Tetrahidrofuran ve Dimetil Sülfoksitin Vanadyum Redoks Akışkan Bataryadaki Pozitif Elektrolit Üzerine Olan Etkilerinin Araştırılması
Bu çalışmada, tetrahidrofuran ve dimetil sülfoksitin vanadyum redoks bataryanın pozitif elektrolitinin elektrokimyasal davranışına olan etkilerinin karşılaştırılmalı bir çalışması yapılmıştır. Bu kapsamda, katkı maddesi, V(IV) ve sülfürik asit içeren elektrolit çözeltilerinin karakterizasyonu için dönüşümlü voltametri ve elektrokimyasal empedands spektroskopisi kullanılmıştır. Piklerin akım ve kapasiteleri voltamogramlardan elde edilmiştir. Redoks reaksiyonu tetrahidrofuran içeren pozitif elektrolit çözeltisinde difüzyonken ile kontrollü gerçekleşmişken, dimetil sulfoksit içeren çözeltide difüzyon+adsorbsiyon ile kontrollü olarak gerçekleşmiştir. Elektrokimyasal impedimetrik analizlerde ise direnç değerleri incelenmiştir. Voltametrik analizlerde kullanılan kalem ucu grafit elektrotun yüzey karakterizasyonu taramalı elektron mikroskobu analizleri ile yapılmıştır.
Investigation the Effects of Tetrahydrofuran and Dimethyl Sulfoxide on the Positive Electrolyte of Vanadium Redox Flow Battery
In this work, a comparative study was done to determine the effects oftetrahydrofuran and dimethyl sulfoxide on the electrochemical behaviors of avanadium redox flow battery’s (VRFB’s) positive electrolyte. In this concept, cyclicvoltammetry and electrochemical impedance spectroscopy were used for thecharacterization of electrolytes consisting of additives, V(IV) and sulfuric acid.Currents and capacities of peaks were determined in cyclic voltammograms. Theredox reaction were controlled by diffusion and diffusion+adsorption intetrahydrofuran and dimethyl sulfoxide including positive electrolyte solutions ofVRFB, respectively. Resistance values were investigated in electrochemicalimpedimetric analysis. The morphological characterization of the pencil graphiteelectrodes used in cyclic voltammetric analysis, were done by scanning electronmicroscopic analysis.
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