Hofmann-dahpn-tipi klatratlar: {M(H2N(CH2)7NH2)Ni(CN)4.G(M=Ni. veya Cd;G=bifenil, antrasen, veya fenantren} için FTIR spektroskopik çalışmaları

Bu çalışmada toz halde hazırlanan M(l,7-diaminoheptan)Ni(CN)4GM=Ni veya Cd; G=bifenil , antrasen veya fenantren) klatratlarının FTIR spektrumları incelendi. Klatratlann spektral verileri bu konuk moleküller için mukayese edildiğinde, klatratların yapılarının; M metal atomuna doğrudan bağlı 1,7- diaminoheptan ligandının, sonsuz polimerik ${M-Ni(CN)4}infty$ tabakalarıyla oluşturduğu boşluklardan meydana geldiği saptandı

FITIR spectroscopic studies on the Hofmann-dahpn-type clathrates: {M(H2N(CH2)7NH2)Ni(CN)4.G(M=Ni. or Cd;G=biphenyl, anthracene or phenanthrene}

In this study, Hofmann-diaminoheptane-type clathrates of the form M(l,7-diaminoheptane) Ni(CN)4G (M=Ni, or Cd; G=biphenyl, anthracene, or phenanthrene) have been prepared in powder form and FTIR spectra of the clathrates are reported. Their spectral data were compared with those of onding hosts. Their structure consists of corrugated pclymeric layers of ${M-Ni(CN)4}infty$ with the 1,7-diaminoheptane bound directly to the metal atom M.

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