Structural and Morphological Properties of CuInS2 Polycrystalline Films Obtained By Spray Pyrolysis Method

CuInS2 yarıiletken filimleri püskürtme yöntemiyle cam tabanlar üzerine üç farklı taban sıcaklıklarında elde edilmiştir. X-ışını kırınım desenlerinden filmlerin chalcopyrite ve polikristal yapıda olduklarını saptanmıştır. Yapılanma katsayısı farklı taban sıcaklıkları için değerlendirilmiştir. SEM yüzey analizleri sıcaklığa bağlı olarak yüzey taneciklerinde farklı morfolojiler göstermiştir.CuInS2 semiconductor films were prepared at three substrate temperatures on glass substrates by spray pyrolysis method. The X-rays diffraction (XRD) spectra of the films have shown that the films produced are polycrystalline and chalcopyrite in structure. The texture coefficients were evaluated for different substrate temperatures. Scanning electron microscopy (SEM) surface micrographs show different morphologies of the surface grains, which are dependent on temperature.

Anahtar Kelimeler:

CuInS2, Chalcopyrite, Püskürtme Yöntemi, X-Işını Kırınımı, Yapılanma Katsayısı, SEM, Taban Sıcaklığı

Structural and Morphological Properties of CuInS2 Polycrystalline Films Obtained By Spray Pyrolysis Method

Keywords:

