Direct Blue 2 Tekstil Boyar Maddesinin Agaricus campestris Biyokütlesi Tarafından Biyosorpsiyonu: Kinetik, İzotermal ve Termodinamik Çalışmalar

Bu çalışmada, Direct Blue 2 (DB2) tekstil boyar maddesinin Agaricus campestris’ten elde edilen biyosorbent ile sulu çözeltilerden giderimi çalışılmıştır. Biyosorpsiyona pH, sıcaklık, başlangıç DB2 derişimi ve biyosorbent miktarı gibi parametrelerin etkisi incelenmiştir. Optimum pH’ın 6.0 olarak tespit edildiği koşullarda 100 mg L-1 başlangıç DB2 derişimi ve 0.01 g biyosorbentin kullanıldığı koşullarda maksimum biyosorpsiyon kapasitesi 38.56 mg g-1, 0.2 g biyosorbentin kullanıldığı koşullarda ise % tutunma miktarının % 93.39 olarakbulunmuştur. Elde edilen sonuçlara göre biyosorpsiyonun Freundlich izoterm modeline ve yalancı-ikinci derece kinetik modele uygun olduğu rapor edilmiştir. Son olarak, biyosorpsiyon mekanizması için termodinamik parametreler (standart serbest enerji, standart entalpi ve standart entropi) belirlenmiştir

Anahtar Kelimeler:

Agaricus campestris, Direct Blue 2, biyosorpsiyon, biyosorbent

Direct Blue 2 Textile Dye Biosorption by Agaricus campestris Biomass: Kinetic, Isotherm and Thermodynamic Studies

In this work, the biosorption of Direct Blue 2 (DB2) textile dye from aqueus solution were studied by biosorbent which were obtained from Agaricus campestris. The effect of pH, temperature, initial DB2 concentration and amount of biosorbent were investigated. When 100 mg L-1 initial concentration of DB2 and 0.01 g of biosorbent were used, the maximum biosorption capacity was determined as 38.56 mg g-1 under the optimum pH, which was determined as 6.0 and 0.2 g of biosorbent were used, the % removal was determined as 93.39 %. It was reported as, biosorption process was fitted Freundlich isotherm model and pseudo-second order kinetic model. In addition, the thermodynamic parameters (such as standard free energy, standard enthalpy, and standard entropy) were determined.

Keywords:

Agaricus campestris, Direct Blue 2, biosorption, biosorbent,

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