Cengiz Yenikaya, Mustafa Demir, Halil İlkimen

2-AMİNOMETİLPİRİDİN ESASLI YENİ OKSİM BİLEŞİĞİ İLE METAL KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

(1Z,2E)-N-hidroksil-(2-hidroksiimino)-N’-(piridin-2-ilmetil) propanimidamid (H2L) ligandı, anti-monoklorglioksim ile 2-aminometilpiridinin reaksiyonundan elde edilmiş olup yapısı 1H-NMR, 13C-NMR, FT-IR, elementel analiz teknikleri kullanılarak aydınlatılmıştır. H2L ligandının Co2+, Ni2+ ve Cu2+ kompleksleri hazırlanarak FT-IR, elementel analiz, ICP-OES, manyetik duyarlılık ve iletkenlik metotları ile yapıları aydınlatılmaya çalışılmıştır.

Anahtar Kelimeler:

Glioksim, metal kompleksleri, 2-aminometilpiridin, vic-dioksim

SYNTHESIS AND CHARACTERIZATION OF A NOVEL OXIME COMPOUND OF 2-AMINOMETHYLPYRIDINE AND ITS METAL COMPLEXES.

(1Z,2E)-N'-hydroxy-2-(hydroxyimino)-N-(pyridin-2-yl)acetimidamide (H2L) is synthesized from the reaction between anti-monochloroglyoxime and 2-aminomethylpyridine and characterized by means of 1H-NMR, 13C-NMR, FT-IR, elemental analysis methods. Co2+, Ni2+ and Cu2+ complexes of H2L ligand were obtained and their structures were elucidated with FT-IR, elemental analysis, ICP-OES, magnetic susceptibility and conductivity studies.

Keywords:

Glyoxime, Metal Complexes, 2-Aminomethylpyridine, Vic-Dioxime,

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