[M(1(2H)-phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Bileşiklerinin Kırmızıaltı ve Mikroraman Spektroskopisi ile İncelenmeleri

Bu çalışmada, 1(2H)-fitalazinon Co(II), Cu(II) ve Mn(II) metal halid bileşikleri, elemental analiz, FT-IR ve mikro-Raman spektroskopileri ile karakterize edilmiştir. M(1(2H)-fitalazinon)n.Cl2 (M = Co, Cu ve Mn; n = 1, 2) bileşikleri ilk kez hazırlanmıştır ve titreşim dalgasayıları sunulmuştur. Deneysel olarak elde edilen sonuçlar, 1(2H)-fitalazinon ile metal iyonları arasındaki koordinasyonun, Co(II) > Mn(II) > Cu(II) olarak azalan metal-oksijen gerilme frekanslarını verdiğini göstermektedir. Anahtar kelimeler: 1(2H)-fitalazinon, IR ve Raman spektroskopileri, Elementel analiz, Metal halid bileşikleri.

Anahtar Kelimeler:

1(2H)-fitalazinon, IR ve Raman spektroskopileri, Elementel analiz, Metal halidbileşikleri

Infrared and Micro-Raman Spectroscopic Studies of [M(1(2H)- phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Complexes

In this study, the Co(II), Cu(II) and Mn(II) metal halide complexes of 1(2H)-phthalazinone were characterized by elemental analysis, FT-IR and micro-Raman spectroscopies. The M(1(2H)-phthalazinone)n.Cl2 (M = Co, Cu and Mn; n = 1, 2) complexes have been prepared for the first time and their vibrational wavenumbers were reported. The results obtained experimentally indicate that the coordination between 1(2H)-phthalazinone and different metal ions gives different metal-oxygen stretching frequencies which decrease in the following order Co(II) > Mn(II) > Cu(II).

Keywords:

1(2H)-phthalazinone, IR and Raman spectroscopies, Elemental analysis, Metal halide complexes,

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Nuri Öztürk e-mail: nuriozturk@sdu.edu.tr