Vibrational spectra and assignments of cis- and trans-1, 4- polybutadiene

ISSN: 1300-0527
Yayın Aralığı: Yılda 6 Sayı
Yayıncı: TÜBİTAK

The Raman spectra of cis- and trans-1,4- polybutadiene were recorded in the region 100-4000 $cm^{-1}$ and its infrared spectra were also measured in the wave number range 200-4000 $cm^{-1}$. The spectra were completely analysed. Probable assignments to observed bands were made with the help of intensities and normal co-ordinate analysis. The calculated normal frequencies were in good agreement with the experimental ones.

PDF

___

1. G. Zerbi and M. Gussoni Spectrochim Acta 22, 2111 (1966)
2. S. Mohan and A.R . Prabhakaran, Proc. Indian Natn. Sci. Acad., 57, No.4, 1991, pp.553-556.
3. D. Morero, F. Ciampelli and E. Mantica, Advances in Molecular Spectroscopy, (A. Mangini, Editor) vol 2, p.898. Pergamon Press, Oxford (1962).
4. S. L. Hsu, W. H. Moore and S. Krimm J Appl Phys., 46, 4185 (1975).
5. L. E. Sutton The Interatomic Bond Distances and Bond Angles in Molecules and Ions The Chemical Society, London (1968).
6. J. H. Schachtschneider Tech Rep Shell Development Company Emeryville CA, USA, (1969).
7. R. G. Synder and J. H. Schachtschneider Spectrochim Acta 19, 117 (1963)
8. M. P. Srivastava, O. N. Singh and I. N. Singh Indian J Pure Appl Phys 7, 504 (1969).
9. R. Zwarich, J. Smolarek and L. Goodman J Mol Spectrosc 38, 336 (1971).
10. J. H. S. Green and D. J. Harrison Spectrochim Acta 32A, 1265 (1976)
11. H. Tadokoro, T. Kitazawa, S. Nozakura and S. Murahashi Bull Chem Soc Japan 34,1209 (1961).
12. G. Zerbi, M. Gussoni and F. Ciampelli Spectrochim Acta 32A, 301 (1967).
13. I. L. Finar, Organic Chemistry, Vol 2 (Longman, England), 1975.