Simple and rapid voltammetric determination of boron in water and steel samples using a pencil graphite electrode

This paper presents a simple, rapid, and accurate voltammetric method for determination of boron in water and steel samples using a disposable pencil graphite electrode. The oxidation of Tiron in the boron-Tiron complex in phosphate buffer at pH 7.5 was measured as a response. Type and concentration of supporting electrolyte, pH, ionic strength, Tiron concentration, scan rate, step amplitude, pulse amplitude, and pencil grade were investigated as the parameters affecting the peak current. The limit of detection (3s) was estimated as 84 $\mu $g/L. The relative standard deviation of the method was 4.6 for 1 mg B/L (N = 7). The recovery results varied between 90% and 103% for water samples and between 94% and 108% for steel samples. The results were compared with those obtained from the ICP-OES method and no statistically significant difference between the methods was found.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

LOKMAN LİV, NURİ NAKİBOĞLU

Magda ABDALLA, Sobhi GOMHA, Mohamad Abd ELAZIZ, Nany SERAG

Comparative density functional study of antioxidative activity of thehydroxybenzoic acids and their anions

Zoran MARKOVIC, Jelena DOROVIC, Jasmina M. DIMITRIC MARKOVIC, Radomir BIOCANIN, Dragan AMIC

Synthesis, and prediction of molecular properties and antimicrobial activity ofsome acylhydrazones derived fromN-(arylsulfonyl)methionine

Esra TATAR, Hasan Erdinç SELLİTEPE, Şengül Alpay KARAOĞLU, Arif BOZDEVECİ, Christophe PANNECOUQUE, Taibi BEN HADDA, Sevil ŞENKARDES, Sükriye Güniz KÜÇÜKGÜZEL, İlkay KÜÇÜKGÜZEL, Erik DE CLERCQ

HASAN KÜÇÜKBAY, AKIN MUMCU, SUAT TEKİN, SÜLEYMAN SANDAL

Synthesis and application of polyvinylimidazole-based Br nsted acidic ionic liquidgrafted silica as an efficient heterogeneous catalyst in the preparation ofquinoxaline derivatives

Alireza SARDARIAN, Elaheh ATAOLLAHI, Bahman TAMAMI

Photocatalysis of formaldehyde in the aqueous phase over ZnO/diatomitenanocomposite

Reza DARVISHI CHESHMEH SOLTAN, Masumeh MASHAYEKHI, Mahdi SAFARI, Alireza KHATAEE

Synthesis and evaluation of some novel thiazoles and 1,3-thiazines as potentagents against the rabies virus

Nany SERAG, Magda ABDALLA, Mohamad ABD EL-AZIZ, Sobhi GOMHA

Ecofriendly one-pot synthesis and antiviral evaluation of novel pyrazolylpyrazolines of medicinal interest

Nany SERAG, Mohamad ABD EL-AZIZ, Magda ABDALLAH, Sobhi GOMHA

REZA DARVISHI CHESHMEH SOLTANI, ALIREZA KHATAEE, MASUMEH MASHAYEKHI, MAHDI SAFARI