The second and third density virial coefficients of six Ar-Ne mixtures at $25.0^circ C$

ISSN: 1300-0527
Yayın Aralığı: Yılda 6 Sayı
Yayıncı: TÜBİTAK

In this paper we present a detailed experimental study of fractions, $ x_{Ar}$ = 0.0821, 0.2727, 0.3618, 0.5838, 0.7722 and 0.9049 at $25.0^circ C$. The pressures are measured with a dead - weight tester. The densities are determined from knowledge of the precise volume and weight measurement of the mixtures. Statistical analysis of the experimental data yielded very precise values for the second and third density virial coefficients. The second virial coefficients calculated with the least squares fitting method and corresponding to above argon mole fractions are $10^6B$ = 11.03, 9.16, 7.65, 1.83, -4.98 and -11.00 $m^3mole^{-1}$. Similarly the third virial coefficients are $10^{12}$ C = 272, 388, 458, 648, 849 and 1013 $m^6mole^{-2}$.

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1. Ö. KorfalI, Proceedings of ECOS'01, First International Conference on Applied Thermodynamics, Istanbul 2001, A. Öztürk and Y. Göğüş, ed., Volume 1, p.129.
2. J. Kestin, Y. Kobayashi and R.T. Wood, Physica 32, 1065 (1966).
3. A.Michels, H. Wijker and H.K. Wijker, Physica 15, 627 (1949).
4. A. Michels, T.Wassenaar and P. Louwerse, Physica 26, 539 (1969).
5. J.P. Vidosic, "Mechanics of Materials", Marks' Mechanical Engineers' Handbook, 6th ed. (McGraw-Hill, New York, 1964).
6. J. Brewer and G.W. Vaughn, J. Chem. Phys. 50, 2960 (1969).