SUDA TPH (TOPLAM PETROL HİDROKARBONLARI) ANALİZİNİN PETROL VE DOĞALGAZ ARAMA AMAÇLI KULLANIMI: TÜRKİYE’DEN İLK ÖNEMLİ SONUÇLAR
Hidrokarbon birikimleri ile ilişkide olan veya hidrokarbonlar tarafından kirletilmişyüzey ve yeraltısuları tipik olarak yüksek miktarda hidrokarbon içerirler. Sunumunelerinde TPH (Toplam Petrol Hidrokarbonları) değeri, yüzey veyeraltısularının hidrokarbon kirliliğini belirlemek için kullanılan önemli birparametredir. Bu çalışmada, suların hidrokarbon içeriğini tanımlayan TPH (ToplamPetrol Hidrokarbonları) analizinin, petrol ve doğalgaz aramacılığındakullanılabilirliğinin incelenmesi amaçlanmıştır. Bu amaçla, Yüksekova (Hakkari),Ulukışla (Niğde) ve Hasanoğlan (Ankara) bölgeleri yeraltısularında yapılan TPHanalizlerine ait sonuçlar, aynı bölgedeki klasik petrol jeokimyası analiz sonuçları ilekarşılaştırılmıştır. İncelenen su numunelerinin tamamının TPH değerlerininyeraltısuları için önerilen sınır değerden oldukça yüksek olduğu görülmüştür.Ayrıca, her üç bölge sularında da olgun doğal petrol kaynaklı n-alkanhidrokarbonları tespit edilmiştir. Çalışma sonucunda, numune alma işlemi oldukçabasit, laboratuvar analizleri de çok kısa sürede sonuçlandırılan, düşük maliyetli,güvenilir ve tutarlı sonuçları olan rezervuar hedefli suda TPH (Toplam PetrolHidrokarbonları) analizleri ile petrol ve doğalgaz birikimleri içeren havzalarınbelirlenebileceği sonucuna ulaşılmıştır. Diğer jeolojik ve jeofizik yöntemler ilebirlikte kullanılması durumunda da, hidrokarbon arama riskini en aza indirerek veticari üretim yapılabilir yeni petrol ve doğalgaz yataklarının keşfedilebilmesi içinpratik ve etkili bir araç olarak kullanılabilecektir. Ayrıca, kaya numuneleri üzerindeyapılan tüm petrol jeokimyasal analiz (gaz kromatografi, gaz kromatografi kütlespektroskopisi, piroliz vb.), yöntem ve yorumların, hidrokarbon içeren sunumuneleri üzerinde de başarılı bir şekilde uygulanabileceği bu çalışmanın diğerönemli sonucudur.
USAGE OF TPH (TOTAL PETROLEUM HYDROCARBONS) IN WATER ANALYSIS FOR OIL AND GAS EXPLORATION: FIRST IMPORTANT RESULTS FROM TURKEY
Surface waters and groundwaters associated with hydrocarbon accumulations or contaminated by hydrocarbons typically contain high amounts of hydrocarbons. TPH (Total Petroleum Hydrocarbons) value in water samples is an important parameter used to determine hydrocarbon contamination of surface waters and groundwaters. In this study, it is aimed to examine TPH analysis which describe the hydrocarbon content of waters in oil and gas exploration. For this purpose, the results of TPH analysis in water samples of Yüksekova (Hakkari), Ulukışla (Niğde) and Hasanoğlan (Ankara) regions are compared with the results of classical petroleum geochemistry analysis in the same regions. It has been found that the TPH values of all examined water samples are considerably higher than the recommended limit values for groundwaters. In addition, petrogenic (natural crude oil) mature n-alkane hydrocarbons have been determined in all three regional waters. As a result of the study, the sampling is very simple and the laboratory analysis have reached TPH in water analysis in reservoir-targeted with low cost, reliable and consistent results, which can be concluded in a very short time and the result that the basins containing oil and gas deposits can be determined. When used in together with other geological and geophysical exploration methods, it can also be used as a practical and effective tool to minimize the risk of hydrocarbon exploration and to discover new oil and gas deposits that are commercial production. In addition, all the petroleum geochemical analysis (gas chromatography, gas chromatography, mass spectroscopy, pyrolysis, etc.) on rock samples can also be applied successfully on hydrocarbon containing water samples.
