Rajni GARG, Priya RANI, Nnabuk Okon EDDY, Rishav GARG

Study on potential applications and toxicity analysis of green synthesized nanoparticles

Nanomaterials have garnered the significant interest of scientists owing to their technological as well as medical applications. In particular, metal and metal oxide nanoparticles have gained prominence because of their enhanced performance as compared to their bulk counterparts. Metal-supported nanomaterials are anticipated to make major contributions to solving today’s most challenging issues, like energy harvesting and environmental remediation. The incorporation of nanoparticles into sensors has significantly enhanced their precision and selectivity. With the advent of green chemistry, green synthetic techniques have been prioritized for the synthesis of single and multicomponent nanomaterials. In the current review, we have addressed the multidimensional applications of nanoparticles in various sectors, including surface coatings, biosensing, environmental remediation, energy devices, construction, and nano probing, etc. This study focuses on the categorization of nanomaterials according to their source, dimensions, and composition, along with the exploration of synthetic modes. The eco-friendly and cost-effective greener route for the synthesis of nanoparticles has been explored in detail. Further, the antibacterial and cytotoxic potential has been addressed, and toxicity analysis has been conducted. The study signifies the augmented potential of green synthesized nanoparticles that can prove as economically viable and eco-friendly alternatives to conventional materials.

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1. Jain R, Mendiratta S, Kumar L, Srivastava A. Green synthesis of iron nanoparticles using Artocarpus heterophyllus peel extract and their application as a heterogeneous Fenton-like catalyst for the degradation of Fuchsin Basic dye. Current Research in Green and Sustainable Chemistry 2021; 4 (March): 100086. doi: 10.1016/j.crgsc.2021.100086
2. Duman F, Ocsoy I, Kup FO. Chamomile flower extract-directed CuO nanoparticle formation for its antioxidant and DNA cleavage properties. Materials Science and Engineering C 2016; 60: 333-338. doi: 10.1016/j.msec.2015.11.052
3. Tasgin E, Nadaroglu H, Babagil A, Demir N. Immobilization of purified pectin lyase from pseudomonas putida onto magnetic lily flowers (Lilium candidum L.) nanoparticles and applicability in industrial processes. Molecules 2020; 25 (11): 2671. doi: 10.3390/ molecules25112671
4. Ferreira AJ, Cemlyn-Jones J, Robalo Cordeiro C. Nanoparticles, nanotechnology and pulmonary nanotoxicology. Revista Portuguesa de Pneumologia 2013; 19 (1): 28-37. doi: 10.1016/j.rppneu.2012.09.003
5. Naseem T, Durrani T. The role of some important metal oxide nanoparticles for wastewater and antibacterial applications: A review. Environmental Chemistry and Ecotoxicology 2021; 3 : 59-75. doi: 10.1016/j.enceco.2020.12.001
6. Jayachandran A, Aswathy TR, Nair AS. Green synthesis and characterization of zinc oxide nanoparticles using Cayratia pedata leaf extract. Biochemistry and Biophysics Reports 2021; 26 (100995): 100995. doi: 10.1016/j.bbrep.2021.100995
7. Sharma R, Garg R, Kumari A. A review on biogenic synthesis, applications and toxicity aspects of zinc oxide nanoparticles. EXCLI Journal 2020; 19 : 1325-1340. doi: 10.17179/excli2020-2842
8. Zhao Y. Surface-Cross-Linked Micelles as Multifunctionalized Organic Nanoparticles for Controlled Release, Light Harvesting, and Catalysis. Langmuir 2016; 32 (23): 5703-5713. doi: 10.1021/acs.langmuir.6b01162
