Mehmet KAYA, Erdal CANPOLAT, Fatih KÖMÜRLÜ

1-[1,2-bis (hidroksiamino) etil]-4-metilpiperidin ligandının sentezi karakterizasyonu ve metal komplekslerinin incelenmesi

Bu çalışmada, l-[l,2-bis(hidroksiamino)etil]-4-metilpiperidin (LH2) ligandı ve bu ligandın Co(II), Ni(II) ve Cu(II) iyonları ile metal:ligand oranı 1:2 olan mononukleer kompleksleri sentezlendi. Komplekslerin 6 koordinasyonlu oktahedral yapıya sahip olduğu belirlendi. Bunların yapıları, elementel analiz, IR, 1H-, 13C-NMR spektroskopisi ve manyetik duyarlılık ile aydınlatıldı. Ayrıca ligand ve komplekslerin termal özellikleri TGA teknikleriyle karakterize edildi.

Synthesis and characterization of 1-[1,2-bis (Hidroksiamino) etil]-4-metilpiperidin ligand and investigation of its metal complexes

In this study, l-[l,2-bis(hydroxyamino)ethyl]-4-methylpiperidine (LH2) ligand and its Co(II), Ni(II) and Cu(II) complexes were synthesized. All complexes have a metal :ligand ratio of 1:2. The complexes have been octahedral geometry. The structure of the ligand and its complexes are proposed and formulated used on the elemental analyses, IR, 1H-, 13C-NMR spectroscopy and magnetic susceptibility. Using TGA techniques also carried out the thermal characterizations of ligands and their complexes.

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