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- Adeniji, A.O., Okoh, O.O. and Okoh, A.I., 2017.
Petroleum hydrocarbon profiles of water and
sediment of Algoa Bay, Eastern Cape, South Africa.
Int. J. Environ. Res. Public Health, 14, 1263;
doi:10.3390/ijerph14101263
- Adewuyi, G.O. and Olowu, R.A., 2012. Assessment of oil
and grease, total petroleum hydrocarbons and
some heavy metals in surface and groundwater
within the vicinity of NNPC oil depot in Apata,
Ibadan Metropolis, Nigeria. IJRRAS, 13 (1), 166-
174
- Akar, Ç., Yılmazer, P., Tokoğlu, E.E., Araç, B., Günaydın,
S., Çetin, S., 2018. Niğde-Ulukışla Gaz ve Su
Örneklerinin Jeokimyasal Değerlendirme Raporu.
TPAO Rapor No: 4310 (Yayımlanmamış)
- Al Darwish, H.D.A., 2004. Assessment of organic and
inorganic pollutants in the offshore sediments,
Dubai, UAE. United Arab Emirates University. MSc.
Thesis, 366 p.
- Allan, J. and Douglas, A.G., 1977. Variations in the
content and distribution of n-alkanes in a series of
carboniferous vitrinites and sporinites of
bituminous rank. Geochimica et Cosmochimica
Acta, 41, 1223-1230
- ATSDR (Agency for Toxic Substances and Disease
Registry), 1999. Toxicological Profile for Total
Petroleum Hydrocarbons (TPH). Atlanta. GA: US
Department of Health and Human Services. Public
Health Service, 231 p.
- Ayotamuno, M.J., Kogbara, R.B., Ogaji, S.O.T. and
Probert, S.D., 2006. Petroleum contaminated
ground-water: Remediation using activated
carbon. Applied Energy, 83, 1258-1264
- Banga, T., Capuano, R.M. and Bissada, K.K., 2011.
Petroleum generation in the southeast Texas basin:
Implications for hydrocarbon occurrence at the
South Liberty salt dome. AAPG Bulletin, 95(7),
1257-1291
- Beyer, J., Jonsson, G., Porte, C., Krahn, M.M. and Ariese,
F., 2010. Analytical methods for determining
metabolites of polycyclic aromatic hydrocarbon
(PAH) pollutants in fish bile: a review. Environ
Toxicol Pharmacol, 30(3), 224-244
- Bray, E.E. and Evans, E.D., 1961. Distribution of nparaffins
as a clue to recognition of source rocks.
Geochim. Cosmochim, Acta. 22, 2-15
- Bray, E.E. and Evans, E.D., 1965. Hydrocarbons in nonreservoir-
rock source beds: Part 1. American
Association of Petroleum Geologists Bulletin, 49,
248-257
- Campos J.C., Borges R.M.H., Filho A.M.O., Nobrega R.,
and Sant’Anna Jr. G.L., 2002. Oilfield wastewater
treatment by combined microfiltration and
biological processes. Water Research, 36, 95 - 104
- Chen, J., Liu, D., Peng, P., Ning, C., Xiaolin, H. and
Baoshou, Z., 2016. Iodine-129 chronological study
of brines from an Ordovician paleokarst reservoir
in the Lunnan oilfield, Tarim Basin. Applied
Geochemistry, 65, 14-21
- Collins, A.G. and Egleeson, G.C., 1967. Iodine
abundance in oilfield brines in Oklahoma. Science,
156, 934-935
- Çoban, M.K., 2017. Petrol Hidrojeolojisi (İkinci Baskı).
Poyraz Ofset. 533 s.
- Çorbacıoğlu, H., Kırman, Z.D., Yılmazer, P., Doğan, S.,
Tokoğlu, E.E., Araç, B., Türesin, F.M., Huvaj, N.Y.,
Elmacı, A., Türkecan, A.T., Çevik, T., Bahtiyar, İ.,
Sarıkaya, H., Aydın, MG., Bakırhan, B. ve Yüksel, M.,
2018. Hakkâri-Yüksekova-Hisardağı Bölgesi’nden
Alınan Su, Emare ve Kayaç Örneklerinin
Değerlendirme Raporu. TPAO Rapor No: 4297
(Yayımlanmamış)
- Deutsch, W.J., 1997. Groundwater Geochemistry,
Fundamental and Applications to Contamination.
