BAZI HOFMANN-Td-TİPİ KLATRATLARIN TİTREŞİM SPEKTROSKOPİSİ İLE İNCELENMESİ: Ni(1,9-DİAMİNONONAN)M(CN)4.2G (M = Cd VEYA Hg, G = 1,3-DİKLOROBENZEN)

Ni(1,9-diaminononan)M(CN)4.2G (M = Cd veya Hg, 1,9-diaminononan = danon, G = 1,3-diklorobenzen) genel formülüne sahip Hofmann-Td-tipi klatratlar toz halde hazırlanmakta ve bunların infrared ve Raman spektrumları sırasıyla (4000–200) cm-1 ve (2850–1650) cm-1 aralıklarında incelenmektedir. Spektrum sonuçları bu bileşiklerin yapısal olarak Hofmann-Td-tipi klatratlara benzediğini ortaya koymaktadır.

Anahtar Kelimeler:

Hofmann-Td-tipi klatrat; Titreşim spektrumu; 1, 9-diaminononan, 3-diklorobenzen

VIBRATIONAL SPECTROSCOPIC INVESTIGATION ON SOME HOFMANN-TdTYPE CLATHRATES: Ni(1,9-DIAMINONONANE)M(CN)4.2G (M = Cd OR Hg, G = 1,3-DICHLOROBENZENE)

New Hofmann-Td-type clathrates in the general form of Ni(1,9-diaminononane)M(CN)4.2G (M = Cd or Hg, 1,9-diaminononane = danon, G = 1,3-dichlorobenzene) have been prepared in powder form and their FT-IR and Raman spectra have been reported in the range of (4000–200) cm-1 and (2850–1650) cm-1, respectively. The spectral results suggest that these compounds are similar in structure to the Hofmann-Td-type clathrates.New Hofmann-Td-type clathrates in the general form of Ni(1,9-diaminononane)M(CN)4.2G (M = Cd or Hg, 1,9-diaminononane = danon, G = 1,3-dichlorobenzene) have been prepared in powder form and their FT-IR and Raman spectra have been reported in the range of (4000–200) cm-1 and (2850–1650) cm-1, respectively. The spectral results suggest that these compounds are similar in structure to the Hofmann-Td-type clathrates.

Keywords:

Hofmann-Td-type clathrate, Vibrational spectrum 1, 9-diaminononane, 3-dichlorobenzene,

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