9. Najahi-Missaoui W, Arnold RD, Cummings BS. Safe nanoparticles: Are we there yet? International Journal of Molecular Sciences 2021; 22 (1): 1-22. doi: 10.3390/ijms22010385
10. Li S, Al-Misned FA, El-Serehy HA, Yang L. Green synthesis of gold nanoparticles using aqueous extract of Mentha Longifolia leaf and investigation of its anti-human breast carcinoma properties in the in vitro condition. Arabian Journal of Chemistry 2021; 14 (2): 102931. doi: 10.1016/j.arabjc.2020.102931
11. Wang Z, Wang W, Liu S, Yang N, Zhao G. Coupling rotating disk electrodes and surface-enhanced Raman spectroscopy for in situ electrochemistry studies. Electrochemistry Communications 2021; 124 (106928): 106928. doi: 10.1016/j.elecom.2021.106928
12. Medhi R, Srinoi P, Ngo N, Tran HV, Lee TR. Nanoparticle-based strategies to combat COVID-19. ACS Applied Nano Materials 2020; 3 (9): 8557-8580. doi: 10.1021/acsanm.0c01978
13. Satpathy S, Patra A, Ahirwar B, Delwar Hussain M. Antioxidant and anticancer activities of green synthesized silver nanoparticles using aqueous extract of tubers of Pueraria tuberosa. Artificial Cells, Nanomedicine and Biotechnology 2018; 46 (sup3): S71-S85. doi: 10.1080/21691401.2018.1489265
14. Devatha CP, Thalla AK, Katte SY. Green synthesis of iron nanoparticles using different leaf extracts for treatment of domestic waste water. Journal of Cleaner Production 2016; 139: 1425-1435. doi: 10.1016/j.jclepro.2016.09.019
15. Demirci Gültekin D, Alaylı Güngör A, Önem H, Babagil A, Nadaroğlu H. Synthesis of Copper Nanoparticles Using a Different Method: Determination of Its Antioxidant and Antimicrobial Activity. Journal of the Turkish Chemical Society, Section A: Chemistry 2016; 3 (3): 623-623. doi: 10.18596/jotcsa.287299
16. Umamaheswari A, Prabu SL, John SA, Puratchikody A. Green synthesis of zinc oxide nanoparticles using leaf extracts of Raphanus sativus var. Longipinnatus and evaluation of their anticancer property in A549 cell lines. Biotechnology Reports 2021; 29: e00595. doi: 10.1016/j. btre.2021.e00595
17. Baldemir A, Köse NB, Ildiz N, İlgün S, Yusufbeyoǧlu S et al. Synthesis and characterization of green tea (Camellia sinensis (L.) Kuntze) extract and its major components-based nanoflowers: A new strategy to enhance antimicrobial activity. RSC Advances 2017; 7 (70): 44303-44308. doi: 10.1039/c7ra07618e
18. Ertugrul MS, Nadaroglu H, Nalci OB, Hacimuftuoglu A, Alayli A. Preparation of CoS nanoparticles-cisplatin bio-conjugates and investigation of their effects on SH-SY5Y neuroblastoma cell line. Cytotechnology 2020; 72 (6): 885-896. doi: 10.1007/s10616-020-00432-5
19. Celik C, Ildiz N, Ocsoy I. Building block and rapid synthesis of catecholamines-inorganic nanoflowers with their peroxidase-mimicking and antimicrobial activities. Scientific Reports 2020; 10 (1): 2903. doi: 10.1038/s41598-020-59699-5
20. Estudiante-Mariquez OJ, Rodríguez-Galván A, Ramírez-Hernández D, Contreras-Torres FF, Medina LA. Technetium-radiolabeled mannose-functionalized gold nanoparticles as nanoprobes for sentinel lymph node detection. Molecules 2020; 25 (8): 1982. doi: 10.3390/ molecules25081982
21. Bao J, Huang T, Wang Z, Yang H, Geng X et al. 3D graphene/copper oxide nano-flowers based acetylcholinesterase biosensor for sensitive detection of organophosphate pesticides. Sensors and Actuators, B: Chemical 2019; 279 : 95-101. doi: 10.1016/j.snb.2018.09.118
22. Poghossian A, Weil MH, Bäcker M, Mayer D, Schöning MJ. Field-effect devices functionalised with goldnanoparticle/ macromolecule hybrids: New opportunities for a label-free biosensing. Procedia Engineering 2012; 47 : 273-276. doi: 10.1016/j.proeng.2012.09.136
