İlknur BABAHAN, Hüseyin ANIL, Nursabah SARIKAVAKLI

75112

Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

In this study, the synthesis of a novel tetraoxime (LH4) derivative containing hydrazone side groups, and its transition metal complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine (GH2) with terephthaldialdehyde. Polymeric complexes with Ni(II) and Co(II) and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were isolated. Structural assignments were supported by a combination of 1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis (TGA), molar conductances, elemental analyses, and magnetic susceptibility.
Anahtar Kelimeler:

Tetraoximes, hydrazone, transition metal complexes

Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

In this study, the synthesis of a novel tetraoxime (LH4) derivative containing hydrazone side groups, and its transition metal complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported. The ligand was synthesized by reacting anti-glyoximehydrazine (GH2) with terephthaldialdehyde. Polymeric complexes with Ni(II) and Co(II) and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were isolated. Structural assignments were supported by a combination of 1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis (TGA), molar conductances, elemental analyses, and magnetic susceptibility.
Keywords:

Tetraoximes, hydrazone, transition metal complexes,

PDF
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

Bromination of 2,3-dihydrobenzobarrelene and synthesis of its mono- and dibromide derivatives: unexpected Wagner-Meerwein rearrangement on silica gel

Selçuk EŞSİZ, Mehmet Emin ŞENGÜL*, Ertan ŞAHİN, Arif DAŞTAN

Solidified floating organic drop microextraction and spectrophotometric determination of vanadium in water samples

Shayessteh DADFARNIA, Ali Mohammad Haji SHABANI, Akram MIRSHAMSI

In silico design of novel and highly selective lysine-specific histone demethylase inhibitors

Ebru Demet AKDOĞAN, Burak ERMAN, Kemal YELEKÇİ

Kinetic spectrophotometric determination of trace copper(II) ions by their catalytic effect on the reduction of brilliant cresyl blue by ascorbic acid

Halil İbrahim ULUSOY, Ramazan GÜRKAN, Mehmet AKÇAY

Antioxidant phenolics from Lobaria pulmonaria (L.) Hoffm. and Usnea longissima Ach. lichen species

Fadime ATALAY, Mesut Bünyami HALICI, Ahmet MAVİ, Ahmet ÇAKIR

Enantioselective Henry reaction catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand and Cu(II) ion

Gamze KOZ, Demet ASTLEY, Stephen Thomas ASTLEY

Constituents of Plantago major subsp. intermedia with antioxidant and anticholinesterase capacities

Ufuk KOLAK, Mehmet BOĞA, Emine Akalin URUŞAK, Ayhan ULUBELEN

Synthesis and antimicrobial activities of some bridged bis-benzimidazole derivatives

Hasan KÜÇÜKBAY, Ülkü YILMAZ, Nihat ŞİRECİ

Synthesis of new substituted 2,2-bis-(3,5-di-t-butyl-4-hydroxybenzyl)benzocycloalkanones, bromopropiophenones, and their alcohol analogs

Jabbar KHALAFY, Mehdi RIMAZ, Sara TAGHINEJHAD

Simultaneous determination of dopamine, uric acid, and folic acid by a modified $TiO_$2 nanoparticles carbon paste electrode

Hossein NAEIMI, Mohammad MAZLOUM ARDAKANI, Ali BENVIDI, Mohammad Ali SHEIKH MOHSENI, Hadi BEITOLLAHI