Mohamed A. HASSAAN, Murat YILMAZ, Ahmed EL NEMR

Acid Red 17, Acid Yellow 11, Direct Yellow 12, Direct Blue 86 ve Mordant Violet 40 Boyalarının Karışımını İçeren Suyun Arıtılması İçin Gelişmiş Oksidasyon İşlemi

Boyaların atık sudan uzaklaştırılması hem çevre hem de üreticiler için tekstil endüstrisindeki en büyük sorunlardan biridir. Bu makale, beş farklı boya (Asit Kırmızısı 17, Asit Sarısı 11, Doğrudan Sarı 12, Doğrudan Mavi 86 ve Mordan Menekşe 40) içeren sentetik atık su karışımını arıtmak için ultraviyole (UV) ile birlikte ozon (O3) ve O3 uygulama olasılığı farklı kromofor ve ankraj gruplarına sahip boyaların renk giderme etkinliği için incelemiştir. Temas süresi, optimum çalışma koşullarını elde etmek için UV ile kombine O3 veya O3 akışı altında bir kesikli reaktörde incelenmiştir. Sonuçlar, O3 uygulamasının UV destekli ozonlamadan daha etkili olduğunu göstermiştir. Bu karışımdaki her bir boyanın ileri oksidasyonu, aynı boyanın çözelti içinde ayrı ayrı çıkarılmasıyla karşılaştırıldı. Sonuçlar, boyayı karışımdan ve su çözeltisindeki tek boyayı çıkarmak için gereken sürede yalnızca küçük bir fark olduğunu kanıtlamıştır.

Anahtar Kelimeler:

Acid Red 17, Acid Yellow 11, Direct Yellow 12, Direct Blue 86, Mordant Violet 40, İleri oksidasyon

Advanced oxidation process for treatment of water containing mixture of Acid Red 17, Acid Yellow 11, Direct Yellow 12, Direct Blue 86 and Mordant Violet 40 dyes

The removal of dyes from wastewater is one of the biggest problems in the textile industry for both environment and manufacturers. This study examined the possibility of applying ozone (O3) and O3 in combination with ultraviolet (UV) to treat a mixture of synthetic wastewater containing five different dyes (Acid Red 17, Acid Yellow 11, Direct Yellow 12, Direct Blue 86 and Mordant Violet 40) for the decolorization efficiency of dyes with different chromophore and anchor groups. The contact time was studied in a batch reactor under the flow of O3 or O3 combined with UV to achieve optimal operating conditions. The results showed that the application of O3 was more effective than UV-assisted ozonation. The advanced oxidation of each dye in this mixture was compared with the removal of the same dye in the solution separately. The results proved that there is only a slight difference in the time required to remove the dye from the mixture and the single dye in the water solution.

Keywords:

Acid Red 17, Acid Yellow 11, Direct Yellow 12, Direct Blue 86, Mordant Violet 40, Advanced oxidation,

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