Pb ile Tarihlemede Modifiye Sabit Akı Modelinin Göl Sedimentlerine Uygulanması ve Bazı Ağır Metallerin Değerlendirilmesi
Bu çalışmada, Kurşun-210 (Polonyum-210) aktivite konsantrasyonları alfa spektroskopisi kullanılarak dolaylı olarak elde edilmiştir. Sediment kronolojisi modifiye CRS modeli kullanılarak belirlenmiştir. Ortalama sediment birikim hızları S-1, S-2, S-3 istasyonlarında sırasıyla 0.351, 0.324, 0.222 g cm-2 y-1 dır. Atmosferik 210Pb akısı (29 mBq cm-2 y-1)’na göre Karagöl, havzasından ekstra dış girdiye (toprak erozyonu) sahiptir. Ağır metal konsantrasyonları Zenginleşme Faktörü (EF) bakımından antropojenik değerlerin altındadır. Dolayısıyla Au hariç elementlerin karasal kaynaklardan meydana geldiği söylenebilir. Beklenmedik biçimde Au, Karagöl’ün kuzey istasyonunda (S-1) çok yüksek EF değerine (58.22) sahiptir. Bu değer, 2004’ten günümüze kadar olan zaman dilimine karşılık gelmektedir. Ancak Kirlilik Yük İndeksi (PLI) durumun EF değerlerinden çıkan sonuçtan farklı olduğunu söylemektedir. PLI değeri, Karagöl’ün kuzey kısmında kirleticilerin sadece baz seviyesine sahipken Karagöl’ün güney kısmı için bölgenin ilerleyici bozunma aşamasında olduğunu göstermektedir.
Applying of Modified Constant Rate of Supply Model to Lake Sediments in 210Pb Dating and Assessment of Some Heavy Metals
In present study, Lead-210 (Polonium-210) activity concentrations wereindirectly obtained by utilizing alpha spectrometry. Sediment chronology wasdetermined by using modified CRS model. Average sediment accumulation ratesare 0.351, 0.324, 0.222 g cm-2 y-1 in S-1, S-2, S-3 stations respectively. Withreference to atmospheric 210Pb flux (29 mBq cm-2 y-1) Lake Karagöl has extra outer210Pb input (soil erosion) from the catchment area. In terms of Enrichment Factor(EF), heavy metal concentrations are lower than the anthropogenic values. So itcan be said that the elements except Au originate from the continental supply. Auhas unexpectedly too high level EF value (58.22) in northern station (S-1) of theLake Karagöl. It corresponds to time interval from 2004 to nowadays. HoweverPollution Load Index (PLI) says different consequences from the EF values. PLIvalue has only baseline levels of pollutants in northern part of the Lake Karagöl asit shows progressive deterioration of the site for southern part of the Lake Karagöl.
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- Tateda, Y., Carvalho, F. P., Fowler, S. F., Miquel, J.
C. 2003. Fractation of 210Po and 210Pb in coastal
waters of the NW Mediterranean continental
margin. Continental Shelf Research 23, 295-316.
- Zuo, Z., Eisma, D., Gieles, R., Beks, J. 1997.
Accumulation rates and sediment deposition in
the Northwestern Mediterranean. Deep-Sea
Research II 44, 597-609.
- Radakovitch, O., Cherry, R. D., Heyraud, M.,
Heussner, S. 1997. Unusual 210Po/210Pb ratios
in the surfacewater of the Gulf of Lions.
Oceanologica Acta 21, 459-468.
- Goldberg, E. D., 1963. Geochronology with Pb-
210. Proceedings of a symposium of Radioactive
Dating. International Atomic Energy Agency,
1963, Vienna, 121-131.
- Krishnaswami, L. D., Martin, J. M., Meybeck, M.
1971. Geochronology of lake sediments. Earth
Planet Sci. Lett, 11, 407-414.
- Koide, M., Soutar, A., Goldberg, E. D. 1972.
