İridoid and lignan glucosides from bellardia trixago (L.) all

İridoid and lignan glucosides from bellardia trixago (L.) all

Five iridoid glucosides aucubin (I), bartsioside (H), melampyroside (111), mus-saenoside (IV) and gardoside meathyl ester (V) as well as the lignan glucoside dehydrod-iconiferyl alcohol-4-O-ß-D-glucoside (VI) were isolated from the overground parts of Bellardia trixago. The structure elucidation of the isolated compounds (l-VI) was realized on the basis of spectral evidence (UV, IR, 1H and 13C NMR) and the results were confirmed by comparison of the isolated compounds with authentic samples on TLC.

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  • 1.Davis P H, Flora of Turkey and EastAegean Islands, Vol. 6, UniversityPress, Edinburgh 1982, pp: 768.
  • 2.Barrero A F, Sanchez J F, Cuenca F G.Dramatic variation in diterpenoids ofdifferent populations of Bellardiatrixago. Phytochemistry 27: 3676-8,1988.
  • 3.Bianco A, Guiso M, lavarone C, TrogoloC. Bartsioside, structure andconfiguration. Gazz Chim Ital 106:725-32, 1976.
  • 4.De Pascual-Teresa J, Caballero E,Caballero C, Medarde M, Barrero A F,Grande M. Trixagol, natural γ-cyclogeranyl from Bellardia trixago (L.)All. Tetrahedron Lett 37: 3491-4,1978.
  • 5.De Pascual-Teresa, J, Caballero E,Caballero C, Medarde M, Barrero A F,Grande M. Minor components with theγ-cyclogeranilgeraniol skeleton fromBellardia trixago (L.) All. Tetrahedron38: 1837-42, 1982.
  • 6.Rimpler H. Structure elucidation ofiridoidglycosides. Planta Med 33: 313-5, 1978.
  • 7.Salama O, Chaudhuri R K, Sticher O. Alignan glucoside from Euphrasiarostkoviana. Phytochemistry 20:2603-4, 1981.
  • 8.Çalış İ. Rhynchocorys stricta(Scrophulariaceae)’dan elde edileniridoit heterozitleri. Doğa TU Tıp ve EczD 13: 23-8, 1989.
  • 9.Ahn B Z, Pachaly P, Melampyroside,ein neue iridoid aus Melampyrumsylvaticum L. Tetrahedron 30: 4049-54, 1974.
  • 10.Takeda Y, Fujita T. Iridoid glucosides ofMelampyrum laxum. Planta Med 41:192-4, 1981.
  • 11.Damtoft S, Hansen S B, Jacobsen B,Jensen S R, Nielsen B J. Iridoidglucosides from Melampyrum.Phytochemistry 23: 2387-9, 1984.
  • 12.Bianco A, Passacantilli P, Righi G,Nicoletti M, Iridoid glucosides fromParentucellia viscosa. Phytochemistry24: 1843-5, 1985.
  • 13.Markham K. R, Terna B, Stanley R,Geiger H, Mabry T J. Carbon-13 NMRstudies of flavonoids III. Tetrahedron
Turkish Journal of Medical Sciences-Cover
  • ISSN: 1300-0144
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK