Heavy metal contents of bootee leathers tanned wıth different process recipes

Bebek patiği üretiminde kullanılan derilerdeki selenyum, civa, kurşun, krom, kadmiyum, baryum, arsenik ve antimon gibi ağır metal içeriklerinin belirlenerek elde edilen sonuçların deri ve tekstillere ait limit değerler ile karşılaştırılması bu çalışmanın amacını oluşturmaktadır. Mamul derilerdeki ağır metal içeriğinin çoğunlukla işlentide kullanılmış olan kimyasallara bağlı olduğu sonucuna varılmıştır. Özellikle, krom içeriğinin oldukça yüksek olduğu tespit edilmiştir. Diğer taraftan, boyama ve finisaj işlemleri sırasında meydana gelen kimyasal ve fiziksel reaksiyonlar sonucu ortaya çıkan selenyum, civa, kurşun, kadmiyum, baryum, arsenik ve antimon içeriğinin ise daha düşük miktarlarda olduğu belirlenmiştir.

Farklı işlenti reçeteleri ile tabaklanmış bebek patiği derilerinin ağır metal içerikleri

The purpose of this work was to determine the content of heavy metals such as antimony, arsenic, barium, cadmium, chromium, lead, mercury, selenium in leather used by producing baby bootees and to compare the limit values for leather and textiles. It was concluded that heavy metal content of finished leathers depended mainly on the chemicals used in processing; in particular, high chromium contents were determined. Moreover, small amounts of antimony, arsenic, barium, cadmium, lead, mercury and selenium deriving from chemical and physical reactions during dyeing and finishing processes were detected.

