Suppression of interfering ions by using ionic liquid and micelle moieties inspectro uorimetric analysis of manganese

Eosin-Y exhibits high affinity and emission based spectral response to most of the major ions in watersamples.In the present study we performed selective spectro uorimetric analysis of manganese with eosin-Y in thepresence of potential interferents. We employed green chemistry reagents, ionic liquids (ILs) and two different micelles,to suppress the effect of conventional cations and anions on the response of eosin-Y. The experimental data revealedthat different test moieties caused enhanced analytical response to Mn2+. The highest analytical signal of eosin-Y wasobtained in the presence of Triton X-100 at a concentration of 2.0 103mol L1. Presence of the green chemistryreagents ILs enhanced the limit of quanti cation for Mn2+10-fold with respect to the IL-free moieties. The interferingeffects of the metal ions of Ca2+, Cu2+, Hg+, Hg2+, As5+, Li+, Al3+, Cr3+, Co2+, Ni2+, and the anionic groupswere completely suppressed in the presence of the ILs and micelles. Additionally, the tolerance limit of Na+and Zn2+ions increased 6-fold in the presence of IL and sodium dodecyl sulfate. The presented method did not use any harmfulconventional solvents and was employed successfully for the detection of Mn2+ions in real water samples.

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1.Gerber, G. B.; Leonard, A.; Hantson, P.Crit. Rev. Oncol. Hematol.2002,42, 25-34.
2.Seleim, M. M.; Abu-Bakr, M. S.; Hashem, E. Y.; El-Zohry, A. M.Can. J. Anal. Sci. Spect.2009,54, 93-101.
3.Zatta, P.; Lucchini, R.; Rensburg, S. J.; Taylor, A.Brain Res. Bull.2003,62, 15-17.
4.Dias, F. D.; Alves, L. S.; Santos, W. N. L.; David, J. M.; Ferreira, S. L. C.Anal. Lett.2009,42, 2206-2213.
5.Almeida, L. F.; Vale, M. G. R.; Dessuy, M. B.; Silva, M. M.; Lima, R. S.; Santos, V. B.; Diniz P. H. D.; Araujo,M. C. U.Talanta.2007,73, 906-912.
6.Sreenivasa, Rao, K.; Balaji, T.; Prasada, Rao, T.; Babu, Y.; Naidu, G. R. K.Spectrochim. Acta B.2002,57,1333-1338.
7.Weiss, H. V.; Kenis, P. R.; Korkisch, J.; Steffan, I.Anal. Chim. Acta.1979,104, 337-343.
8.Ruiz, M. C.; Rodriguez, M. H.; Perino, E.; Olsina, R. A.Latin Am. Appl. Res.2004,34, 23-27.
9.Beltagi, M.; Ismail, M. I.; Ghoneim, M. M.Am. J. Anal. Chem.2013,4, 197-206.
10.Ahrland, S.; Herman, R. G.Anal. Chem.1975,47, 2422-2426.
11.Shuhong, X.; Wang, C.; Zhang, H.; Sun, Q.; Wang, Z.; Cui, Y. J.Mater. Chem.2012,22, 9216-9221.
12.Liang, J.; Canary, J. W.Angew. Chem. Int. Ed.2010,49, 7710-7713.
13.Mao, X.; Su, H.; Tian, D.; Li, H.; Yang, R.ACS Appl. Mater. Interfaces2013,5, 592-597.
14.Gruppi, F.; Liang, J.; Bartelle, B.; Royzen, M.; Turnbull, D. H.; Canary, J. W.Chem. Commun.2012,48,10778-10780.
15.http://www.lifetechnologies.com/tr/en/home/references/molecular-probes-the-handbook/indicators-for-ca2-mg2-zn2-and-other-metal-ions.html.
16.Bakthavatsalam S.; Sarkar, A.; Rakshit, A.; Jain, S.; Kumar, A.; Datta, A.Chem. Commun. (Camb).2015,51,2605-2608.
17.Garca, E. A.; Fernandez, R. G.; Daz-Garca, M. E.Micropor. Mesopor. Mat.2005,77, 235-239.
18.Oter, O.; Aydogdu, S. J.Fluoresc.2011,21, 43-50.
19.Merrigan, L.; Bates, E. D.; Dorman, S. C.Chem. Commun.2000,20, 2051-2052.
20.Oter,O.; Sahin, G. S.Turk. J. Chem.2015,39, 395-411.
21.Oter, O.; Sabanci, G.; Ertekin, K.Sensor Letters2013,11, 1-9.
22.Ongun, M. Z.; Oter, O.; Sabanci, G.; Ertekin. K.; Celik, E.Sens. Actut. B-Chem. 2013,183, 11-19.
23.Matsumiya, H.; Kato, T.; Hiraide, M.Talanta.2014,119, 505-508.
24.Ros, A. P.; Hernandez-Fernandez, F. J.; Lozano, L. J.; Sanchez-Segado, S.; Ginesta-Anzola, A., Godnez, C.;Tomas-Alonso, F.; Quesada, J. M.J. Membr. Sci.2013,444, 469-481.
25.Rios, A. P.; Hernandez-Fernandez, F. J.; Alguacil, F. J.; Lozano, L. J.; Ginesta, A.; Garcia-Diaz, I.; Sanchez-Segado,S.; Lopez, F. A.; Godinez, C.Sep. Purif. Tech.2012,97, 150-157.
26.Wellens, S.; Vander Hoogerstraete, T.; Moller, C.; Thijs, B.; Luyten, J.; Binnemans, K.Hydrometallurgy2014,144, 27-33.
27.Whitehead, J. A.; Zhang, J.; Pereira, N.; McCluskey, A.; Lawrance, G. A.Hydrometallurgy2007,88, 109-120.
28.Regel-Rosocka, M.; Nowak, L.; Wisniewski, M.Sep. Pur. Tech. 2012,97, 158-163.
29.Regel-Rosocka, M.; Wisniewski, M.Hydrometallurgy2011,110, 85-90.
30.Cheng, D. H.; Chen, X. W.; Shu, Y.; Wang; J. H.Talanta2008,75, 1270-1278.
31.Kogelniga, D.; Stojanovica, A.; Jirsa, F.; Kornerb, W.; Krachlera, R.; Kepplera, B. K. Sep. Purif. Tech.2010,72,56-60.
32.Yanga, F.; Kubotaa, F.; Babaa, Y.; Kamiya, N.; Gotoa, M. J. Hazard. Mater.2013,254-255, 79-88.
33.Garcia, M. E. D.; Medel, A. S.Talanta1986, 33, 255-264.
34.Safavi, A.; Abdollahi, H.; Maleki, N.; Zeinali, S. J.Colloid Interf. Sci.2008,322, 274-280.
35.Werner, T.; Wolfbeis, O. S. Fresen. J. Anal. Chem.1993,346, 564-568.
36.Dutta, K.; Deka, R.; Das, D. K. J.Fluoresc.2013,23, 1173-1178.
37.Seleim, M. M.; Abu-Bakr, M. S.; Hashem, E.Y.; El-Zohry, A. M.Can. J. Anal. Sci. Spect.2009,54, 93-101.
38.Kostova, D. J.Anal. Chem.2010,65, 159-163.
39.Ragos, G. C.; Demertzis, M. A.; Issopoulos, P. B.Farmaco1997,52, 199-203.
40.Tang, B.; Fang, H.Anal. Lett.2001,34, 1353-1368.