23. Gokturk E, Ocsoy I, Turac E, Sahmetlioglu E. Horseradish peroxidase-based hybrid nanoflowers with enhanced catalytical activities for polymerization reactions of phenol derivatives. Polymers for Advanced Technologies 2020; 31 (10): 2371-2377. doi: 10.1002/pat.4956
24. Altinkaynak C, Tavlasoglu S, Kalin R, Sadeghian N, Ozdemir H et al. A hierarchical assembly of flower-like hybrid Turkish black radish peroxidase-Cu2+ nanobiocatalyst and its effective use in dye decolorization. Chemosphere 2017; 182 : 122-128. doi: 10.1016/j. chemosphere.2017.05.012
25. Leng Y, Fu L, Ye L, Li B, Xu X et al. Protein-directed synthesis of highly monodispersed, spherical gold nanoparticles and their applications in multidimensional sensing. Scientific Reports 2016; 6 (June): 1-11. doi: 10.1038/srep28900
26. Spada A, Emami J, Tuszynski JA, Lavasanifar A. The Uniqueness of Albumin as a Carrier in Nanodrug Delivery. Molecular Pharmaceutics 2021; 18 (5): 1862-1894. doi: 10.1021/acs.molpharmaceut.1c00046
27. Khan S, Babadaei MMN, Hasan A, Edis Z, Attar F et al. Enzyme–polymeric/inorganic metal oxide/hybrid nanoparticle bio-conjugates in the development of therapeutic and biosensing platforms. Journal of Advanced Research 2021; 33 (xxxx): 227-239. doi: 10.1016/j. jare.2021.01.012
28. Hernández-Hernández AA, Aguirre-Álvarez G, Cariño-Cortés R, Mendoza-Huizar LH, Jiménez-Alvarado R. Iron oxide nanoparticles: synthesis, functionalization, and applications in diagnosis and treatment of cancer. Chemical Papers 2020; 74 (11): 3809-3824. doi: 10.1007/s11696-020-01229-8
29. Corcione CE, Frigione M. Novel ultraviolet-curable methacrylate nanocomposite as coatings for cultural heritage applications. Proceedings of the Institution of Mechanical Engineers, Part N: Journal of Nanoengineering and Nanosystems 2014; 228 (1): 33-39. doi: 10.1177/1740349913486098
30. Miao F, Shao C, Li X, Lu N, Wang K et al. Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors. Energy 2016; 95 : 233-241. doi: 10.1016/j. energy.2015.12.013
31. Zhou K, Zhou X, Liu J, Huang Z. Application of magnetic nanoparticles in petroleum industry: A review. Journal of Petroleum Science and Engineering 2020; 188 (December 2019): 106943. doi: 10.1016/j.petrol.2020.106943
32. Albukhari SM, Ismail M, Akhtar K, Danish EY. Catalytic reduction of nitrophenols and dyes using silver nanoparticles @ cellulose polymer paper for the resolution of waste water treatment challenges. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2019; 577 (March): 548-561. doi: 10.1016/j.colsurfa.2019.05.058
33. Dayem AA, Hossain MK, Lee S Bin, Kim K, Saha SK et al. The role of reactive oxygen species (ROS) in the biological activities of metallic nanoparticles. International Journal of Molecular Sciences 2017; 18 (1): 120. doi: 10.3390/ijms18010120
34. Chen T, Öçsoy I, Yuan Q, Wang R, You M et al. One-Step facile surface engineering of hydrophobic nanocrystals with designer molecular recognition. Journal of the American Chemical Society 2012; 134 (32): 13164-13167. doi: 10.1021/ja304115q
35. Yousef MI, Mutar TF, Kamel MAEN. Hepato-renal toxicity of oral sub-chronic exposure to aluminum oxide and/or zinc oxide nanoparticles in rats. Toxicology Reports 2019; 6 (September 2017): 336-346. doi: 10.1016/j.toxrep.2019.04.003
36. Rašović I. Water-soluble fullerenes for medical applications. Materials Science and Technology (United Kingdom) 2017; 33 (7): 777-794. doi: 10.1080/02670836.2016.1198114
37. Baranowska-Wójcik E, Szwajgier D, Oleszczuk P, Winiarska-Mieczan A. Effects of Titanium Dioxide Nanoparticles Exposure on Human Health—a Review. Biological Trace Element Research 2020; 193 (1): 118-129. doi: 10.1007/s12011-019-01706-6
38. Moreno-Ríos AL, Tejeda-Benítez LP, Bustillo-Lecompte CF. Sources, characteristics, toxicity, and control of ultrafine particles: An overview. Geoscience Frontiers Published online 2021: 101147. doi: 10.1016/j.gsf.2021.101147
39. Van de Walle A, Sangnier AP, Abou-Hassan A, Curcio A, Hémadi M et al. Biosynthesis of magnetic nanoparticles from nanodegradation products revealed in human stem cells. Proceedings of the National Academy of Sciences of the United States of America 2019; 116 (10): 4044-4053. doi: 10.1073/pnas.1816792116
40. Patra JK, Das G, Fraceto LF, Campos EVR, Rodriguez-Torres MDPet al. Nano based drug delivery systems: Recent developments and future prospects 10 Technology 1007 Nanotechnology 03 Chemical Sciences 0306 Physical Chemistry (incl. Structural) 03 Chemical Sciences 0303 Macromolecular and Materials Chemistry 11 Medical and Health Sciences 1115 Pharmacology and Pharmaceutical Sciences 09 Engineering 0903 Biomedical Engineering Prof Ueli Aebi, Prof Peter Gehr. Journal of Nanobiotechnology 2018; 16 (1): 71. doi: 10.1186/s12951-018-0392-8
41. Kumar M, Bansal M, Garg R. An overview of beneficiary aspects of zinc oxide nanoparticles on performance of cement composites. Materials Today: Proceedings 2020; 43 (xxxx): 892-898. doi: 10.1016/j.matpr.2020.07.215
42. Warghane UK, Dhankar RP. Novel biosynthesis of silver nanoparticles for catalytic oxidation of Alcohols containing aromatic ring. Materials Today: Proceedings 2019; 15 : 526-535. doi: 10.1016/j.matpr.2019.04.117
43. Lazauskas A, Jucius D, Puodžiukynas L, Guobienė A, Grigaliūnas V. Sio2-based nanostructured superhydrophobic film with high optical transmittance. Coatings 2020; 10 (10): 1-7. doi: 10.3390/coatings10100934
44. Fu D, Li L-J. Label-free electrical detection of DNA hybridization using carbon nanotubes and graphene. Nano Reviews 2010; 1 (1): 5354. doi: 10.3402/nano.v1i0.5354
45. Kumar S, Mukherjee A, Dutta J. Chitosan based nanocomposite films and coatings: Emerging antimicrobial food packaging alternatives. Trends in Food Science and Technology 2020; 97 (August 2019): 196-209. doi: 10.1016/j.tifs.2020.01.002
46. Shi H, Chen X, Li L, Tan L, Ren X et al. One-pot and one-step synthesis of bioactive urease/ZnFe2O 4 nanocomposites and their application in detection of urea. Dalton Transactions 2014; 43 (24): 9016-9021. doi: 10.1039/c4dt00825a
47. Yang YN, Lu KY, Wang P, Ho YC, Tsai ML et al. Development of bacterial cellulose/chitin multi-nanofibers based smart films containing natural active microspheres and nanoparticles formed in situ. Carbohydrate Polymers 2020; 228 (September 2019): 115370. doi: 10.1016/j. carbpol.2019.115370
48. Nadaroglu H, Ince S, Gungor AA. Green synthesis of gold nanoparticles using quail egg yolk and investigation of potential application areas. Green Processing and Synthesis 2017; 6 (1): 43-48. doi: 10.1515/gps-2016-0091
49. Ma N, Sargent EH, Kelley SO. One-step DNA-programmed growth of luminescent and biofunctionalized nanocrystals. Nature Nanotechnology 2009; 4 (2): 121-125. doi: 10.1038/nnano.2008.373
50. Park CS, Yoon H, Kwon OS. Graphene-based nanoelectronic biosensors. Journal of Industrial and Engineering Chemistry 2016; 38: 13-22. doi: 10.1016/j.jiec.2016.04.021
51. Evtugyn G, Hianik T. Electrochemical immuno- and aptasensors for mycotoxin determination. Chemosensors 2019; 7 (1): 10. doi: 10.3390/CHEMOSENSORS7010010
52. Sivaprakash S, Kumar PS, Krishna SKK. Synthesis & Characteristic Study of Agricultural Waste Activated Carbon /Fe3o4– Nano Particles. Int J Mater Sci 2017; 12 (1): 97–105.
53. Demetzos C. Pharmaceutical nanotechnology: Fundamentals and practical applications. In: Pharmaceutical Nanotechnology: Fundamentals and Practical Applications. ; 2016:1-203. doi: 10.1007/978-981-10-0791-0
54. Sun W, Mignani S, Shen M, Shi X. Dendrimer-based magnetic iron oxide nanoparticles: their synthesis and biomedical applications. Drug Discovery Today 2016; 21 (12): 1873-1885. doi: 10.1016/j.drudis.2016.06.028
55. Bajpai VK, Kamle M, Shukla S, Mahato DK, Chandra P, et al. Prospects of using nanotechnology for food preservation, safety, and security. Journal of Food and Drug Analysis 2018; 26 (4): 1201-1214. doi: 10.1016/j.jfda.2018.06.011
56. Singh A, Gautam PK, Verma A, Singh V, Shivapriya PM et al. Green synthesis of metallic nanoparticles as effective alternatives to treat antibiotics resistant bacterial infections: A review. Biotechnology Reports 2020; 25: e00427. doi: 10.1016/j.btre.2020.e00427
57. Huo D, Ding J, Cui YX, Xia LY, Li H et al. X-ray CT and pneumonia inhibition properties of gold-silver nanoparticles for targeting MRSA induced pneumonia. Biomaterials 2014; 35 (25): 7032-7041. doi: 10.1016/j.biomaterials.2014.04.092
58. Sunderam V, Thiyagarajan D, Lawrence AV, Mohammed SSS, Selvaraj A. In-vitro antimicrobial and anticancer properties of green synthesized gold nanoparticles using Anacardium occidentale leaves extract. Saudi Journal of Biological Sciences 2019; 26 (3): 455-459. doi: 10.1016/j.sjbs.2018.12.001
59. Ocsoy I, Paret ML, Ocsoy MA, Kunwar S, Chen T et al. Nanotechnology in plant disease management: DNA-directed silver nanoparticles on graphene oxide as an antibacterial against Xanthomonas perforans. ACS Nano 2013; 7 (10): 8972-8980. doi: 10.1021/nn4034794
60. Marra F, Baiamonte L, Bartuli C, Valente M, Valente T et al. Tribological behaviour of alumina-titania nanostructured coatings produced by air plasma spray technique. Chemical Engineering Transactions 2016; 47 : 127-132. doi: 10.3303/CET1647022
61. Matinise N, Fuku XG, Kaviyarasu K, Mayedwa N, Maaza M. ZnO nanoparticles via Moringa oleifera green synthesis: Physical properties & mechanism of formation. Applied Surface Science 2017; 406: 339-347. doi: 10.1016/j.apsusc.2017.01.219
62. Bhakay A, Rahman M, Dave RN, Bilgili E. Bioavailability enhancement of poorly water-soluble drugs via nanocomposites: Formulation– Processing aspects and challenges. Pharmaceutics 2018; 10 (3): 86. doi: 10.3390/pharmaceutics10030086
63. San KA, Shon YS. Synthesis of alkanethiolate-capped metal nanoparticles using alkyl thiosulfate ligand precursors: A method to generate promising reagents for selective catalysis. Nanomaterials 2018; 8 (5): 1–21. doi: 10.3390/nano8050346
64. Hu CMJ, Zhang L, Aryal S, Cheung C, Fang RH et al. Erythrocyte membrane-camouflaged polymeric nanoparticles as a biomimetic delivery platform. Proceedings of the National Academy of Sciences of the United States of America 2011; 108 (27): 10980-10985. doi: 10.1073/pnas.1106634108
65. Manna O, Singh SK, Paul G. Enhanced thermal conductivity of nano-SiC dispersed water based nanofluid. Bulletin of Materials Science 2012; 35 (5): 707-712. doi: 10.1007/s12034-012-0366-7
66. Parveen K, Banse V, Ledwani L. Green synthesis of nanoparticles: Their advantages and disadvantages. AIP Conference Proceedings 2016; 1724 . doi: 10.1063/1.4945168
67. Dadi S, Celik C, Ocsoy I. Gallic acid nanoflower immobilized membrane with peroxidase-like activity for m-cresol detection. Scientific Reports 2020; 10 (1): 1-9. doi: 10.1038/s41598-020-73778-7
