Nurşah KÜTÜK, Filiz BORAN, Sevil CETINKAYA GÜRER

Mor lahana özütü kullanarak grafen oksitin indirgenmesi ve oksidasyon ile fotokatalitik aktivitesinin incelenmesi

Grafen pek çok eşsiz sayılabilecek özelliğe sahip, fotokatalitik bozunum ve adsorpsiyon uygulamalarında potansiyeli olan önemli bir malzemedir. Grafen elde etmek için grafen oksitin (GO) indirgenmesi tekniği son yıllarda sıkça kullanılan ilgi çekici bir yöntemdir. Bu çalışmanın amacı kolay ve etkili bir yöntem olan yeşil sentez ile mor lahana sulu özütü kullanarak GO indirgenmesi ve fotokatalitik giderim uygulamalarında kullanımının incelenmesidir. Sentezleme koşullarını optimize etmek için reaksiyon sıcaklığı 25, 50 ve 100 ⁰C’de ve reaksyon süresinin etkisi ise 1, 2, 4 ve 6 saat için incelendi. XRD, FTIR, UV/vis ve SEM sonuçlarına göre 100 ⁰C reaksiyon sıcaklığı ve 6 saat reaksiyon süresi GO’nun indirgenmesi için uygun deneysel şartlar olarak bulundu. Elde edilen indirgenmiş grafen oksit (IGO) organik ve katyonik bir boya olan metilen mavisinin (MM) sulu çözeltisinde UV lamba altında fotokatalitik bozunum deneylerinde kullanıldı. Çalışmanın bu kısmında hidrojen peroksitin (H2O2) fotokatalitik bozunum süreci üzerindeki etkisi araştırıldı. Sonuçlar 120 dakika sonunda IGO’nun sulu çözeltiden MM’yi %85 oranında giderdiğini gösterdi.

Anahtar Kelimeler:

İndirgenmiş grafen oksit, yeşil sentez, metilen mavisi, fotokatalitik bozunum

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