Doğal biyosorbent olarak Onopordum turcicum Danin tarafından sulu çözeltiden toksik bir bazik boya-malakit yeşili uzaklaştırılması

Bu çalışmada doğal kaynaklı olan Onopordum turcicum Danin bitkisi adsorban olarak kullanarak, Malakit yeşil MG boyasının solu ortamdan uzaklaştırılması çalışılmıştır. Bitkinin potansiyel MG boya uzaklaştırma özelliklerini araştırmak amacıyla, pH, adsorban miktarı, temas süresi ve başlangıç MG konsantrasyonu gibi değişik parametrelere göre değerlendirilmiştir. MG boyasının O. turcicum biyokütle tarafından adsorlanan en etkin pH’sı 8.0 olarak tespit edildi. Adsorpsiyon izotermi ise Langmuir ve Freundlich adsopsiyon modeli kullanılarak analiz edildi. Langmuir izotermine göre adsopsiyon kapasitesi 1110.1 mg/g olarak bulundu. Elde edilen sonuçlara göre, O. turcicum bitkisinin MG boyasının sulu çözeltiden uzaklaştırabilme özelliğine sahip olduğu görülmektedir

Removal of a toxic basic dye-malachite green from aqueous solution by Onopordum turcicum Danin as natural biosorbent

Biosorption of malachite green MG was studies using natural origin adsorbent Onopordum turcicum Danin. Batch adsorption studies were carried out to evaluate the potentiality of O. turcicum for the removal of malachite green dye from wastewater, on different parameters such as pH, adsorbent dose, contact time and initial MG concentration. The effective pH was 8.0 for adsorption of MG by the biomass. The equilibrium isotherm was analyzed with the Langmuir and Freundlich models of adsorption. The biosorption data of MG on Onopordum turcicum Danin was fitted with Langmuir model with a maximum adsorption capacity was 1110.1 mg/g. The acquired results show that O. turcicum was effective in removal of MG dye from aqueous solution

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  • Ayed, L., Chaieb, K., Cheref, A., Bakhrouf, A. (2009). Biodegradation of triphenylmethane dye Malachite Green by Sphingomonas paucimobilis. World Journal of Microbiology and Biotechnology, 25, 705–711.
  • Baek, M.H., Ijagbemi, C.O., O, S.J., Kim, D.S. (2010). Removal of Malachite Green from aqueous solution using degreased coffee bean. Journal of Hazardous Materials. 176, 820–828.
  • Crini, G., Peindy, H.N., Gimbert, F., Robert, C. (2007). Removal of C.I. Basic Green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: Kinetic and equilibrium studies. Separation and Purification Technology. 53, 97–110.
  • Doğan, M.,Abak, H., M.A. (2009). Adsorption of methylene blue onto hazelnut shell: kinetics, mechanism and activation parameters. Journal of Hazardous Materials.164, 172–181.
  • Guari, E.B., Janaina, É., Almeida, R. De, Jesus, M. De, Martiarena, S., Yamagami, N.S., Corso, C.R. (2015). Azo Dye Acid Blue 29: Biosorption and Phytotoxicity Test. doi: 10.1007/s11270-015-2611-3
  • Haddad, M. E., Slimani, R., Mamouni, R., ElAntri, S., Lazar, S. (2013). Removal of two textile dyes from aqueous solutions onto calcined bones. Journal of the Association of Arab Universities for Basic and Applied Sciences. 14, 51–59.
  • Kannan, C., Muthuraja, K., Devi, M.R. (2013). Hazardous dyes removal from aqueous solution over mesoporous aluminophosphate with textural porosity by adsorption. Journal of Hazardous Materials 244–245, 10–20.
  • Kumar, K.V. (2007). Optimum sorption isotherm by linear and non-linear methods for malachite green onto lemon peel. 74, 595– 597.
  • Malik, R., Ramteke, D.S., Wate, S.R. (2007). Adsorption of malachite green on groundnut shell waste based powdered activated carbon. Waste Management. 27, 1129–1138.
  • Mittal, A., (2006). Adsorption kinetics of removal of a toxic dye, Malachite Green, from wastewater by using hen feathers. Journal of Hazardous Materials. 133, 196–202.
  • Muhammed J.Iqbal, M.N.A. (2007). Adsorption of dyes from aqueous solutions on activated charcoal. Journal of Hazardous Materials.139, 57–66.
  • Rahmat, N.A., Ali, A.A. (2016). Removal of Remazol Brilliant Blue R from Aqueous Solution by Adsorption Using Pineapple Leaf Powder and Lime Peel Powder. doi:10.1007/s11270-016-2807-1
  • Rajeshkannan, R., Rajasimman, M., Rajamohan, N. (2010). Removal of Malachite Green from Aqueous Solution using Hydrilla verticillata - Optimization, Equilibrium and Kinetic Studies 222–229.
  • Raval, N.P., Shah, P.U., Shah, N.K. (2016). Malachite green “a cationic dye” and its removal from aqueous solution by adsorption. Applied Water Science. doi:10.1007/s13201-016-0512-2
  • Robinson, T., Chandran, B., Nigam, P. (2002). Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw. Water Research. 36, 2824–2830.
  • S.D.Khattri, M.K.S. (2009). Removal of malathite green from dye wasterwater using neem sawdust by adsorption. Journal of Hazardous Materials. 167, 1089–1094.
  • Tsai, W.T., Chen, H.R. (2010). Removal of malachite green from aqueous solution using low-cost chlorella-based biomass. Journal of Hazardous Materials. 175, 844–849.
  • Vijayaraghavan, K., Premkumar, Y., Jegan, J. (2016). Malachite green and crystal violet biosorption onto coco-peat: characterization and removal studies. Desalination and Water Treatment. 57, 6423–6431.
  • Wang, L., Zhang, J., Zhao, R., Li, C., Li, Y., Zhang, C. (2010). Adsorption of basic dyes on activated carbon prepared from Polygonum orientale Linn: Equilibrium, kinetic and thermodynamic studies. Desalination. 254, 68–74
  • Wawrzkiewicz, M., Hubicki, Z. (2010). Weak Base Anion Exchanger Amberlite FPA51 as Effective Adsorbent for Acid Blue 74
  • Removal from Aqueous Medium – Kinetic and Equilibrium Studies. Separation Science and Technology. 45, 1076–1083.
  • Zhou, Q., Chen, F., Wu, W., Bu, R., Li, W., Yang, F. (2016). Reactive orange 5 removal from aqueous solution using hydroxyl ammonium ionic liquids/layered double hydroxides intercalation composites. Chemical Engineering Journal. 285, 198–206.
Biyolojik Çeşitlilik ve Koruma-Cover
  • ISSN: 1308-5301
  • Yayın Aralığı: Yılda 3 Sayı
  • Başlangıç: 2008
  • Yayıncı: Ersin YÜCEL