68. Nadaroglu H, Gungor AA, Ince S, Babagil A. Green synthesis and characterisation of platinum nanoparticles using quail egg yolk. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 2017; 172 : 43-47. doi: 10.1016/j.saa.2016.05.023
69. Yang Z, Malinick AS, Yang T, Cheng W, Cheng Q. Gold nanoparticle-coupled liposomes for enhanced plasmonic biosensing. Sensors and Actuators Reports 2020; 2 (1): 100023. doi: 10.1016/j.snr.2020.100023
70. Celik C, Tasdemir D, Demirbas A, Kati A, Gul OT et al. Formation of functional nanobiocatalysts with a novel and encouraging immobilization approach and their versatile bioanalytical applications. RSC Advances 2018; 8 (45): 25298-25303. doi: 10.1039/c8ra03250e
71. Strayer A, Ocsoy I, Tan W, Jones JB, Paret ML. Low concentrations of a silver-based nanocomposite to manage bacterial spot of tomato in the greenhouse. Plant Disease 2016; 100 (7): 1460-1465. doi: 10.1094/PDIS-05-15-0580-RE
72. Dadi S, Celik C, Mandal AK, Ocsoy I. Dopamine and norepinephrine assistant-synthesized nanoflowers immobilized membrane with peroxidase mimic activity for efficient detection of model substrates. Applied Nanoscience (Switzerland) 2021; 11 (1): 117-125. doi: 10.1007/s13204-020-01577-7
73. Tasgin E, Babagil A, Nadaroglu H. Immobilization of purified pectin lyase from acinetobacter calcoaceticus onto magnetic carboxymethyl cellulose nanoparticles and ıts usability in food ındustry. Journal of Chemistry 2020; 2020 . doi: 10.1155/2020/4791408
74. Galal GF, Abd-Elhalim BT, Abou-Taleb KA, Haroun AA, Gamal RF. Toxicity assessment of green synthesized Cu nanoparticles by cellfree extract of Pseudomonas silesiensis as antitumor cancer and antimicrobial. Annals of Agricultural Sciences 2021; 66 (1): 8-15. doi: 10.1016/j.aoas.2021.01.006
75. Devanesan S, Jayamala M, AlSalhi MS, Umamaheshwari S, Ranjitsingh AJA. Antimicrobial and anticancer properties of Carica papaya leaves derived di-methyl flubendazole mediated silver nanoparticles. Journal of Infection and Public Health 2021; 14 (5): 577-587. doi: 10.1016/j.jiph.2021.02.004
76. Seshadri VD. Zinc oxide nanoparticles from Cassia auriculata flowers showed the potent antimicrobial and in vitro anticancer activity against the osteosarcoma MG-63 cells. Saudi Journal of Biological Sciences 2021; 28 (7): 4046-4054. doi: 10.1016/j.sjbs.2021.04.001
77. Vitta Y, Figueroa M, Calderon M, Ciangherotti C. Synthesis of iron nanoparticles from aqueous extract of Eucalyptus robusta Sm and evaluation of antioxidant and antimicrobial activity. Materials Science for Energy Technologies 2020; 3 : 97-103. doi: 10.1016/j. mset.2019.10.014
78. Koca FD, Demirezen Yilmaz D, Ertas Onmaz N, Yilmaz E, Ocsoy I. Green synthesis of allicin based hybrid nanoflowers with evaluation of their catalytic and antimicrobial activities. Biotechnology Letters 2020; 42 (9): 1683-1690. doi: 10.1007/s10529-020-02877-2
79. Karaagac Z, Gul OT, Ildiz N, Ocsoy I. Transfer of hydrophobic colloidal gold nanoparticles to aqueous phase using catecholamines. Journal of Molecular Liquids 2020; 315 : 113796. doi: 10.1016/j.molliq.2020.113796
80. Demirbas A, Büyükbezirci K, Celik C, Kislakci E, Karaagac Z et al. Synthesis of long-term stable gold nanoparticles benefiting from red Raspberry (Rubus idaeus), Strawberry (Fragaria ananassa), and Blackberry (Rubus fruticosus) extracts-gold ıon complexation and ınvestigation of reaction conditions. ACS Omega 2019; 4 (20): 18637-18644. doi: 10.1021/acsomega.9b02469
81. Unal IS, Demirbas A, Onal I, Ildiz N, Ocsoy I. One step preparation of stable gold nanoparticle using red cabbage extracts under UV light and its catalytic activity. Journal of Photochemistry and Photobiology B: Biology 2020; 204 : 111800. doi: 10.1016/j.jphotobiol.2020.111800
