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Hindi Kesimhanesi Atıksuyunda Fotokatalitik Arıtma ve Taguchi Metodu ile Optimizasyon

Heterojen fotokataliz, kimyasal oksijen ihtiyacı (KOİ), azot ve fosfor gibi yüksek seviyede organik kirleticiler içeren kanatlı endüstrisinden ham hindi kesimhanesi atık sularının arıtımında umut verici yeşil bir teknoloji olup arıtım potansiyeli şimdiye kadar yeterince incelenmemiştir. Bu çalışmada, hindi kesimhanesi atık suyunun fotokatalitik bozunması, Taguchi yöntemine dayalı bir yanıt yüzeyi metodolojisi (RSM) uygulanarak incelenmiştir. Bu amaçla, kritik çalışma parametreleri; fotokatalizör konsantrasyonu (0,5-3 g/L, A), pH (2-10, B), hidrojen peroksit (H2O2) konsantrasyonu (0-20 mmol/L, C), lamba türü (UVA, UVC, D) ve katalizör tipi (TiO2, ZnO, E) optimize edilmiştir. Bu deneysel faktörler karışık seviyelerde (43 22) ele alınmış ve L16 testleri uygulanarak çalışma parametreleri optimize edilmiştir. ANOVA sonuçlarına göre katalizör ve H2O2 konsantrasyonu ile pH parametreleri atık sudan KOİ gideriminde en önemli etkiye sahiptir. Optimum koşullar şu şekilde elde edilmiştir: başlangıç katalizör dozu 0,5 g/L (Seviye 1), pH 2 (Seviye 1), H2O2 konsantrasyonu 10 mmol/L (Seviye 3), lamba tipi UVA (Seviye 1) ve katalizör tipi ZnO (Seviye 2). Bu şartlar altında deneysel ve tahmini KOİ giderim verimleri sırasıyla %62 ve %63 olarak elde edilmiştir. Ayrıca yapılan çalışmada, işletme maliyetini oluşturan en önemli faktör elektrik enerjisi tüketimi olurken kimyasal ve elektrik enerjisi maliyeti optimum koşullar altında 1,315 TL ve 32,325 TL olarak elde edilmiştir.

Anahtar Kelimeler:

Kanatlı endüstrisi, Hindi atık suyu, Fotokataliz, Taguchi metodu, Optimizasyon

Photocatalytic Treatment of Turkey Slaughterhouse Wastewater and Optimization by Taguchi Method

Heterogeneous photocatalysis is a promising green technology in the treatment of raw turkey slaughterhouse wastewater from the poultry industry, which contains high levels of organic pollutants such as chemical oxygen demand (COD), nitrogen and phosphorus, and its treatment potential has not been adequately studied until now. In this work, the photocatalytic degradation of turkey slaughterhouse wastewater was studied by applying a response surface methodology (RSM) based on Taguchi method. For this purpose, critical operating parameters; photocatalyst concentration (0,5-3 g/L, A), pH (2-10, B), hydrogen peroxide (H2O2) concentration (0-20 mmol/L, C), lamp type (UVA, UVC, D), and catalyst type (TiO2, ZnO, E) were optimized. These experimental factors were handled in mixed levels (43 22), and operation parameters were optimized by the application of L16 tests. According to ANOVA results, catalyst and H2O2 concentration and pH parameters have the most important effects on COD removal from wastewater. Optimum conditions were obtained as: initial catalyst dosage of 0,5 g/L (Level 1), pH of 2 (Level 1), H2O2 concentration of 10 mmol/L (Level 3), lamp type as UVA (Level 1) and catalyst type as ZnO (Level 2). Under these conditions, experimental and estimated COD removal efficiencies were obtained as 62% and 63%, respectively. In addition, in the study, electrical energy consumption is the most significant factor that creates the operating cost, while the chemical and electrical energy costs are 1,315 TL and 32,325 TL under optimum conditions.

Keywords:

Poultry industry, Turkey wastewater, Photocatalysis, Taguchi method, Optimization,

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