POLY(MPAEMA)/CLAY NANOCOMPOSITES: SYNTHESIS, CHARACTERIZATION, STRUCTURAL, AND THERMAL PROPERTIES

In this study, the synthesis, characterization, and thermal properties of poly(2-(4-methoxyphenyl amino)-2-oxoethyl methacrylate) (MPAEMA) polymer/clay based nanocomposites were investigated by in situ polymerization. At the characterizations of nanomaterials FTIR, XRD, SEM, and TGA techniques were used. It was determined from XRD and SEM measurements that the morphology of nanocomposites was exfoliated when the clay content in the polymer matrix was kept at 3% and 5%. From thermal analysis, a positive correlation was observed between the clay ratio and thermal stability of nanomaterials.

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  • [1] Robeson, L.M., Paul, D.R., (2008) Polymer nanotechnology:Nanocomposites, Polymer, 49, 3187-3204.
  • [2] Mandalia, T., Bergaya, F., (2006) Organo clay mineral-melted polyolefin nanocomposites effect of surfactant/CEC Ratio, Journal of Physics and Chemistry of Solids, 67, 836-845.
  • [3] İşçi, S., Ece, Ö.I., Güngör, N., (2006) Characterization of rheology, electrokinetic properties and surface micromorphology of DTABr/MMT and CPBr/MMT organoclays, Journal of Composite Materials, 40, 1105-1115.
  • [4] Mandalia, T., Bergaya, F., (2006) Organo clay mineral-melted polyolefin nanocomposites effect of surfactant/CEC Ratio, Journal of Physics and Chemistry of Solids, 67, 836-845.
  • [5] Ray, S.S., Okamoto, M., (2003) Polymer/Layered Silicate Nanocomposites: A Review from Preparation to Processing, Progress in Polymer Science, 28, 1539-1641.
  • [6] Paiva, L.B., Morales, A.N., Valenzuela F.R., (2008) Organoclay: properties, preparation and applications, Applied Clay Science, 42, 8-24.
  • [7] Liu, P., (2007) Polymer modified clay minerals: A review, Applied Clay Science, 38, 64-76.
  • [8] Çankaya, N., Besci, G., (2018) Synthesis, characterization, thermal properties and reactivity ratios of methacrylate copolymers including methoxy group, Journal of the Faculty of Engineering and Architecture of Gazi University, 33(3), 1155-1170.
  • [9] Daşbaşı, T., Soykan, C., Çankaya, N., Ülgen, A., (2018) Determination of some trace metals with a new synthesized polymer resin by FAAS in various tea and herbal plants samples, Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 55(6), 466-473.
  • [10] Çankaya, N., (2020) Preparaiıon of Oxo Methacrylate-Containing Polymer/Clay Based Nanocomposites, International Transaction Journal of Engineering, Management,&Applied Sciences&Technologies, 128, 11(7), 1-8.
  • [11] Zhang, W.A., Chen, D.Z., Xu, H.Y., Shen, X.F., Fang Y.E., (2003) Influence of four different types of organophilic clay on the morphology and thermal properties of polystyrene/clay nanocomposites prepared by using the c-ray irradiation technique, European Polymer Journal, 39(12), 2323-2328.
  • [12] Kurt, A., Topsoy, O.K., (2017) Preparation of Novel Coumarin Cyclic Polymer/Montmorillonite Based Nanocomposites, Russian Journal of Applied Chemistry, 90(12), 2019−2027.
  • [13] Delibas, A., Alparslan, M., (2015) Synthesis and characterization of halogen-containing aryl amide polymer-clay nanocomposites, Turkish Journal of Chemistry, 39, 630-638.
  • [14] Çankaya, N., Şahin, R., (2019) Chitosan/Clay Bionanocomposites: Structural, Antibacterial, Thermal and Swelling Properties, Cellulose Chemistry and Technology, 53(5-6), 537-549.
  • [15] Kurt, A., Yavuz, R., Bozdağ, G., (2013) Polistiren-Kil Nanokompozitlerin Sentezi, Termal ve Optik Özelliklerinin İncelenmesi, Adıyaman University Journal of Science, 3(2) 58-70.
  • [16] Kurt, A., Kaya, M., Koca, M., (2017) Kumarin Modifiyeli Organokilin PMMA Nanokompozitlerinin Hazırlanmasındaki Rolü, TÜBAV Bilim Dergisi, 10(4), 11-20.
  • [17] Kurt, A., Çağlayan, Z., Bektaş, H.S., (2014) Preparation of Poly(Methyl Methacrylate)/Clay Nanocomposites and Investigation of Some Physical Properties, Sigma Journal of Engineering and Natural Sciences, 32, 71-80.
  • [18] Tcherbi-Narteh, A., Hosur, M.V., Triggs, E., Jelaani, S., (2013) Effects of Surface Treatments of Montmorillonite Nanoclay on Cure Behavior of Diglycidyl Ether of Bisphenol A Epoxy Resin, Hindawi Publishing Corporation Journal of Nanoscience, 1-12.
  • [19] Tcherbi-Narteh, A., Hosur, M., Jeelani, S., (2016) Effects of Different Montmorillonite Nanoclay Loading on Cure Behavior and Properties of Diglycidyl Ether of Bisphenol A Epoxy, Hindawi Publishing Corporation Journal of Nanomaterials, 1-12.
  • [20] Tcherbi-Narteh, A., Hosur, M., Triggs, E., Owuor, P., Jelaani, S., (2014) Viscoelastic and thermal properties of full and partially cured DGEBA epoxy resin composites modified with montmorillonite nanoclay exposed to UV radiation, Polymer Degradation and Stability, 101, 81-91.