Yusuf Doruk ARACAGÖK, Gözde KOŞARSOY AĞÇELİ, Mahmut KABALAK

Polimerle Boya Gideriminde Yeni Bir Yaklaşım: Karides Kitini İle Sulu Çözeltiden Asit Portakal 12'nin Giderimi

Kitin, doğal olarak bol miktarda bulunan bir mukopolisakkarit olup kabukluların, böceklerin vb. canlıların destekleyici malzemesidir. Kitin ve ana türevi kitosan, toksik olmamaları, biyolojik olarak parçalanabilirlikleri, biyouyumlulukları, antimikrobiyal ve antioksidan özelliklerinden dolayı tıp, eczacılık, biyoteknoloji, çevre ve gıda mühendisliğinde çeşitli uygulamalara sahiptir. Burada, tekstilde en çok kullanılan azo boya maddelerden biri olan Asit Portakal 12'nin bir polimer olan karides kitini vasıtasıyla sulu çözeltilerden uzaklaştırılması üzerine araştırma yapılmıştır. En uygun koşulları belirlemek için farklı parametreler (pH dereceleri, kitin miktarı, boya miktarı, temas süresi) çalışılmıştır. Kitin, pH 5 koşullarında kullanılarak Asit Portakal 12'nin uzaklaştırılmasında en verimli olarak tespit edilmiştir. Boyanın kitin üzerine adsorpsiyonu Langmuir izotermine ve yalancı-ikinci-dereceden kinetik modele uymuştur.

Anahtar Kelimeler:

Eklembacaklı, biyopolimer, su, temizleme, çevre

A New Approach for Dye Removal with a Polymer: Removal of Acid Orange 12 from Aqueous Solution with Shrimp Chitin

Chitin, a naturally abundant mucopolysaccharide, is the supporting material of crustaceans, insects, and etc. Chitin and its main derivative chitosan have various applications in medicine, pharmacy, biotechnology, environment, and food engineering because of their nontoxicity, biodegradability, biocompatibility, antimicrobial, and antioxidant properties. Here, research was conducted on the removal of Acid Orange 12, which is among the most used azo dyes in textiles, from aqueous solutions using shrimp chitin, a polymer. To determine the most suitable conditions, different parameters (pH degrees, amount of chitin, amount of dye, contact time) were studied. Chitin was determined to be the most efficient in removing Acid Orange 12 using pH 5 conditions. The adsorption of dye onto chitin followed the Langmuir isotherm and pseudo-second-order kinetic model.

Keywords:

Arthropod, biopolymer, water, cleaning, environment.,

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