Gülsen ASMAN, Gülşen TAŞKIN ÇAKICI, Ebru KONDOLOT SOLAK, Kannan SİVAPRAKASAM

Use of Ultrasound to Prepare Permeable Crosslinked PVA Membranes

The major topic covered in this paper is the application of ultrasound to crosslinked- poly(vinyl alcohol) (c-PVA) membranes as a novel, simple, eco-friendly, green-method to enhance the reduced permeabilities of c-PVA membranes due to crosslinking. The effect of sonication on the swelling and diffusion behaviors of c-PVA membranes was compared with that of the additive added crosslinked composite membranes, for which n-SiO2 and n-Ag were used as nanofillers. Aqueous solutions of rhodamine-b (RB) and Fe3+ were used to determine the permeation characteristics of the membranes. By the study, it was determined that although the presence of n-Ag and also n-SiO2 increased the hydrophilicity and the permeation capability of the c-PVA membranes, ultrasonication (US) was found to be more effective, eco-friendy method to promote the permeation characteristics of the membranes.

Keywords:

Green chemistry, ultrasound membrane PVA, n-SiO2, n-SiO2, n-Ag,

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