High-temperature oxidation behavior of boron carbide

High-temperature oxidation behavior of boron carbide

The aim of this study is to determine the cyclic oxidation behavior of boron carbide (B4C) in the air atmosphere at elevated temperatures. For this purpose, as-received B4C powders were characterized by XRD and SEM and then shaped by the cold pressing method for oxidation studies. Tests were performed in the air atmosphere at 800˚C and 1000˚C for 5, 10, 15 and 20 hours. Oxidation behavior of the samples was evaluated by weight changes. XRD, SEM and EDS analyses were also conducted on the oxidized samples. It was observed that cyclic oxidation behaviors of the samples depended on temperature and time. Based on the analyses results and the microstructure observations, volatilization of B2O3 had a significant effect on the oxidation of the samples as the temperature increased.

___

  • Hou X., Chou K. C., Quantitative investigation of oxidation behavior of boron carbide powders in air, J. Alloys. Compd., 573, 182–186, 2013.
  • Lavrenko V. A., Gogotsi Y. G., Influence of oxidation on the composition and structure of the surface layer of hot-pressed boron carbide, Oxid. Met., 29 (3/4), 193202, 1988.
  • Thévenot F., Boron carbide a comprehensive review, J. Eur. Ceram. Soc., 6, 205-225, 1990.
  • Kılıçarslan A., Toptan F., Kerti I., Piskin S., Oxidation of boron carbide particles at low temperatures, Mater. Lett., 128, 224–226, 2014.
  • Frage N., Levin L., Dariel M. P., The effect of the sintering atmosphere on the densification of B4C ceramics, J. Solid State Chem., 177, 410–414, 2004.
  • Erdemir A., Bindal C., Zuiker C., Savrun E., Tribology of naturally occurring boric acid films on boron carbide, Surf. Coat. Technol., 86-87, 507-510, 1996.
  • Li Y. Q., Qiu T., Oxidation behaviour of boron carbide powder, Mater. Sci. Eng. A, 444, 184–191, 2007.
  • Steinbrück M., Oxidation of boron carbide at high temperatures, J. Nucl. Mater., 336, 185–193, 2005.
  • Lavrenko V. A., Pomytkin A. P., Kislyj P. S., Grabchuk B. L., Kinetics of high-temperature oxidation of boron carbide in oxygen, Oxid. Met, 10 (2), 85-95, 1976.
  • Litz L. M., Mercuri R. A., Oxidation of boron carbide by air, water, and air-water mixtures at elevated temperatures, J. Electrochem. Soc., 110 (8), 921-925, 1963.
  • Lee D. B., Lee Y. C., Kim D. J., The oxidation of TiB2 ceramics containing Cr and Fe, Oxid. Met, 56, 177189, 2001.
  • Parthasarathy T. A., Rapp R. A., Opeka M., Kerans R. J., A model for the oxidation of ZrB2, HfB2 and TiB2, Acta Mater., 55, 5999–6010, 2007.
  • Irving R. J., Worsley I. G., The oxidation of TiB2 and ZrB2 at high temperatures, J. Less-Common Met., 16, 103-112, 1968.
  • Turkdoğan E.T., Physical chemistry of high temperature technology, Academic Press, 1980.
  • Kofstad P, High temperature oxidation corrosion, England: Elsevier Applied Science Publishers, 1998.