Marine geochronology with 210Pb. Earth Planet
Sc Lett., 14, 442-446.
- Robbins, J. A., Krezosky, J. R., Mozley, S. C. 1977.
Radioactivity in sediments of the Great Lakes:
Post-depositional redistribution by depositfeeding
organisms. Earth Planet Sc Lett., 36, 325-
333.
- Appleby, P. G., Oldfield, F. 1978. The calculation
of lead-210 dates assuming a constant rate of
supply of unsupported 210Pb to the sediment.
Catena, 5, 1-8.
- Oldfield, F., Appleby, P. G., Battarbee, R. W. 1978.
Alternative 210Pb dating: results from the New Guinea Highlands and Lough Erne. Nature, 271,
339-342.
- Liu, J., Carroll, J. L., Lerche, I. 1991. A technique
for disentangling temporal source and sediment
variations from radioactive isotope
measurements with depth. Nucl. Geophys., 5, 31-
45.
- Appleby, P. G. 2001. Chronostratigraphic
techniques in recent sediments. ss 171-203.
- Last, W. M., Smol, J. P., ed. 2001. Tracking
Environmental Change Using Lake Sediments 1.
E-Publishing Inc., Springer, Nedherlands, 548s.
- Benoit, G., Rozan, T. F. 2001. 210Pb and 137Cs
dating methods in lakes: a retrospective study. J.
Peleolimnol., 25, 455-465.
- Walling, D. E., He, Q., Appleby, P. G. 2003.
Conversion Models for Use in Soil-Erosion, Soil-
Redistribution and Sedimentation
Investigations. ss 111-164. Zapata, F., ed. 2003.
- Handbook for the Assessment of Soil Erosion
and Sedimentation Using Environmental
Radionuclides. Springer Netherlands, 219s.
- Tylmann, W. 2005. Lithological and geochemical
record of antropogenic changes in recent
sediments of a small and shallow lake (Lake
Pusty Staw, northern Poland). J Paleolimnol., 33,
313-325.
- Lubis, A. A. 2006. Constant rate of supply (CRS)
model for determination the sediment
accumulation rates in the coastal area using
210Pb. J. Coast. Develop., 10 (1), 9-18.
- Zaborska, A., Carroll, J., Papucci, C., Pempkowiak,
J. 2007. Intercomparison of alpha and gamma
spectrometry techniques used in 210Pb
geochronology. J. Environ. Radioact., 93, 38-50.
- Applby, P. G. 2008. Three decades of dating
recent sediments by fallout radionuclides: a
review. The Holocene, 18, 83-93.
- Kircher, G. 2011. 210Pb as a tool for establishing
sediment chronologies: examples of potentials
and limitations of conventional dating models. J.
Environ. Radioact., 102, 490-494.
- Pittauerová, D., Hettwig, B., Fischer, H. W. 2011.
Pb-210 sediment chronology: focused on
supported lead. Radioprotection, 46 (6), 277-
288.
- Gui, Z., Xue, B., Yao, S., Zhang, F., Yi, S. 2012.
Catchment erosion and trophic status changes
over the past century as recorded in sediments
from Wudalianchi Lake, the northernmost
volcanic lake in China. Quatern Int., 282, 163-
170.
- Sanches-cabeza, J. A., Ruiz-fernandez, A. C. 2012.
210Pb sediment chronology: an integrated formulation and classification of dating models.
Geochim. Cosmochim. Acta, 82, 183-200.
- O’Reilly, J., Vintró, L. L., Mitchell, P. I., Donohue, I.,
Leira, M., Hobbs, W., Irvine, K. 2011. 210Pbdating
of a lake sediment core from Lough Carra
(Co. Mayo, western Ireland): use of
paleolimnological data for chronology validation
below the 210Pb dating horizon. Journal of
Environmental Radioactivity, 102, 495-499.
