Vibrational spectra and assignments of cis- and trans-1, 4- polybutadiene

Vibrational spectra and assignments of cis- and trans-1, 4- polybutadiene

The Raman spectra of cis- and trans-1,4- polybutadiene were recorded in the region 100-4000 $cm^{-1}$ and its infrared spectra were also measured in the wave number range 200-4000 $cm^{-1}$. The spectra were completely analysed. Probable assignments to observed bands were made with the help of intensities and normal co-ordinate analysis. The calculated normal frequencies were in good agreement with the experimental ones.

___

  • 1. G. Zerbi and M. Gussoni Spectrochim Acta 22, 2111 (1966)
  • 2. S. Mohan and A.R . Prabhakaran, Proc. Indian Natn. Sci. Acad., 57, No.4, 1991, pp.553-556.
  • 3. D. Morero, F. Ciampelli and E. Mantica, Advances in Molecular Spectroscopy, (A. Mangini, Editor) vol 2, p.898. Pergamon Press, Oxford (1962).
  • 4. S. L. Hsu, W. H. Moore and S. Krimm J Appl Phys., 46, 4185 (1975).
  • 5. L. E. Sutton The Interatomic Bond Distances and Bond Angles in Molecules and Ions The Chemical Society, London (1968).
  • 6. J. H. Schachtschneider Tech Rep Shell Development Company Emeryville CA, USA, (1969).
  • 7. R. G. Synder and J. H. Schachtschneider Spectrochim Acta 19, 117 (1963)
  • 8. M. P. Srivastava, O. N. Singh and I. N. Singh Indian J Pure Appl Phys 7, 504 (1969).
  • 9. R. Zwarich, J. Smolarek and L. Goodman J Mol Spectrosc 38, 336 (1971).
  • 10. J. H. S. Green and D. J. Harrison Spectrochim Acta 32A, 1265 (1976)
  • 11. H. Tadokoro, T. Kitazawa, S. Nozakura and S. Murahashi Bull Chem Soc Japan 34,1209 (1961).
  • 12. G. Zerbi, M. Gussoni and F. Ciampelli Spectrochim Acta 32A, 301 (1967).
  • 13. I. L. Finar, Organic Chemistry, Vol 2 (Longman, England), 1975.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Determination of trace amounts of gold (III) using ethopropazine hydrochloride and isothipendyl hydrochloride: A spectrophotometric study

Mahaveer B. MELWANKI, Saraswati P. MASTI, Jaldappa SEETHARAMAPPA

Extraction Equilibria of Nicotinic Acid Using Alamine 300/Diluent and Conventional Solvent Systems

Aynur ŞENOL

Determination of Manganese and Iron in Magmatic Rocks After Ultrasonic Leaching by flame AAS

M. Hikmet ÖZKAN, Mehmet AKÇAY

Determination of the Protonation Constants of Some Substituted Salicylideneanilines by the Spectrophotometric Method in Ethanol-Water Mixtures

Esin CANEL, M. Abdülkadir AKAY, Esma KILIÇ, Fitnat KÖSEOĞLU

Determination of Cadmium by FAAS After Solid-Phase Extraction of its 1-Benzylpiperazinedithiocarbamate Complex on Microcrystalline Naphthalene

Hasan CESUR, Bekir BATI

Kinetic Spectrophotometric Determination of Nanogram Levels of Manganese (II) by Azo Dye -- Potassium Periodate -- 1,10-Phenanthroline System

Konstantin L. MUTAFTCHIEV

Electron Ionization Mass Spectrometric Studies of Homalicine tertraacetate, Dihydrohomalicine tetraacetate and Related Compounds

Muhammad Tahir HUSSAIN, Nasim Hasan RAMA

Automated Recognition of Ergogenic Aids Using Soft Independent Modeling of Class Analogy (SIMCA)

M. PRAISLER, J. Van BOCXLAER, A. De LEENHEER, D. L. MASSART

Kinetic spectrophotometric determination of nanogram levels of manganese (II) by azo dye-potassium periodate-1, 10-phenanthroline system

Konstantin L. MUTAFTCHIEV

Vibrational spectra and assignments of cis- and trans-1, 4- polybutadiene

P. NALLASAMY, P. M. ANBARASAN, S. MOHAN