Selahattin YILMAZ, Emine KILIÇ, Ali Osman SOLAK, Nilgün SEÇKEN

Electrochemical behavior of I-nitrobenzo[c]cinnoline on platinum electrode

l-nitrobenzo[c]cinolin sentezlendi ve elektrokimyasal davranışı incelendi. Bu bileşiğin asetonitril-tetrabutilamonyum perklorat (TBAP) sisteminde platin elektrotda indirgenme ve yükseltgenme davranışları dönüşümlü voltametri tekniğiyle araştırıldı ve uygun indirgenme mekanizmaları önerildi, indirgenme ve yükseltgenme reaksiyonlarının heterojen hız sabitleri bulundu. Ayrıca bu bileşiğin platin elektrotta adsorpsiyon özelliği de incelendi.

I-nitrobenzo[c]cinolinin platin elektrotta elektrokimyasal davranışlarının incelenmesi

1-nitrobenzo[c]cinnoline was synthesized and its electrochemical behaviour was investigated. Reduction and oxidation on a platinum electrode in acetonitrile + tetrabutylammonium perchlorate (TBAP) system were studied by using cyclic voltammetry and suitable mechanisms were proposed. Heterogeneous rate constants were determined for reduction and oxidation reactions. Adsorption characteristics of this compound on a platinum electrode was also investigated.

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