THE REMOVAL OF NICKEL IONS WITH WALNUT SHELL

THE REMOVAL OF NICKEL IONS WITH WALNUT SHELL

The present study was aimed at determining whether walnut shell would have acceptable adsorption efficiency for removing Ni (II) and thereby offer an effective and economical alternative to more expensive treatments. This paper describes the removal of Ni (II) ions from aqueous solutions containing 100 mg L-1of nickel using walnut shell. The effects of various parameters such as optimum adsorbent mass, contact time, pH of the medium were investigated. The maximum removal efficiency of 43.23% was obtained at a pH of 5.85 with a 5-min contact time for a 5 mg L-1solid-to-liquid ratio and an initial heavy metal concentration of 100 mg L-1. it can be concluded that walnut shell could be used as a low-cost and abundant source for the removal of Ni (II), and as an alternative to more costly materials such as ion-exchange resins and activated carbon. It is thought that it will be possible to make walnut shell modification studies in order to obtain higher increases in recovery efficiency.

___

  • Altun, T., Pehlivan E. (2012). “Removal of Cr(VI) from aqueous solutions by modified walnut shells.” Food Chemistry, Vol. 132, pp. 693-700.
  • Amari, T., Ghnaya, T., Abdelly, C. (2017). “Nickel, cadmium and lead phytotoxicity and potential of halophytic plants in heavy metal extraction.” South African Journal of Botany, Vol. 111, pp. 99-110.
  • APHA (2005), Standard methods for the examination of water and wastewater, American Public Health Association (ALPHA): Washington, DC, USA.
  • Cao, S.-J., Lin, X.-J., Fang, F., Zhang, T.-M., Hu, R.-Z. (2014). “A new absorbent by modifying walnut shell for the removal of anionic dye: Kinetic and thermodynamic studies.” Bioresource Techonology, Vol. 163, pp. 199- 205.
  • Çelebi, H., Gök, O. (2015). “Evaluation of lead adsorption.” International Journal of Environmental Research, Vol. 11, pp. 83-90.
  • El Samrani, A.G., Lartiges, B.S., Villieras, F. (2008). “Chemical coagulation of combined sewer overflow: Heavy metal removal and treatment optimization.” Water Research, Vol. 42, pp. 951-960.
  • Feizi, M., Jalali, M. (2015) “Removal of heavy metals from aqueous solutions using sunflower, potato, canola and walnut shell residues.” Journal of Taiwan Institute of Chemical Engineers, Vol. 54, pp. 125-136.
  • Ghaee, A., Shariaty-Niassar, M., Barzin, J., Zarghan, A. (2012). “Adsorption of copper and nickel ions on macroporous chitosan membrane: equilibrium study.” Applied Surface Science, Vol. 258, pp. 7732–7743.
  • Gupta V.K., Ali L. (2000). “Utilization of bagasse fly ash (a sugar industry waste) for the removal of copper and zinc from wastewater.” Separation and Purification Technology, Vol, 18, pp. 131-140.
  • Gupta V.K., Ali L. (2004). “Removal of lead and chromium from wastewater using bagasse fly ash – a sugar industry waste.” Journal of Colloid and Interface Science, Vol, 271, pp. 321-328.
  • Gupta, V.K., Jain, C.K., Ali, L., Sharma, M., Saini, V.K. (2003). “Removal of cadmium and nickel from wastewater using bagasse fly ash – a sugar industry waste.” Water Research, Vol. 37, pp. 4038-4044.
  • Kobielska, A.P., Howarth, J. A., Farha, K. O., Nayak, S.(2018). “Metal-organic frameworks for heavy metal removal from water.” Coordination Chemistry Reviews, Vol. 358, pp. 92-107.
  • Mangaleshwaran, L., Thirulogachandar, A., Rajasekar, V. Muthukumaran, C.,Rasappan, K. (2015). “Batch and fixed bed column studies on nickel (II) adsorption from aqueous solution by treated polyurethane foam.” Journal of the Taiwan Institute of Chemical Engineers, Vol. 55, pp. 112–118.
  • Mauchauffee, S., Meux, E. (2007). “Use of sodium decanoate for selective precipitation of metals contained in industrial wastewater.” Chemospher, Vol. 69, pp.763- 768.
  • Mohsen-Nia, M., Montazeri, P., Modarress H. (2007). “Removal of Cu2+ and Ni2+ from wastewater with a chelating agent and reverse osmosis processes.” Desalination, Vol. 217, pp. 276-281.
  • Ong, C.D., Kan, C.-C., Mae, S., Pingul-Ong, B., Daniel, M., de Luna, G. (2017). “Utilization of groundwater treatment plant (GWTP) sludge for nickel removal from aqueous solutions: Isotherm and kinetic studies.” Journal of Environmental Chemical Engineering, Vol. 5, pp. 5746-5753.
  • Raval, N.P., Shah, P.U., Shah, N.K. (2016). “Adsorptive removal of nickel(II) ions from aqueous environment: a review.” Journal of Environmental Management, Vol. 179, pp. 1–20.
  • Verma,V.K., Tewari, S., Rai, J.P.N. (2008). “Ion exchange during heavy metal bio-sorption from aqueous solution by dried biomass of macrophytes.” Bioresource Technolgy, Vol. 99, pp. 1932-1938.
  • Verma,V.K., Tewari, S., Rai, J.P.N. (2008). “Ion exchange during heavy metal bio-sorption from aqueous solution by dried biomass of macrophytes.” Bioresource Technolgy, Vol. 99, pp. 1932-1938.
  • Whang, S.X., Li, Z.Z., Tao, R.S. (2009). “Removal of chromium (VI) from aqueous solution using walnut hull.” Journal of Environmental Management, Vol. 90, pp.721- 729.
  • Zabihi, M., Ahmadpour, A., Asl, H. A. (2009). “Removal of mercury from water by carbonaceous sorbents derived from walnut shell.” Journal of Hazardous Materials, Vol, 167, pp. 230-236.