Lewis Publisher, 232 p.
- Didyk, B.M., Simoneit, B.R.T., Brassel, S.C. and
Englington, G., 1978. Organic geochemical
indicators of paleoenvironmental conditions of
sedimentation. Nature, 272, 216-222
- Doğanay, E., 2014. AB Su Çerçeve Direktifine Göre
Ülkemiz Sularının Fizikokimyasal ve Kimyasal
Parametreler Açısından İzlenebilmesi için
Kullanılabilecek Analiz Metotlarının
Değerlendirilmesi, Orman ve Su İşleri Bakanlığı,
Uzmanlık Tezi, 205 s.
- Dow, W.G., 1978. Petroleum source beds on
continental slope and rises. Amer. Assoc. Petr. Geol.
Bull., 62(9), 1584-1606
- Ekpo, B.O., Essien, N., Fubara, E.P., Ibok, U.J., Ukpabio,
E.J. and Wehner, H., 2013. Petroleum geochemistry
of Cretaceous outcrops from the Calabar Flank,
southeastern Nigeria. Marine and Petroleum
Geology, 48, 171-185
- El Nemr, A., Moneer, A.A., Ragab, S. and Sikaily, A.E.,
2016. Distribution and sources of n-alkanes and
polycyclic aromatic hydrocarbons in shellfish of
the Egyptian Red Sea coast. Egyptian Journal of
Aquatic Research (2016),
http://dx.doi.org/10.1016/j.ejar.2016.05.003
- Emara, H.I., 1998. Total organic carbon content in the
waters of the Arabian Gulf. Environment Int.,
24(1/2), 97-103
- Fabryka-Martin, J.T., Bentley, H., Elmore, D. and Airey,
P.L., 1985. Natural iodine-129 as environmental
tracer: Geochim. Cosmochim. Acta, 49, 337-347
- Fabryka-Martin, J.T., Davis, S.N. and Elmore, D., 1987.
Applications of 129I and 36Cl in hydrogeology: Nucl.
Instrum. Methods Phys. Res., B29, 361-371
- Fan, W., Yang, Y.S., Du, X.Q., Lu, Y. and Yang, M.X., 2011.
Finger-Printing Biodegradation of Petroleum
Contamination in Shallow Groundwater and Soil
System Using Hydro-bio-geochemical Markers and
Modelling Support, Water Air Soil Pollut., 220, 253-
263
- Fehn, U., Moran, J.E., Snyder, G.T. and Muramatsu, Y.,
2007. The initial 129I/I ratio and the presence of
“old” iodine in continental margins. Nuclear
Instruments and Methods in Physics Research
Section B-Beam Interactions with Materials and
Atoms, 259, 496-502
- Fehn, U., Tullai, S., Teng, R.T.D., Elmore, D. and Kubik,
P.W., 1987. Determination of 129I in heavy residues
of two crude oils: Nucl. Instrum. Methods Phys.
Res., B52, 446-45
- Frimmel, A., Oschmann, W. and Schwark, L. 2004.
Chemostratigraphy of the Posidonia Black Shale,
SW Germany: I. Influence of sea-level variation on
organic facies evolution. Chemical Geology, 206,
199-230
- Gawad, E.A., Lotfy, M.M. and Sakroon, S.A., 2010.
Assessing the organic and inorganic pollutants of
oilfield brine water in Marmul area, Sultanate of
Oman. Australian Journal of Basic and Applied
Sciences, 4(5), 859-876
- Hakimi, M.H., Al-Matary, A.M. and Ahmed, A.., 2017.
Bulk geochemical characteristics and carbon
isotope composition of oils from the Sayhut subbasin
in the Gulf of Aden with emphasis on organic
matter input, age and maturity. Egyptian Journal of
Petroleum,
https://doi.org/10.1016/j.ejpe.2017.06.002
- Hartkopf-Fröder, C., Kloppisch, M., Mann, U.,
Neumann-Mahlkau, P., Schaefer, R.G. and Wilkes
- H., 2007. The end-Frasnian mass extinction in the
Eifel Mountains, Germany: new insights from
organic matter composition and preservation.