82. Some S, Bulut O, Biswas K, Kumar A, Roy A et al. Effect of feed supplementation with biosynthesized silver nanoparticles using leaf extract of Morus indica L. V1 on Bombyx mori L. (Lepidoptera: Bombycidae). Scientific Reports 2019; 9 (1): 14839. doi: 10.1038/s41598-019- 50906-6
83. Edison TJI, Sethuraman MG. Instant green synthesis of silver nanoparticles using Terminalia chebula fruit extract and evaluation of their catalytic activity on reduction of methylene blue. Process Biochemistry 2012; 47 (9): 1351-1357. doi: 10.1016/j.procbio.2012.04.025
84. Şeker Karatoprak G, Aydin G, Altinsoy B, Altinkaynak C, Koşar M et al. The Effect of pelargonium endlicherianum fenzl. root extracts on formation of nanoparticles and their antimicrobial activities. Enzyme and Microbial Technology 2017; 97 : 21-26. doi: 10.1016/j. enzmictec.2016.10.019
85. Bharathi D, Bhuvaneshwari V. Evaluation of the Cytotoxic and Antioxidant Activity of Phyto-synthesized Silver Nanoparticles Using Cassia angustifolia Flowers. BioNanoScience 2019; 9 (1): 155-163. doi: 10.1007/s12668-018-0577-5
86. Dogru E, Demirbas A, Altinsoy B, Duman F, Ocsoy I. Formation of Matricaria chamomilla extract-incorporated Ag nanoparticles and size-dependent enhanced antimicrobial property. Journal of Photochemistry and Photobiology B: Biology 2017; 174 (May): 78-83. doi: 10.1016/j.jphotobiol.2017.07.024
87. Ocsoy I, Gulbakan B, Chen T, Zhu G, Chen Z et al. DNA-guided metal-nanoparticle formation on graphene oxide surface. Advanced Materials 2013; 25 (16): 2319-2325. doi: 10.1002/adma.201204944
88. Singh D, Rathod V, Ninganagouda S, Hiremath J, Singh AK et al. Optimization and characterization of silver nanoparticle by endophytic fungi penicillium sp. isolated from curcuma longa (Turmeric) and application studies against MDR E. coli and S. aureus. Bioinorganic Chemistry and Applications 2014; 2014 : 1-8. doi: 10.1155/2014/408021
89. Sivasankar P, Seedevi P, Poongodi S, Sivakumar M, Murugan T et al. Characterization, antimicrobial and antioxidant property of exopolysaccharide mediated silver nanoparticles synthesized by Streptomyces violaceus MM72. Carbohydrate Polymers 2018; 181 (November 2017): 752-759. doi: 10.1016/j.carbpol.2017.11.082
90. Tran HM, Tran H, Booth MA, Fox KE, Nguyen TH et al. Nanomaterials for treating bacterial biofilms on implantable medical devices. Nanomaterials 2020; 10 (11): 1-19. doi: 10.3390/nano10112253
91. Mohanta YK, Panda SK, Jayabalan R, Sharma N, Bastia AK et al. Antimicrobial, antioxidant and cytotoxic activity of silver nanoparticles synthesized by leaf extract of Erythrina suberosa (Roxb.). Frontiers in Molecular Biosciences 2017; 4 (MAR): 1-9. doi: 10.3389/ fmolb.2017.00014
92. Mohanta YK, Panda SK, Jayabalan R, Sharma N. Antimicrobial, Antioxidant and Cytotoxic Activity of Silver Nanoparticles Synthesized by Leaf Extract of Erythrina suberosa (Roxb.). 2017; 4 (March): 1-9. doi: 10.3389/fmolb.2017.00014
93. Wu D, Huang C. Thermal conductivity study of SiC nanoparticle beds for thermal insulation applications. Physica E: Low-Dimensional Systems and Nanostructures 2020; 118 (October 2019): 113970. doi: 10.1016/j.physe.2020.113970
94. Kumar A, Patel A, Duvalsaint L, Desai M, Marks ED. Thymosin β4 coated nanofiber scaffolds for the repair of damaged cardiac tissue. Journal of Nanobiotechnology 2014; 12 (1): 10. doi: 10.1186/1477-3155-12-10
95. Dong W, Wang R, Gong X, Dong C. An efficient turn-on fluorescence biosensor for the detection of glutathione based on FRET between N,S dual-doped carbon dots and gold nanoparticles. Analytical and Bioanalytical Chemistry 2019; 411 (25): 6687-6695. doi: 10.1007/ s00216-019-02042-3
