FATMA ESEN, AHMET EGEMEN SAKIN, Mehmet Ferhat SARİ

BURSA’DA TRAFİĞİN YOĞUN OLDUĞU BİR BÖLGEDE PASİF HAVA ÖRNEKLEYİCİ KULLANARAK POLİKLORLU BİFENİLLERİN (PCB’lerin) KONSANTRASYONLARININ MEVSİMSEL OLARAK BELİRLENMESİ

Bu çalışmada, trafiğin yoğun olduğu bir bölge olan Bursa Test ve Analiz Laboratuvarı’nda (BUTAL) Haziran 2008-Haziran 2009 tarihleri arasında pasif hava örnekleyici kullanılarak PUF Disk, XAD-2 Reçine ve Saf su medyalarında PCB’lerin konsantrasyon değerleri tespit edilmiştir. Bu kapsamda bir yıl boyunca bir aylık örnekleme periyotlarında hava örnekleri toplanmıştır. Ortalama atmosferik Ʃ61PCB konsantrasyonları PUF Disk, XAD-2 Reçine ve Saf su medyalarında sırasıyla 89±71, 56±92, 32±25 pg/m3 değerlerini almıştır. Ayrıca tüm medyalarda elde edilen PCB konsantrasyonlarının mevsimsel dağılımları yaz, sonbahar, kış ve ilkbahar mevsimlerinde sırasıyla, PUF Disk medyasında 146±93, 104±53, 40±19 ve 46, ±19 pg/m3, XAD-2 reçine medyasında 118±147, 15±6, 13±5 ve 56±53 pg/m3 ve son olarak Saf Su medyasında 34±37, 36±25, 35±24 ve 39±28 pg/m3 olarak hesaplanmıştır. Tüm medyalarda 3- ve 4- klorobifeniller (CB’ler) baskın homolog grup olarak bulunmuştur. Bu değerler daha önce benzer özelliğe sahip bölgelerde ve medyalarda yapılmış olan çalışmalarla benzerlik göstermektedir.

Anahtar Kelimeler:

yarı uçucu organik bileşikler, PCB, BUTAL

Seasonal determination of the concentrations of polychlorinated biphenyls (PCBs) using a passive air sampler in a region where traffic is intense in Bursa

In this study, the concentrations of PCBs were determined with PUF disk, XAD-2 Resin and Pure Water media using passive air sampler between June 2008 and June 2009 in the Bursa Test and Analysis Laboratory (BUTAL) which is an area with high traffic. The mean atmospheric Σ61PCB concentrations were 89±71, 56±92, 32±25 pg / m3 in the PUF disk, XAD-2 Resin and Pure Water media, respectively. In addition, the seasonal distributions of PCB concentrations in all media for summer, autumn, winter and spring seasons calculated as in the PUF Disc media 146±93, 104±53, 40±19 and 46, ±19 pg/m3, in the XAD-2 resin media 118±147, 15±6, 13±5 and 56±53 pg/m3 and finally in the Pure Water media 34±37, 36±25, 35±24 and 39±28 pg/m3, respectively. 3- and 4- chlorobiphenlys (CBs) was the dominant homolog group in all medias. These values are similar to those previously reported in similar regions and in media.

Keywords:

semi-volatile organic compounds PCB, BUTAL, passive air sampler,

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