Geological Society, London, Special Publications,
278, 173-196. doi: 10.1144/SP278.8
- Heroux, Y., Chagnon, A.G. and Bertrand, R., 1979.
Compilation and correlation of major thermal
maturation indicators. AAPG Bulletin, 63, 2128-
2144
- Hunt, J.M., 1995. Petroleum Geochemistry and
Geology. W.H. Freeman and Company, New York.
743 p.
- Kartsev, A.A., Tabasaranskii, S.A., Subbota, M.I. and
Mogilevsky, G.A., 1959. Geochemical methods of
prospecting and exploration for petroleum and
natural gas (P. A. Witherspoon and W. D, Romey,
eds., English translation) : Berkeley, Univ. Calif.
Press, 238 p.
- Kendrick, M.A. and Phillips, D., 2009. New constraints
on the release of noble gases during in vacuo
crushing and application to scapolite Br-Cl-I and
40Ar/39Ar age determinations. Geochim.
Cosmochim. Acta, 73, 5673-5692
- Kendrick, M.A., Phillips, D., Wallace, M. and Miller,
J.McL., 2011. Halogens and noble gases in
sedimentary formation waters and Zn-Pb deposits:
A case study from the Lennard Shelf, Australia.
Applied Geochemistry, 26, 2089-2100
- Kırkland, D.W. and Evans, K., 1981. Source rock
potential of evaporitic environment. Amer. Assoc.
Petr. Geol. Bull., (65/2), 181-190
- Kolukırık, M., İnce, O. and İnce, B.K., 2009. Local and
Seasonal Changes in Microbial Diversity of the
Marmara Sea Sediments. Mar Pollut Bull MPB-D-
09-00623 (Ketre, C.Z., 2010. Anaerobic BTEX
Degrading Microorganism Abundances in
Marmara Sea Sediments. İstanbul Teknik
Üniversitesi, Yüksek Lisans Tezi, 137 s., içerisinde)
- Kolukırık, M., İnce, O., Çetecioğlu, Z., Çelikkol, S., İnce,
B.K., 2011. Spatial and temporal changes in
microbial diversity of the Marmara Sea Sediments.
Marine Pollution Bulletin, 62, 2384-2394
- Koons, C.B., Jamieson, G.W. and Ciereszko, L.S., 1965.
Normal alkane distributions in marine organisms:
possible significance to petroleum origin. Bull. Am.
Assoc. Petrol. Geol., 49; 301-316
- Kurchikov, A.R. and Plavnik, A.G., 2009. Clustering of
groundwater chemistry data with implications for
reservoir appraisal in West Siberia. Russian
Geology and Geophysics 50, 943-949
- Land, L.S., 1991. Evidence for vertical movement of
fluids, Gulf Coast Sedimentary Basin: Geophys. Res.
Lett., 18(5) 919-922
- Lee, R., Seright, R., Hightower, M., Sattler, A., Cather, M.,
McPherson, B., Wrotenbery, L., Martin, D. and
Whitworth, M., 2002. Strategies for Produced
Water Handling in New Mexico. Groundwater
Protection Council Produced Water Conference,
http://www.gwpc.org/meetings/special/PW%20
2002/Papers/ Robert_Lee_PWC2002.pdf
- Lundegard, P.D. and Sweeney, R.E., 2004. Total
petroleum hydrocarbons in groundwaterevaluation
of nondissolved and nonhydrocarbon
fractions. Environmental Forensics, 5(2), 85-95,
DOI: 10.1080/15275920490454346
- Massoud, S., Al-Abdali, F., Al-Ghadban, A.N. and Al-
Sarawi, M., 1996. Bottom sediments of the Arabian
Gulf II: TPH and TOC contents as indicators of oil
pollution and implications for the effect and fate of
the Kuwait oil slick. Environmental Pollution,
93(27), 1-284.
- Mazor, E., 2004. Global Water Dynamics (Shallow and
Deep Groundwater, Petroleum Hydrology,
Hydrothermal Fluids, and landscaping). Marcel
Dekker, Inc., 393 p.