96. Ul’yanova NY, Golubeva OY. Zeolites Modified with Silver Nanoparticles and Clusters: Synthesis, Characterization, and Catalytic Performance in H2 and CO Oxidation Reactions. Glass Physics and Chemistry 2018; 44 (5): 418-422. doi: 10.1134/S1087659618050218
97. Wang HK, Yi CY, Tian L, Wang WJ, Fang J et al. Ag-Cu bimetallic nanoparticles prepared by microemulsion method as catalyst for epoxidation of styrene. Journal of Nanomaterials 2012; 2012 : 1-8. doi: 10.1155/2012/453915
98. Ildiz N, Baldemir A, Altinkaynak C, Özdemir N, Yilmaz V et al. Self assembled snowball-like hybrid nanostructures comprising Viburnum opulus L. extract and metal ions for antimicrobial and catalytic applications. Enzyme and Microbial Technology 2017; 102 (March): 60-66. doi: 10.1016/j.enzmictec.2017.04.003
99. Srivastava K, Srivastava A, Singh P, Sharma V, Singh P. Remediation of distillery waste water using zero valent iron nanoparticles. Current Research in Green and Sustainable Chemistry 2021; 4 (February): 100072. doi: 10.1016/j.crgsc.2021.100072
100. Khaydarov RR, Khaydarov RA, Gapurova O, Garipov I, Lutfi Firdaus M. Silver Nanoparticles as a Biocide for Water Treatment Applications. In: Nanotechnology in the Life Sciences 2019, pp. 407-419. doi: 10.1007/978-3-030-02381-2_18
101. Garg R, Garg R, Bansal M, Aggarwal Y. Experimental study on strength and microstructure of mortar in presence of micro and nanosilica. Materials Today: Proceedings 2020; 43 (xxxx): 769-777. doi: 10.1016/j.matpr.2020.06.167
102. Garg R, Garg R. Effect of zinc oxide nanoparticles on mechanical properties of silica fume-based cement composites. Materials Today: Proceedings 2020; 43 (xxxx): 778-783. doi: 10.1016/j.matpr.2020.06.168
103. Gowthaman NSK, John SA. Modification of a glassy carbon electrode with gold-platinum core-shell nanoparticles by electroless deposition and their electrocatalytic activity. RSC Advances 2015; 5 (53): 42369-42375. doi: 10.1039/c5ra06537b
104. Xiang M, Xu X, Liu F, Li N, Li KA. Gold nanoparticle based plasmon resonance light-scattering method as a new approach for glycogenbiomacromolecule interactions. Journal of Physical Chemistry B 2009; 113 (9): 2734-2738. doi: 10.1021/jp8065822
105. Jazayeri MH, Aghaie T, Avan A, Vatankhah A, Ghaffari MRS. Colorimetric detection based on gold nano particles (GNPs): An easy, fast, inexpensive, low-cost and short time method in detection of analytes (protein, DNA, and ion). Sensing and Bio-Sensing Research 2018; 20 (May): 1-8. doi: 10.1016/j.sbsr.2018.05.002
106. Yu M, Niu Y, Zhang J, Zhang H, Yang Y et al. Size-dependent gene delivery of amine-modified silica nanoparticles. Nano Research 2016; 9 (2): 291-305. doi: 10.1007/s12274-015-0909-5
107. Gupta R, Xie H. Nanoparticles in daily life: Applications, toxicity and regulations. Journal of Environmental Pathology, Toxicology and Oncology 2018; 37 (3): 209-230. doi: 10.1615/JEnvironPatholToxicolOncol.2018026009
108. von Mikecz A, Schikowski T. Effects of airborne nanoparticles on the nervous system: Amyloid protein aggregation, neurodegeneration and neurodegenerative diseases. Nanomaterials 2020; 10 (7): 1-10. doi: 10.3390/nano10071349
109. Some S, Sarkar B, Biswas K, Jana TK, Bhattacharjya D et al. Bio-molecule functionalized rapid one-pot green synthesis of silver nanoparticles and their efficacy toward the multidrug resistant (MDR) gut bacteria of silkworms (Bombyx mori). RSC Advances 2020; 10 (38): 22742-22757. doi: 10.1039/d0ra03451g