Transesterification of palm oil over KOH/NaY zeolite in a packed-bed reactor

Transesterification of palm oil over KOH/NaY zeolite in a packed-bed reactor

The transesterification of palm oil to methyl ester was investigated on a KOH/NaY catalyst using a packed-bed reactor. The KOH/NaY was characterized by using XRD, nitrogen adsorption/desorption, SEM with EDS, CO2-TPD, and XRF. It was found that the KOH/NaY created strong basic sites, and the agglomeration was greatly increased by increasing the potassium content. The 15 wt % K/NaY exhibited good activity and the yield of FAME reached 92.18 % at 60 °C for 7 h. Additionally, the reusability of the catalyst was tested in order to observe deactivation of the catalyst from potassium leaching.

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  • A. Demirbas, “Progress and recent trends in biofuels”, Prog. Energy. Combus.t Sci., vol. 33, pp. 1–18,2007.
  • [2] L. Cui, G. Xiao, B. Xu, G. Teng, “Transesterification of cottonseed oil to biodiesel by using heterogeneous solid basic catalysts”, Energ. Fuel, vol. 21, pp. 3740– 3743, 2007.
  • W. Xie, H. Peng, L. Chen, “Transesterification of soybean oil catalyzed by potassium loaded on alumina as a solid-base catalyst”, Appl. Catal. A:Gen., vol. 300, pp. 67–74, 2006.
  • W. Xie, H. Li, ”Alumina-supported potassium iodide as a heterogeneous catalyst for biodiesel production from soybean oil”, J. Mol. Catal. A-Chem., vol. 255, pp. 1–9, 2006.
  • G. Arzamendi, I. Campo, E. Arguinarena, M. Sanchez, M. Montes, L.M. Gandia, “Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts: Comparison with homogeneous NaOH”, Chem. Eng. J., vol. 134, pp. 123–130, 2007.
  • X. Li, G. Lu, Y. Guo, Y. Guo, Y. Wang, Z. Zhang, X. Liu, Y. Wang, “A novel solid superbase of Eu2O3/Al2O3 and its catalytic performance for the transesterification of soybean oil to biodiesel”, Catal. Commun., vol. 8, pp.1969–1972, 2007.
  • H.J. Kim, B.S. Kang, M.J. Kim, Y.M. Park, D.K. Kim, J.S. Lee, K.Y. Lee, “Transesterification of vegetable oil to biodiesel using heterogeneous base catalyst”, Catal. Today, vol. 93–95, pp. 315–320, 2004.
  • G.J. Suppes, M.A. Dasari, E.J. Doskocil, P.J. Mankidy, M.J. Goff, “Transesterification of soybean oil with zeolite and metal catalysts”, Appl. Catal. A:Gen., vol. 257, pp. 213–23, 2004.
  • W. Xie, X. Huang, H. Li, “Soybean oil methyl esters preparation using NaX zeolites loaded with KOH as a heterogeneous catalyst”, Bioresour. Technol., vol. 98, pp. 936–939, 2007.
  • D.M. Alonso, R. Mariscal, R. Moreno-Tost, M.D.Z. Poves, M.L. Granados, “Potassium leaching during triglyceride transesterification using K/ -Al2O3 catalysts”, Catal. Commun., vol. 8, pp. 2080–2086, 2007.
  • C.S. MacLeoda, A.P. Harvey, A.F. Lee, K. Wilson, “Evaluation of the activity and stability of alkali-doped metal oxide catalysts for application to an intensified method of biodiesel production”, Chem. Eng. J., vol. 135, pp. 63–70, 2008.
  • K. Noiroj, P. Intarapong, A. Luengnaruemitchai, S. Jai- In, “A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil”, Renew. Energy, vol. 34, pp. 1145–1150, 2009.
  • D. Barthomeuf, “Acidity and Basicity in zeolites”, Stud. Surf. Sci. Catal., vol. 65, pp. 157–169, 1991.
  • Y. Wang, W.Y. Huang, Y. Chun, J.R. Xia, J.H. Zhu, “Dispersion of potassium nitrate and the resulting strong basicity on zirconia”, Chem. Mater., vol. 13, pp. 670– 6777, 2001.
  • J. Zhu, Y. Chun, Y. Wang, Q. Xu, “Attempts to create new shape-selective solid strong base catalysts”, Catal. Today, vol. 51, pp. 103–11, 1999.
  • G. Madhavi, S.J. Kulkarni, K.V.V.S.B.S.R. Murthy, V. Viswanathan, K.V. Raghavan, “Side-chain alkylation of 4-picoline with formaldehyde over alkali-modified zeolites”, Appl. Catal. A:Gen., vol. 246, pp. 265–282, 2003.
  • F. Yagi, N. Kanuka, H. Tsuji, H. Kita, H. Hattori, ”Preparation of basic zeolite”, Stud. Surf. Sci. Catal., vol. 90, pp. 349–354, 1994.
  • Choudhary, S.A.R. Mulla, B.S. Uphade, ”A novel method for measuring base strength distribution on basic solid catalysts under operating conditions”, Fuel, vol. 78, pp. 427–437, 1999.
  • S. Ku , M. Otremba, A. Tórz, M. Taniewski, ”Further evidence of responsibility of impurities in MgO for variability in its basicity and catalytic performance in oxidative coupling of methane”, Fuel, vol. 81, pp. 1755– 1760, 2002.
  • Istadi, N.A.S. Amin, “Synergistic effect of catalyst basicity and reducibility on performance of ternary CeO2-based catalyst for CO2 OCM to C2 hydrocarbons”, J. Mol. Catal. A-Chem., vol. 259, pp. 61–66, 2006.
  • M.D. Serio, M. Ledda, M. Cozzolino, G. Minutillo, R. Tesser, E. Santacesaria, “Transesterification of soybean oil to biodiesel by using heterogeneous basic catalysts”, Ind. Eng. Chem. Res., vol. 45, pp. 3009–3014, 2006.
  • M. Brazlauskas, S. Kitrys, “Synthesis and properties of CuO/Zeolite sandwich type adsorbent-catalysts”, Chin. J. Catal., vol. 29, pp. 25–30, 2008.
  • H. Imahara, E. Minami, S. Hari, S. Saka, “Thermal stability of biodiesel fuel as prepared by supercritical methanol process”, 2nd Joint International Conference on Sustainable Energy and Environment (SEE 2006), Bangkok, Thailand, pp. 21–23, November 2006.
  • G. Li, S.C. Larsen, V.H. Grassian, “An FT-IR study of NO2 reduction in nanocrystalline NaY zeolite: Effect of zeolite crystal size and adsorbed water”, Catal. Letters, vol. 103, pp. 1–2, 2005.