- Meinhold, R., 1972. Hydrodynamic control of oil and
gas accumulation as indicated by geothermal,
geochemical and hydrological distribution
patterns, Trans. 8th World Petrol. Cong., 2, 55-66
- Mille, G., Asia, L., Guiliano, M., Malleret, L. and
Doumenq, P., 2007. Hydrocarbons in coastal
sediments from the Mediterranean Sea (Gulf of Fos
area, France). Marine Pollution Bulletin, 54, 566-
575
- Momper, J.A., 1978. Oil migration limitations
suggested by geological consideration. AAPG. Bull.,
Continuing Educ. Course Note, 8, 21-38
- Moran, J.E., Fehn, U. and Hanor, J.S., 1995.
Determination of source ages and migration of
brines from the U.S. Gulf Coast basin using 129 I.
Geochim. Cosmochim. Acta 59, 5055-5069
- Neff, J.M., 2002. Bioaccumulation in Marine
Organisms: Effect of Contaminants from Oil Well
Produced Water. Elsevier Science, 452 p.
- Obermajer, M., Osadetz, K.G., Fowler, M.G., Snowdon,
L.R., 2000. Light hydrocarbon (gasoline range)
parameter refinement of biomarker-based oil-oil
correlation studies: an example from Williston
Basin. Organic Geochemistry, 31, 959-976
- Onojake, M.C., Osuji, L.C. and Oforka, N.C., 2013.
Preliminary hydrocarbon analysis of crude oils
from Umutu / Bomu fields, south west Niger Delta
Nigeria. Egyptian Journal of Petroleum, 22, 217-
224
- Oppo, D. and Capozzi, R., 2015. Spatial association of
mud volcano and sandstone intrusions, Boyadag
anticline, western Turkmenistan. Basin Research,
1-13, doi: 10.1111/bre.12136
- Özdemir, A., Turgay, S.O. and Şahinoğlu, A., 2018. High
accuracy estimation with computer-aided
hydrogeochemical methods of oil and gas deposits
in wildcat sedimentary basins. Journal of Applied
Geology and Geophysics, 6(4), 62-104
- Özdemir, A., 2018a. Güneydoğu Anadolu havzasında
petrol ile iyot ilişkisi. MTA Dergisi,
http://dx.doi.org/10.19076/mta.464160
- Özdemir, A., 2018b. Relationships of formation,
migration and trapping between petroleum and
iodine. International Journal of Natural and
Engineering Sciences (baskıda)
- Özdemir, A., 2018c. Hasanoğlan (Ankara) petrol
sisteminin organik hidrojeokimyasal kanıtları.
Pamukkale Üniversitesi Mühendislik Bilimleri
Dergisi (baskıda)
- Özdemir, A., 2018d. Türkiye’nin iyotça zengin suları ve
petrol potansiyeli, Sürdürülebilir Mühendislik
Uygulamaları ve Teknolojik Gelişmeler Dergisi
(baskıda)
- Özdemir, A. ve Şahinoğlu, A., 2018. Ulukışla (Niğde)
havzasının petrol potansiyeli. Afyon Kocatepe
Üniversitesi Fen ve Mühendislik Bilimleri Dergisi
(hakemde)
- Peters, K.E. and Moldowan, J.M., 1993. The Biomarker
Guide, Interpreting Molecular Fossils in Petroleum
and Ancient Sediments. Englewood Cliffs, Jersey,
Prentice Hall, 339-363
- Peters, K.E., Fraser, T.H., Amris, W., Rustanto, B. and
Hermanto, E., 1999. Geochemistry of crude oils
from eastern Indonesia. American Association of
Petroleum Geologists Bulletin, 83, 1927-1942
- Potter II, R. W., Harrington, P.A., Silliman, A.H. and
Viellenave, J.H., 1996. Significance of geochemical
anomalies in hydrocarbon exploration, in D.
Schumacher and M. A. Abrams, eds., Hydrocarbon
migration and its near-surface expression: AAPG
Memoir 66, 431-439
- Qiao, X., Zhang, Z., Yu, J. and Ye, X., 2008. Performance
characteristics of a hybrid membrane pilot-scale plant for oilfield-produced wastewater.