-,

PDF

___

Afify, H.H, Nasse, S.A. and Demian, S.E., Influence of Substrate Temperature on The Structural, Optical and Electrical Properties of ZnO Thin Films Prepared by Spray Pyrolysis, J. of Mater. Sci., 2 (1991), pp.152-156.
Aksay, S., The Films The Compound Semiconductors are Produced by Spray Pyrolysis, Anadolu University Journal of Faculty of Science, 5 (2001), pp.147-156.
Aksay, S. and Zor, M., AC Electrical Properties of Cu(Zn,Cd)InS2 Films Produced by The Spray Pyrolysis Method’, Anad. Uni. J. Sci. and Tech., 4, 1 (2003), pp.35-38.
Altıokka, B. and Aksay, S., Optical Properties of CuInS2 Films Produced by Spray Pyrolysis Method, Journal of Arts and Sciences, 3 (2005), pp.27-34.
Antony Aldrin, A.S. Asha, Rahana Yoosuf, R. Manoj, M.K. Jayaraj, Growth of CuInS2 Thin Films by Sulphurization of Cu-In Alloys, Solar Energy Materials & Solar Cells, 81 (2004), pp.407-417.
Bandyopadhyaya, S., Chaudhuri, S., Pal, A.K., Synthesis of CuInS2 Films by Sulphurization of Cu/In Stacked Elemental Layers, Solar Energy Materials & Solar Cells, 60 (2000), pp.323-339.
Bihri, H. and Abd-Lefdil, M., Effect of An Initially Sulphurich Sprayed on CuInS2 Thin Films, Thin Solid Films, 354 (1999), pp.5-8.
Br.Patent 632256 to H.A.Mc Masters Lebley Owers Ford Glass Co., (1942).
Chamberlin, R.R., Skarman, J.S., Chemical Spray Deposition Process for Inorganic Films, J. Electrochem. Soc., 113 (1966), pp.86-89.
Christopher V. Kelly, Michael H. C. Jin, Kulbinder K. Banger, Jeremiah S. McNatt, John E. Dickman, Aloysius F. Hepp, Parametric Study on Non-vacuum Chemical Vapor Deposition of CuInS2 from a Single-source Precursor, Materials Science and Engineering B 116 (2005), pp.403-408.
Falcony, C., Garcia, M., Ortiz, A. and Alonso, J.C., Luminescent Properties of ZnS: Mn Films Deposited by Spray Pyrolysis, J. Appl. Phys.72 (1992), pp.4.
Guha, P., Das, D., Maity, A.B., Ganguli, D., Chaudhuri, S., Synthesis of CuInS2 by Chemical Route: Optical Characterization, Solar Energy Materials & Solar Cells, 80 (2003), pp.115-130.
Guillen, C., Kerrero, J., Gutierrez, M., Briones, F., Structure, Morphology and Optical Properties of CuInS2 Thin Films Prepared by Modulated Flux Deposition, Thin Solid Films, 480-481 (2005), pp.19-23.
He, Y.B., Kramer, T., Polity, A., Gregor, R., Kriegseis, W., Österreicher, D., Hasselkamp,, Meyer, B.K., Preparation and Characterization of Highly (112)-oriented CuInS2 Films Deposited by a One-stage RF Reactive Sputtering Process, Thin Solid Films, 431-432 (2003), pp.231-236.
Hou, Xianghui and Choy Kwang-Leong, Synthesis and characteristics of CuInS2films for photovoltaic applications, Thin Solid Films, 480-481 (2005), pp.13-18.
Joseph, B., Gopchandran, K.G., Thomas, P.V., Koshy, P., Vaidyan, V.K., A Study on The Chemical Spray Deposition of Zinc Oxide Thin Films and Their Structural and Electrical Properties, Materials Chemistry and Physics, 58 (1999), pp.71-77.
Kanzari, M. and Rezig, B., Effect of Deposition Temperature on The Optical and Structural Properties of as- deposited CuInS2Films, Semicond. Sci. Technol., 15 (2000), pp.335-340.
Kijatkina, O., Krunks, M., Mere, A., Mahrov, B., Dloczik, L., CuInS2 Sprayed Film on Different Metal Oxide Underlayers, Thin Solid Films, 431-432 (2003), pp.105-109.
Krunks, Malle, Olga Bijakina, Tiit Varema, Valdek Mikli, Enn Mellikov, Structural and Optical Properties of Sprayed CuInS2Films, Thin Solid Films, 338 (1999), pp.125-130.
Krunks, M., V. Mikli, O. Bijakina, H. Rebane, A. Mere, T. Varema, E. Mellikov, Composition and Structure of CuInS2Films Prepared by Spray Pyroysis, Thin Solid Films, 361-362 (2000), pp.61-64.
Krunks, M., Kijatkina, O., Rebane, H., Oja, I., Mikli, V., Mere, A., Composition of CuInS2Thin Films Prepared by Spray Pyroysis, Thin Solid Films, 403-404 (2002), pp.71-75.
Krunks, M., Kijatkina, O., Mere, A., Varema, T., Oja, I., Mikli, V., Sprayed CuInS2Film Grown Under Cu-rich Conditions as Absorbers for Solar Cells, Solar Energy Materials & Solar Cells, 87 (2005), pp.207-214.
Lampkin, Curt M., Aerodynamics of Nozzles Used in Spray Pyrolysis, Prog. Crystal Growth Charact., 1 (1979), pp.406-416.
Marsillac, S., Zouaghi, M. C., Bernede, J. C., Ben Nasrallah, T., Belgacem, S., Evolution of The Properties of Spray-deposited CuInS2Thin Films with Post-annealing Treatment, Solar Energy Materials & Solar Cells, 76 (2003), pp.125-134.
Martinez, A.M., Arriaga, L.G., Fernandez, A.M., Cano, U., Band Edges Determination of CuInS2 Thin Films Prepared by Electrodeposition, Materials Chemistry and Physics, 88 (2004), pp.417-420.
Nasser, S.A., Afify, H.H., El-Hakim, S.A., Zayed, M.K., Structural and Physical Properties of Sprayed Copper-Zinc Oxide Films, Thin Solid Films, 315 (1998), pp.327-335.
Nunes, P., Fortunate, E., Tonello, P., Braz Fernandes, F., Vilarinho, P. and Martins, R., Effect of Different Dopant Elements on The Properties of ZnO Thin Films, Vacuum 64 (2002), pp.281-285.
Oja I., M. Nanu, A. Katerski, M. Krunks, A.Mere, J. Randoja, A. Goossens, Crystal Quality Studies of CuInS2 Films Prepared by Spray Pyrolysis, Thin Solid Films, 480-481 (2005), pp.82-86.
Ortega-Lopez Mauricio, Arturo Morales-Acevedo, Characterization of CuInS2 Thin Films for Solar Cells Prepared by Spray Pyrolysis, Thin Solid Films, 330 (1998), pp.96-101.
Pathan, H.M. and Lokhande, C.D., Chemical Deposition and Characterization of Copper Indium Disulphide Thin Films, Applied Surface Science, 239 (2004), pp.11-18.
Zor, M., Aksay, S., Kul, M. and Aybek, A.Ş., DC and AC Properties of The Compound Semiconductors Prepared by Spray Pyrolysis, Balkan Phys. Lett., 5 (1997), pp.1132-1135.
Zouaghi, M.C., T. Ben Nasrallah, S. Marsillac, J.C. Bernede, S.Belgacem, Physico-chemical Characterization of Spray-deposited CuInS2 Thin Films, Thin solid Films, 382 (2001), pp.39-46.
Xiao, J., Xie, Y., X., Tang, R., and Qian, Y., Synthesis and Characterization of Ternary CuInS2 Nanorods via a Hydrothermal Route, J. of Solid State Chemistry, 161 (2001), pp.179-183.