- Diaz-asencio, M., Alonso-Hernández, C. M.,
Balanos-lvarez, Y., Gómez-Batista, M., Pinto, V.,
Morabito, R., Hernández-Albernas, J. I., Eriksson,
M., Sanchez-Cabeza, J. A. 2009. One century
sedimentary record of Hg and Pb pollution in the
Sagua estuary (Cuba) derived from 210Pb and
137Cs chronology. Mar. Pollut. Bull., 59, 108-
115.
- Ridgway, J., Breward, N., Langston, W. J., Lister,
R., Rees, J. G., Rowlatt, S. M. 2003. Distinguishing
between natural and anthropogenic sources of
metals entering the Irish Sea. Applied
Geochemistry, 18, 283-309.
- Salomons, W., Kertlik, H., van Pagee, H., Klomp,
R., Schreur, A. 1988. Behaviour and impact
assessment of heavy metals in estuary and
coastal zones. ss 157-198. Seeliger, U., de
Lacerda, L. D., Patchineelam, S. R., ed. 1988.
Metals in Coastal Environments of Latin
America. Springer, Berlin, Heidelberg, 297s.
- Nieboer, E., Richardson, D. H. S. 1980. The
replacement of the nondescript term ‘heavy
metals’ by a biologically and chemically
significant classification of metal ions. Environ
Pollut B, 1, 3-26.
- Bryan, G. W. 1979. Bioaccumulation of marine
pollutants. Philos Trans R Soc Lond Ser B, 286,
483-505.
- Sert, I., Eftelioglu, M., Ozel, F. E. 2017. Historical
Evalution of Heavy Metal Pollution and Recent
Records in Lake Karagöl Sediment Cores Using
Lead-210 Models, Western Turkey. J Radioanal.
Nucl. Chem., 314, 2155-2169.
- Flynn, W. W. 1968. The determination of low
levels of Polonium-210 in environmental
materials. Anal. Chim. Acta, 43, 221-227.
- Boisson, F., Miquel, J. C., Cotret, O., Fowler, S. W.
2001. 210Po and 210Pb cycling in an
hydrothermal vent zone in the coastal Aegean
Sea. The Sci. Total Environ, 281, 111-119.
- Sert, I., Yener, G., Ozel, E., Pekcetinoz, B.,
Eftelioglu, M., Gorgun, A. U. 2012. Estimation of
sediment accumulation rates using naturally
occuring 210Pb models in Gulbahce Bay, Aegean
Sea, Turkey. Journal of Environmental
Radioactivity, 107, 1-12.
- Bateman, H. 1910. Solution of a system of
differential equations occurring in the theory of
radioactive transformations. Proc. Cambridge
Philos. Soc., 15, 423-427.
- McDonald, C. P., Urban, N. R. 2007. Sediment
radioisotope dating across a stratigraphic
discontinuity in a mining-impacted lake. Journal
of Environmental Radioactivity, 92, 80-95.
- Parsons, M. J., Long, D. T., Yohn, S. S. 2010.
Assessing the natural recovery of a lake
contaminated with Hg using estimated recovery
rates determined by sediment chronologies.
Applied Geochemistry, 25, 1676–1687.
- Chatterjee, M., Silva, F. E. V., Sarkar, S. K. 2007.
Distribution and possible source of trace
elements in the sediment cores of a tropical
macrotidal estuary and their ecotoxicological
significance. Environ Int., 33, 346-356.
- Zakir, H. M., Shikazono, N., Otomo, K. 2008.
Geochemical distribution of trace metals and
assessment of anthropogenic pollution in
sediments of Old Nakagawa River. Tokyo Jpn.
Am. J. Environ. Sci., 4 (6), 661-672.
- Cobelo-Garcia, A., Prego, R. 2003. Land inputs,
behavior and contamination levels of copper in a
ria estuary (NW Spain). Marine Environmental
Research, 56 (3), 403-422.
- Liu, W. H., Zhao, J. Z., Quyang, Z. Y. 2005. Impact
of sewage irrigation on heavy metal distribution
and contamination in Beijing. China. Environ.
Pol., 31, 805-812.