Desalination, 225(1-3),113–122
- Riccardia, C. Di Filippoa, D., Pomataa, D., Incoronatoa,
F., Di Basilioa, M., Papinib, M.P. and Spicaglia, S.,
2008. Characterization and distribution of
petroleum hydrocarbons and heavy metals in
groundwater from three Italian tank farm. Science
of the Total Environment, 393, 50 - 63
- Robertson, A. 1998. Petroleum hydrocarbons. Arctic
Monitoring and Assessment Programme (AMAP),
Oslo, pp. 661-716
- Sakroon, S.A., 2008. Effect of oilfield brine on
groundwater quality in Marmul area, Sultanate of
Oman. United Arab Emirates University, MSc.
Thesis, 146 p.
- Shahsavari, A.A., Khodaei, K., Rahele, H, Asadian, F. and
Zamanzadeh, S.M., 2013. Distribution of total
petroleum hydrocarbons in Dezful aquifer,
Southwest of Iran. Arabian Journal of Geosciences,
DOI 10.1007/s12517-013-0887-4
- Stueber, A.M., Walter, L.M., Huston, T.J. and Pushkar, P.,
1993. Formation waters from Mississippian-
Pennsylvanian reservoirs, Illinois basin, USA:
Chemical and isotopic constraints on evolution and
migration. Geochimica et Cosmochimica Acta. 57,
163-784
- Su, X., Lv, H., Zhang, W., Zhang, Y. and Jiao, X., 2013.
Evaluation of petroleum hydrocarbon
biodegradation in shallow groundwater by
hydrogeochemical indicators and C, S-isotopes.
Environ Earth Sci., 69, 2091-2101
- Tedesco, S.A., 1995. Surface Geochemistry in
Petroleum Exploration. Springer, 206 p.
- Teng, Y., Feng, D., Song, L., Wang, J. and Li, J., 2013.
Total petroleum hydrocarbon distribution in soils
and groundwater in Songyuan oilfield, Northeast
China. Environ. Monit. Assess. 185, 9559-9569
- Thompson, J.G., 1982. Hydrocarbon source rock
analyses of Pakawau Group and Kapuni Formation
sediments, northwest Nelson and offshore South
Taranaki, New Zealand. New Zealand Journal of
Geology and Geophysics, 25(2), 141-148,
DOI:10.1080/00288306.1982.10421406
- Tissot, B.P. and Welte, D.H., 1984. Petroleum
Formation and Occurrence. Springer-Verlag, 699 p.
Tran, K.L. and Philippe, B., 1993. Oil and rock extract
analysis. in Applied Petroleum Geochemistry (M.L.,
Bordenave, eds.), p. 373-394
- Tullai, S., Tubbs, L. E. and Fehn, U., 1987. Iodine
extraction from petroleum for analysis of 129I/I
ratios by AMS. Nucl. Instrum. Methods Phys. Res. B,
29, 383-386
- Veil, J.A., 2006. Comparison of two international
approaches to controlling risk from produced
water discharges. Paper presented at the 70th
PERF meeting, Paris, France
- Volkman, J.K. and Maxwell, J.R., 1986. Acyclic
isoprenoids as biological markers. In: Biological
Markers in the Sedimentary Record (R.B. Johns,
eds.), Elsevier, New York; pp. 1-42
- Waples, D.W., 1985. Geochemistry in Petroleum
Exploration. International Human Resources
Development Corp., 232 p.
- Xie, X., Wang, Y. and Su, C., 2012. Hydrochemical and
sediment biomarker evidence of the impact of
organic matter biodegradation on arsenic
mobilization in shallow aquifers of Datong basin,
China. Water Air Soil Pollut., 223, 483-498
- Yang, Z.H., Lien, P.J., Huang, W.S., Surampalli, R.Y. and
Kao, C.M., 2015. Development of the risk
assessment and management strategies for TPHcontaminated
sites using TPH fraction methods. J.
Hazard. Toxic Radioact. Waste. DOI:
10.1061/(ASCE)HZ.2153-5515.0000290
- Zemo, D.A. and Foote, G.R., 2003. The technical case
eliminating the use of the TPH analysis in assessing
and regulating dissolved petroleum hydrocarbons
in groundwater. Ground Water Monitoring &
Remediation, 23(3), 95-104