi tutulmuştur. Plazma işlemine maruz kalan numuneler potasyum alüminyum sülfat ile mordanlanmıştır. Boyama işleminden sonra, renk kuvveti, renk haslıkları ve yüzey özellikleri incelenmiştir. Sonuçlara göre plazma uygulaması ve mordanlama işlemi renk verimini artırmıştır. Taramalı elektron mikroskobu görüntüleri plazma uygulamasının ipek liflerinin yüzeyinde mikro boyutta çatlakların oluşmasına neden olduğunu göstermektedir. Plazma uygulamasından sonra, numunelerin hidrofilitesinin artığını görülmektedir. Ayrıca plazma uygulaması ipek liflerinin yüzeyinde mikro çatlakların oluşturmuş ve numunelerin mukavemetleri azalmıştır

İPEKLİ KUMAŞIN PHYTOLACCA DECANDRA L. BİTKİSİNDEN ELDE EDİLEN DOĞAL BOYA İLE BOYANABİLİRLİĞİNE PLAZMA UYGULAMASININ ETKİSİ

The aim of this study is that plasma treatment effect on dyeability properties of silk fabric with natural dye is investigated. For this purpose, in this study, silk fabric was dyed by the conventional method with natural dye extracted from Phytolacca Decandra L. Before the dyeing process, the sericin on silk fabric was removed. After then, plasma treatment was applied the samples with using oxygen and nitrogen gas for 1, 5 and 10 minutes at low frequency. Furthermore, plasma treated samples were mordanted with potassium aluminum sulfate before the dyeing process. After the dyeing process, colour strength, colour fastness, surface properties, moisture absorption, chemical groups and tensile strength of the dyed samples were investigated. According to the results, the plasma treatment and mordanting process caused to improve the colour yields. The scanning electron microscope images showed that the plasma treatment causes microcracks on the surface of the silk fiber. After the plasma treatment, the hydrophility of samples increased. Moreover, plasma treatment creates microcracks on the silk fiber surface, resulting tensile strength decreases

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1. Dogan, Y., Başlar, S., Mert, H. H., Güngör, A., 2003,“ Plants used as natural dye sources in Turkey”, Economic Botany, 57(4), 442-453.
2. Ibrahim, N. A., El-Gamal, A. R., Gouda, M., & Mahrous, F., 2010, “A new approach for natural dyeing and functional finishing of cotton cellulose”, Carbohydrate Polymers, 82(4), 1205-1211.
3. Singh, R., Jain, A., Panwar, S., Gupta, D., Khare, S.K., 2005, “Antimicrobial activity of some natural dyes”, Dyes and Pigments, 66 (2), 99-102.
4. Cristea, D., Vilarem, G., 2006, “Improving light fastness of natural dyes on cotton yarn”, Dyes and Pigments, 70 (3), 238-245.
5. Shahid, M., Mohammad, F., 2013,”Recent advancements in natural dye applications: a review”, Journal of Cleaner Production, 53, 310-331.
6. Tendero, C., 2006, “Atmospheric pressure plasmas: A Review”, Spectrochimica Acta Part B, 61, 2-30.
7. Vassallo, E., Cremona, A., Ghezzi, F., Ricci, D., 2010, “Characterization by optical emission spectroscopy of an oxgyen plasma used for improving PET wettability”, 2010, 84 (7), 902-906.
8. Mirabedini, S.M., Arabi, H., Salem, A., Asiaban, S., 2007, “Effect of low-pressure O2 and Ar plasma treatments on the wettability and morphology of biaxial-oriental polypropylene (BOPP) film”, 60 (2), 105-111.
9. Ferrero, F., 2003, “Wettability measurements on plasma treated synthetic fabrics by capillary rise method”, Polymer Testing, 22 (5), 571-578.
10. Sanchis, M.R., Blanes, V., Blanes, M., Garcia, D., Balart, R.,2006, “Surface modification of low density polyethylene (LDPE) film by low pressure O2 plasma treatment”, 42 (7), 1558-1568.
11. Teshima, K., Sugimura, H., Inoue, Y., Takai, O., Takano, A., 2005, “Transparent ultra water-repellent poly(ethylene terephthalate) substrates fabricated by oxygen plasma treatment and subsequent hydrophobic coating”, Applied Surface Science, 244 (1-4), 619-622.
12. Tsafact, M.J., Hochart, F., Grutzmacher, J.L., 2004, “Polymerization and surface modification by low pressure plasma technique”, 26 (3), 14th International Colloquium on Plasma Processes (CIP 2003).
13. Hochart, F., Jaeger, R.D., Grutzmacher, J.L., 2003, “Graft-polymerization of a hydrophobic monomer onto PAN textile by low-pressure plasma treatments”, 165 (2), 201-210.
14. Sun, D., Stylios, G.K., 2004, “Effect of low temperature plasma treatment on the scouring and dyeing of natural fabrics”, Textile Research Journal, 74 (9), 751-756.
15. Iriyama, Y., Mochizuki, T., Watanabe, M., Utada, M., 2002, “Plasma treatment of silk fabrics for better dyeability”, Journal of Photopolymer Science and Technology, 15 (2), 299-306.
16. Shishoo, R., 2007, “Introduction. Plasma technologies for textiles”, Shishoo, R. Abington: Woodhead Publishing Limited.
17. Flor, C., 2010, “Surface modifications of PET fabrics with low pressure plasma”, Thesis of Master of Science, Cornell University.
18. Kan, C. W., Lam, Y. L., 2015, “The effect of plasma treatment on water absorption properties of silk fabrics”, Fibers and Polymers, 16(8),1705-1714.
19. Hodak, S. K., Supasai, T., Paosawatyanyong, B., Kamlangkla, K.,Pavarajarn, V., 2008, “Enhancement of the hydrophobicity of silk fabrics by SF 6 plasma”, Applied Surface Science, 254(15), pp. 4744-4749.
20. Long, J. J., Wang, H. W., Lu, T. Q., Tang, R. C., Zhu, Y. W., 2008, “ Application of low-pressure plasma pretreatment in silk fabric degumming process”, Plasma Chemistry and Plasma Processing, 28(6),701-713.
21. Schliemann, W., Joy, R. W., Komamine, A., Metzger, J. W., Nimtz, M., Wray, V., Strack, D, 1996, “Betacyanins from plants and cell cultures of Phytolacca americana”, Phytochemistry, 42(4),1039-1046.
22. ISO 105-C06 Standard. Textiles-Tests for Colour Fastness- Part C06: Colour Fastness to Domestic and Commercial Laundering, (2010).
23. EN ISO 105 – B02 Standard. Textiles-Tests for Colour Fastness- Part B02: Colour Fastness to Artificial Light: Xenon Acr Fading Lamp Test, (1994).
24. ISO 105 X12 Standard. Textiles-Tests for Colour Fastness- Part X12: Colour Fastness to Rubbing, (2001).
25. AATCC 195-2012; Liquid Moisture Management Properties of Textile Fabrics.
26. http://lasurface.com/database/elementxps.php, Access Time: 29.04.2016
27. http://xpssimplified.com/periodictable.php, Access Time: 29.04.2016
28. Standard Test Method for Breaking Strength and Elongation of Textile Fabrics.
29. Brady, J.E., Holum, J.R., 1996, Chemistry, John Wiley&Sons,Inc.