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  • 1. Basaran, B., Iscan, M., Bitlisli, B.O., et al., 2006, “Heavy Metal Contents of Various Finished Leathers”, Journal of the Society of Leather Technologists and Chemists, Vol. 90(6), pp: 229-234.
  • 2. BS EN 71-3, 1995, “Safety of Toys. Specification for Migration of Certain Elements”, British Standard Institution, pp:1-24.
  • 3. Lenntech Holding BV, 2009, “Heavy Metals”, in: Lenntech Holding BV homepage. Available via http://www.lenntech.com/heavy-metals.htm. Accessed 04 Aug 2009.
  • 4. European Commission, 2009, “Environment”, in: European Commission homepage. Available via http://ec.europa.eu/environment/ecolabel/pdf/furniture/ draftcriteria_101203.pdf. Accessed 04 Aug 2009.
  • 5. Anonymous, 1996, “IUC 3-Preparation of Sample by Grinding”, Official Methods of Analysis, The Society of Leather Technologists and Chemists, Northampton, England, pp: 89-92.
  • 6. Wikipedia, 2009, “Heavy Metals”, in: Wikipedia homepage. Available via http://en.wikipedia.org/wiki/Heavy_metals. Accessed 04 Aug 2009.
  • 7. Sari, O., 2008, Tanning Materials Lecture Notes. Ege University Engineering Faculty Leather Engineering Department, Izmir, Turkey.
  • 8. Ozdogan, E., 1997, Determination of Heavy Metal Ions Caused by Regional Cotton and Dyestuffs during Fabric Production Process. MSc. Thesis. Ege University Institution of Natural and Applied Science, Izmir, Turkey.
  • 9. TFL, 2009, “The TFL White Line System in Harmony with the Skin”, in: TFL homepage. Available via http:tfl.com/pdfs/others/whiteline.pdf. Accessed 04 Aug 2009.
  • 10. Egemen, O., Sunlu, U., 1999, Water Quality. Ege University Press, Izmir, Turkey.
  • 11. John, G., 1996, “Finishing”, Possible Defects in Leather Production. Druck Partner Rübelmann GmbH, Hemsback, Germany, pp: 158-209.
  • 12. Sari, O., 2009, Leather Dyestuffs and Dyeing Techniques Lecture Notes. Ege University Engineering Faculty Leather Engineering Department, Izmir, Turkey.
  • 13. Bradberry, S.M., Harrison, W.N., Beer, S.T., et al., 2009, “Antimony (III) Trichloride”, in: IPCS INTOX Databank Homepage. Available via http://www.intox.org/ databank/ documents/chemical/anttrich/ukpid35.htm. Accessed 01 Marc 2009.
  • 14. Chemicalland21, 2009, “Antimony Pentoxide”, in: Chemicalland21 Homepage. Available via http://chemicalland21.com/industrialchem/inorganic/ ANTIMONY%20PENTOXIDE.htm. Accessed 01 Marc 2009.
  • 15. Healthy Toys, 2009, “SG-the Label for Low-Pollutant Leather Products”, in: HealtyToys Homepage. Available via http://www.healthytoys.org/ documents/SG_E2001.pdf. Accessed 01 Marc 2009.
  • 16. Aloy, M., 2009, “Introduction of Cleaner Leather Production Methods-Prospects and Constraints”, in: BVSDE Homepage. Available via http://www.bvsde.ops-oms.org/cdrom-repi86/fulltexts/eswww/fulltext/repind60/aloy/aloy.htm. Accessed 01 Marc 2009.
  • 17. Hemond, H.F., 1995, “Movement and Distribution of Arsenic in the Aberjona Watershed”, Env. Health Pers., 103, pp: 35-40.
  • 18. Pei Long, 2009, “Various Barium Compounds”, in: Pei Long Homepage. Available via http://www.pei-lin.com/product2-i.htm. Accessed 01 Marc 2009.
  • 19. Cory, N.J., 2002, “An Update on Environmental Constraints”, Journal of the American Leather Chemists Association, 97, pp: 496–505.
  • 20. EPA, 2009, “Integrated Pollution Prevention and Control (IPPC) Reference Document on Best Available Techniques for the Tanning of Hides and Skins”, in: Environmental Protection Agency Homepage. Available via http://www.epa.ie/downloads/advice/brefs/tanning.pdf. Accessed 01 Marc 2009.
  • 21. BLC, 2009, “Update”, in: BLC Leather Technology Centre Homepage. Available via http://www.blcleathertech.com/Uploads/PDFs/Updatejuly.pdf. Accessed 01 Marc 2009.
  • 22. Graf, D., 2001, “Formation of Cr (VI) Traces in Chrome Tanned Leather: Causes, Prevention and Latest Findings”, Journal of the American Leather Chemists Association, 96, pp: 169-179.
  • 23. Heidemann, E., 1993, Fundamentals of Leather Manufacture. Roetherdruck, Darmstadt, Germany.
  • 24. Gustavson, K.H., 1956, “The Chemistry of Chromium Salts and Chrome Tanning”, The Chemistry of Tanning Processes, Academic Press Inc., New York, USA, pp: 5-55.
  • 25. Thorstensen, T.C., 1993, Practical Leather Technology. Krieger Publishing Company, Malabar, Florida,USA.
  • 26. BASF, 1996, “Finishing”, Pocket Book for the Leather Technologist, BASF Aktiengesellschaft 67056, Ludwigshafen, Germany, pp: 173-208.
  • 27. Harmancıoglu, M., Dikmelik, Y., 1993, “Inorganic Substances of Hide and Skin”, Raw Skin, Özen Press, Izmir, Turkey, pp: 207-210.
  • 28. Sharphause, J.H., 1989, “Pigment Finishing”, Leather Technician’s Handbook, Leather Producers Association, Northampton, UK, pp: 388-395.
  • 29. Leather Research Laboratory, 2009, “Lead (Pb) Content”, in: Leather Research Laboratory Homepage. Available via http://www.leatherusa.org/i 4a/pages/index.cfm?pageid=3279. Accessed 01 Marc 2009.
  • 30. IFC, 2009, “Environmental, health, and Safety Guidelines Tanning and Leather Finishing”, in: International Finance Corporation Homepage. Available via http://www.ifc.org/ifcext/sustainability.nsf/AttachmentsByTitle/gui_EHSGuidelines2007_TanningandLeather/$FILE/Final+-+Tanning+and+Leather+Finishing.pdf. Accessed 01 Marc 2009.
Tekstil ve Konfeksiyon-Cover
  • ISSN: 1300-3356
  • Yayın Aralığı: Yılda 4 Sayı
  • Yayıncı: Ege Üniversitesi Tekstil ve Konfeksiyon Araştırma & Uygulama Merkezi