Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands (Part 4): Synthesis and Characterization of a New 5-Hydroxysalicyliden-P-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II) and Zn(II)

5-Hydroxysalicyliden-p-aminoacetophenoneoxime (LH) was synthesized starting from p-aminoacetophenoneoxime and 5-hydroxysalicylaldehyde. Complexes of this ligand with Co+2, Ni+2, Cu+2 and Zn+2 salts were prepared. With this ligand, complexes were synthesized using Co+2, Ni+2, Cu+2 and Zn+2 salt with a metal:ligand ratio of 1:2. Their structures were elucidated on the basis of elemental analyses, IR, 1H- and 13C-NMR, electronic spectra, magnetic susceptibility measurements, molar conductivity and thermogravimetric analyses.

Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands (Part 4): Synthesis and Characterization of a New 5-Hydroxysalicyliden-P-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II) and Zn(II)

5-Hydroxysalicyliden-p-aminoacetophenoneoxime (LH) was synthesized starting from p-aminoacetophenoneoxime and 5-hydroxysalicylaldehyde. Complexes of this ligand with Co+2, Ni+2, Cu+2 and Zn+2 salts were prepared. With this ligand, complexes were synthesized using Co+2, Ni+2, Cu+2 and Zn+2 salt with a metal:ligand ratio of 1:2. Their structures were elucidated on the basis of elemental analyses, IR, 1H- and 13C-NMR, electronic spectra, magnetic susceptibility measurements, molar conductivity and thermogravimetric analyses.

___

  • K. Arora and K.P. Sharma, Synth. React. Inorg. Met.-Org. Chem. 32, 913 (2003).
  • P.A. Vigato and S. Tamburini, Coord. Chem. Rev. 248, 1717 (2004).
  • T. Katsuki, Coord. Chem. Rev. 140, 189 (1995).
  • T.D. Thangadurai, M. Gowri and K. Natarajan, Synth. React. Inorg. Met.-Org. Chem. 32, 329 (2002).
  • R. Ramesh and M. Sivagamasundari, Synth. React. Inorg. Met.-Org. Chem. 33, 899 (2003).
  • E. Canpolat and M. Kaya, Polish J. Chem. 79, (2005).
  • E. Canpolat, M. Kaya and A.O. G¨org¨ul¨u, Polish J. Chem. 76, 687 (2002).
  • E. Canpolat, and M. Kaya, J. Coord. Chem. 55, 961 (2002).
  • E. Canpolat and M. Kaya, J. Coord. Chem. 55, 1419 (2002).
  • O. G¨ung¨or, E. Canpolat and M. Kaya, Polish J. Chem. 77, 403 (2003).
  • E. Canpolat, M. Kaya and A. Yazıcı, Russian J. Coord. Chem. 30, 87 (2004).
  • E. Canpolat and M. Kaya, Polish J. Chem. 77, 961 (2003).
  • S. Satapathy and B. Sahoo, J. Inorg. Nucl. Chem. 32, 2223 (1970).
  • L.F. Lindoy, W.E. Moody and D. Taylor, Inorg. Chem. 16, 1962 (1977).
  • H.A. Patwardhan, S. Gopinathan and C. Gopinathan, Indian J. Chem. 16, 224 (1978).
  • P. Bamfield, J. Chem. Soc., A, 804 (1967).
  • B. Sing and U.R. Sing, Cryst. Res. Technol. 26B, 1039 (1991).
  • E. Canpolat, M. Kaya and S. G¨ur, Turk. J. Chem. 28, 235 (2004).
  • E. Canpolat and M. Kaya, J. Coord. Chem. 57, 25 (2004).
  • E. Canpolat and M. Kaya, Transition Met. Chem. 29, 550 (2004).
  • M.M. Aboaly and M.M.H. Khalil, Spectros. Lett. 34, 495 (2001).
  • R. Atkins, G. Brewer, E. Kokot, G.M. Mockler and E. Sinn, Inorg. Chem. 24, 127 (1985).
  • J.C. Rasmussen, H. Toftlund, A.N. Nivorzhkin, J. Bourassa and P.C Ford, Inorg. Chim. Acta. 251, 291 (1996).
  • S. Yamada and A. Takeuchi, Coord. Chem. Rev. 43, 187 (1982).
  • A.B.P. Lever, Inorganic Electronic Spectroscopy, 2ndElsevier, Amsterdam, (1997).
  • M.R. Wagner and F.A. Walker, Inorg. Chem. 22, 3021 (1983).
  • W.J. Geary, Coord. Chem. Rev. 7, 81 (1971).
  • E. Canpolat, M. Kaya and A. Yazıcı, Spectros. Lett. 38, 35 (2005).
  • E. Canpolat and M. Kaya, Russian J. Chem. 31, 415 (2005).
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Phlinoside F, a New Phenylethanoid Glycoside from Phlomis angustissima

Funda Nuray YALÇIN, Tayfun ERSÖZ, Erdal BEDİR, Sevser ŞAHPAZ, François BAILLEUL, İkhlas A. KHAN, Ali A. DÖNMEZ, İhsan ÇALIŞ

Design and Characterization of Amino and Chloro Functionalized Rhombohedral Silsesquioxanes

Ahmet GÜLTEK, Turgay SEÇKİN, Halil İbrahim ADIGÜZEL

Synthesis of isomorphous prototypic $[CrFe_2O(AcO)_6(TEP)_3]Cl$ and $[CrFe_2O(AcO_6(TMP)_3]Cl$ As Oxo-centered hetero tri-nuclear carboxylate complexes

Massoud RAFIZADEH, Vahid AMANI, Reza TAYEBEE

Catalytic Spectrophotometric Determination of Chromium

Angelina Miltcheva STOYANOVA

Determination of Cadmium, Copper, Iron, Manganese, Lead and Zinc in Lichens and Botanic Samples by Electrothermal and Flame Atomic Absorption Spectrometry

Orhan ACAR, Sümer ÖZVATAN, Murat İLİM

Proton conduction in PVPA-benzimidazole hybrid electrolytes

Ayhan BOZKURT, Fatma SEVİL

Synthesis of Isomorphous Prototypic [CrFe2O(AcO)6(TEP)3]Cl and [CrFe2O(AcO)6(TMP)3]Cl As Oxo-Centered Hetero Tri-Nuclear Carboxylate Complexes

Massoud RAFIZADEH, Reza TAYEBEE, Vahid AMANI

Some New Mannich Bases of 5-Methyl-2-Benzoxazolinones With Analgesis and Anti-Inflammatory Activities

Nesrin GÖKHAN, Meriç KÖKSAL, Esra KÜPELİ

O-Galloyl Flavonoids from Geranium pyrenaicum and Their in vitro Antileishmanial Activity

Dilek ERCİL, Maeki KALOGA, Oliver A. RADTKE, M. Koray SAKAR, Albrecht F. KIDERLEN, Herbert KOLODZIEJ

Studies an mononuclear chelates derived from substituted Schiff base ligands (Part 4):Synthesis and characterization of a new 5-hydroxysalicyliden-P-aminoacetophenoneoxime and its complexes with Co(II),Ni(II),Cu(II) and Zn(II)

Mehmet KAYA, Erdal CANPOLAT