Gold and Silver Bimetallic Core-shell Nanoparticles with a Polydopamine Interface as an Ideal Catalytic Nanosystem

Çekirdek-kabuk nanopartikül sistemler esnek ve sıradışı özellikleri ile başta katalitik dönüşüm olmak üzere farklı alanlarda kullanılmaktadır. Fakat, bu nanosistemleri üretmek için basit, düşük maliyetli ve yenilikçi stratejiler sınırlı sayıda olup, etkin çekirdek-kabuk nanoyapılar yüksek oranda talep görmektedir. Bu çalışmada ince bir polidopamin (PDOP) tabakası ile oluşturulan bimetalik altın ve gümüş çekirdek-kabuk nanosistemin üretimini önermekteyim. PDOP tabakası bir ara tabaka olarak indirgeme ve stabilize ajan olarak etkin bir performans sunmuştur. Bimetalik çekirdek-kabuk sistemin üretimi elektron mikroskop görüntüleri ve UV-vis absorpsiyon spektrası ile doğrulanmıştır. Nanoyapıların katalitik aktivite testleri, 4-nitrofenolün (4-NP) 4-aminofenole (4-AP) indirgenmesi, çekirdek-kabuk sisteminin tepkimenin ilerlemesini arttırdığı gösterilmiştir. Ayrıca, gümüş indirgeme süresinin önerilen nanosistemin katalitik performansı üzerinde önemli etkiye sahip olduğu gözlenmiştir. 60 dakika gümüş indirgeme süresi için 4-NP’nin 4-AP’ye tamamen dönüşümünün sadece 20 dakikada gerçekleştiği görülmüştür.

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