- Ip, C. C. M., Li, X. D., Zhang, G., Wai, O. W. H., Li, Y.
S. 2007. Trace metal distribution in sediments of
the Pearl River Estuary and surrounding coastal
area South China. Environ. Pollut., 14, 311-323.
- Goher, M. E., Farhat, H. I., Abdo, M. H., Salem, S. G.
2014. Metal pollution assessment in the surface
sediment of Lake Nasser, Egypt. Egyptian
Journal of Aquatic Research, 40, 213-224.
- Guo, W., Huo, S., Xi, B., Zhang, J., Wu, F. 2015.
Heavy metal contamination in sediments from
typical lakes in the five geographic regions of
China: Distribution, bioavailability, and risk.
Ecological Engineering, 81, 243-255.
- El-Amier, Y. A., Elnaggar, A. A., El-Alfy, M. A.
2016. Evaluation and mapping spatial
distribution of bottom sediment heavy metal
contamination in Burullus Lake, Egypt. Egyptian
Journal of Basic and Applied Sciences, 4 (1), 55-
66.
- Din, Z.B. 1992. Use of aluminium to normalize
heavy-metal data from estuarine and coastal
sediments of Straits of Melaka. Marine Pollution
Bulletin, 24 (10), 484-491.
- Rubio, B., Nombela, M., Vilas, F. 2000.
Geochemistry of major and trace elements in
sediments of the Ria de Vigo (NW Spain): an
assessment of metal pollution. Mar. Pollut. Bull.,
40, 968-980.
- Shi, Q., Leipe, T., Rueckert, P., Zhou, D., Harff, J.
2010. Geochemical sources, deposition and
enrichment of heavy metals in short sediment
cores from the Pearl River Estuary, Southern
China. Journal of Marine Systems, 82 (Supp 1),
28-42.
- Darwish, M.A.G. 2013. Geochemistry of the High
Dam Lake sediments, south Egypt: implications
for environmental significance. International
Journal of Sediment Research, 28, 544-559.
- Qi, S., Leipe, T., Rueckert, P., Di, Z. 2010.
Geochemical sources, deposition and
enrichment of heavy metals in short sediment
cores from the Pearl River Estuary. Southern
China Journal of Marine Systems, 82, 28-42.
- Szefer, P., Szefer, K., Glaspy, G.P., Pempkowiak, J.,
Kaliszan, R. 1996. Heavy-metal pollution in
surfical sediments from the southern Baltic Sea
off Poland. J Environ Sci Health. Part A: Environ
Sci Eng Toxic Hazard Subst Control, 31 (10),
2723-2754.
- Szefer, P., Glasby, G.P., Kunzendorf, H., Görlich,
E.A., Latka, K., Ikuta, K., Ali, A. 1998. The
distribution of rare earth and other elements
and the mineralogy of the iron oxyhydroxide
phase in marine ferromanganese concretions
from within Slupsk Furrow in the southern
Baltic. Applied Geochemistry, 13 (3), 305-312.
- Nolting, R.F., Ramkema, A., Everaats, J.M. 1999.
The geochemistry of Cu, Cd, Zn, Ni and Pb in
sediment cores from the continental slope of the
Banc d’Arguin (Mauritania). Continental Shelf
Research, 19, 665-691.
- Sutherland, R.A. 2000. Bed sediment-associated
trace metals in an urban stream. Oahu. Hawaii.
Environ. Geol., 39, 611-627.
- Shumilin, E.N., Carriquiry, J.D., Camacho-Ibar,
V.F., Sapozhnikov, D., Kalmykov, S., Sánchez, A.,
Aguı́n iga-Garcı́a, S., Sapozhnikov, Y.A. 2002.
Spatial and vertical distributions of elements in
sediments of the Colorado river delta and upper
Gulf of California. Mar Chem., 79, 113-131.
- Liaghati, T., Preda, M., Cox, M. 2003. Heavy metal
distribution and controlling factors within
coastal plain sediments, bells creek catchments,
Southeast Queensland, Australia. Environment
International, 29, 935-948.
- Glasby, G.P., Szefer, P., Geldon, J., Warzocha, J.
2004. Heavy-metal pollution of sediments from
Szczecin Lagoon and the Gdansk Basin, Poland.
Sci. Total Environ., 330, 249-269.
- Hakanson, L. 1980. An ecological risk index for
aquatic pollution control: a sedimentological
approach. Water Res., 14, 975-1001.
- Tomlinson, D.C., Wilson, J.G., Harris, C.R., Jeffrey,
D.W. 1980. Problems in the assessment of
heavy-metal levels in estuaries and the
formation of a pollution index. Helgoland Mar.
Res., 33, 566-575.
- Krishnaswami, S., Lal, D. 1978. Radionuclide
limnochronology. ss 153-177. Lerman A ed.
Lakes-chemistry geology physics. 1978.
Springer-Verlag, New York.
- Appleby, P.G., Oldfield, F. 1983. The assessment
of 210Pb data from sites with varying sediment
accumulation rates. Hydrobiologia, 103, 29-35.
- Garcia-Orellana, J., Sanchez-Cabeza, J.A., Masque,
P., [villa, A., Costa, E., Loÿe-Pilot, M.D., Bruach-
Menchén, J.M. 2006. Atmospheric fluxes of
210Pb to the western Mediterranean Sea and
Saharan dust influence. Journal of Geophysical
Research, 111 (D15305), 1-9.
- Wan, G., Chen, J., Xu, S., Wu, F., Santschi, P.H.
2005. Sudden enhancement of sedimentation
flux of 210Pbex as an indicator of lake
productivity as exemplified by Lake Chenghai.
Science in China Ser. D Earth Sciences, 48 (4),
484-495.
- Al-Masri, M.S., Mamish, S., Budeir, Y. 2002. The
impact of phosphate loading activities on near
marine environment: the Syrian coast. J.
Environ. Radioact, 58, 35–44.
- Ribeiro Guevara, S., Meili, M., Rizzo, A., Daga, R.,
Arribére, M. 2010. Sediment records of highly variable mercury input to mountain lakes in
Patagonia during the past millennium. Atmos.
Chem. Phys., 10, 3443-3453.
- Huh, C-A., Chu, K-S., Wei, C-L., Liew, P-M. 1996.
Lead-210 and plutonium fallout in Taiwan as
recorded at a subalpine lake. Journal of
Southeast Asian Earth Science, 14, 373-376.
- Schettler, G., Mingram, J., Negendank, J.F.W.,
Jiaqi, L. 2006. Palaeovariations in the East-Asian
monsoon regime geochemically recorded in
varved sediments of Lake Sihailongwan
(Northeast China, Jilin province). Part 2: a 200-
year record of atmospheric lead-210 flux
variations and its palaeoclimatic implications.
Journal of Paleolimnology, 35, 271-288.
- Begy, R.Cs., Kovacs, T., Veres, D., Simon, H. 2016.
Atmospheric flux, transport and mass balance of
210Pb and 137Cs radiotracers in different
regions of Romania. Applied Radiation and
Isotopes, 111, 31-39.
- Atgin, R.S, El-Agha, O., Zararsiz, A., Kocatas, A.,
Parlak, H., Tuncel, G. 2000. Investigation of the
sediment pollution in Izmir Bay: trace elements.
Spectrochim. Acta B, 55 (7), 1151-1164.
- Zhang, L.P, Liu, C.L. 2002. Riverine composition
and estuarine geochemistry of particulate
metals in China-Weathering features,
anthropogenic impact and chemical fluxes.
Estuary. Coast. Shelf Sci., 54 (6), 1051-1070.
- Karaoglu, O. 2014. Tectonic controls on the
Yamanlar volcano and Yuntdağı volcanic region,
western Turkey: implications for an incremental
deformation. J. Volcanol. Geoth. Res., 274, 16–33.