Muhammad Adeel SAEED, Muhammad Khawar RAUF

8383

Some bioactive organotin(IV) derivatives with 3,4-dichlorophenylacetic acid: synthesis, spectroscopic properties, and X-ray structure of [Sn4(C4H9)8(OOCCH2C6H3Cl2)4O2]

Some bioactive organotin(IV) derivatives of 3,4-dichlorophenylacetic acid (HL) were synthesized by reacting the ligand acid with various di- or tri-organotin compounds (in suitable mole ratios) in the presence of triethylamine. The structural investigation was carried out via multinuclear (1H, 13C, and 119Sn) NMR, IR spectroscopy, and X-ray crystallography. The crystal structure of 4 comprises a central Sn2O2 core with O atoms bonded to 2 dibutylbis(3,4-dichlorophenylacetato)tin(IV) units. All the Sn atoms of 4 are essentially 5-coordinated in distorted trigonal-bipyramidal geometry. Some of the compounds exhibited significant antibacterial and antifungal activity.

Anahtar Kelimeler:

Organotin(IV), spectroscopy, distannoxane, X-ray structure, antibacterial, antifungal.

Some bioactive organotin(IV) derivatives with 3,4-dichlorophenylacetic acid: synthesis, spectroscopic properties, and X-ray structure of [Sn4 (C4H9)8 (OOCCH2C6H3Cl2)4O2 ]

Some bioactive organotin(IV) derivatives of 3,4-dichlorophenylacetic acid (HL) were synthesized by reacting the ligand acid with various di- or tri-organotin compounds (in suitable mole ratios) in the presence of triethylamine. The structural investigation was carried out via multinuclear (1H, 13C, and 119Sn) NMR, IR spectroscopy, and X-ray crystallography. The crystal structure of 4 comprises a central Sn2O2 core with O atoms bonded to 2 dibutylbis(3,4-dichlorophenylacetato)tin(IV) units. All the Sn atoms of 4 are essentially 5-coordinated in distorted trigonal-bipyramidal geometry. Some of the compounds exhibited significant antibacterial and antifungal activity.

Keywords:

Organotin(IV), spectroscopy, distannoxane, X-ray structure, antibacterial, antifungal.,

Turkish Journal of Chemistry-Cover

ISSN: 1300-0527
Yayın Aralığı: 6
Yayıncı: TÜBİTAK

Arşiv

Sayıdaki Diğer Makaleler

Template synthesis and characterization of 16-membered octaazamacrocyclic complexes: a photoelectron spectroscopic study

Abul KALAM, Vishnu TRIPATHI, Shekhar SRIVASTAVA

Cellular distribution of activity for three enzymes with maltose binding protein as fusion partner and the structural implications

Özde F. ÜTKÜR, Berna SARIYAR AKBULUT Amable HORTAÇSU

Synthesis, characterization, and application of nanoporous materials based on silicon- or halogen-containing spiroketal and spirothioketal polymers

Hamada Hamada ABDEL-RAZIK

Synthesis and uranyl ion adsorption study of cross-linked allyl propionate-maleic anhydride-styrene terpolymer

Elchin AKPEROV, Abel MAHARRAMOV, Oktay AKPEROV

Influence of AlCl3 on the optical properties of new synthesized 3-armed poly(methyl methacrylate) films

Synthesis of some pyridazine derivatives carrying urea, thiourea, and sulfonamide moieties and their antimicrobial activity

Deniz S. DOĞRUER, Şölen URLU, Tijen ÖNKOL

Density functional theory investigation of electrophilic addition reaction of chlorine to tricyclo[4.2.2.$2^{2,5}$ ]dodeca-1,5-diene

Rza ABBASOĞLU, Ahmet YAŞAR

Multichannel spectrophotometry for analysis of organophosphate paraoxon in beverages

Miroslav POHANKA, Jana Zdarova KARASOVA

Synthesis and characterization of new optically active polyamides containing 2-(4-nitro-1,3-dioxoisoindolin-2-yl)succinic acid and aromatic diamines via direct polycondensation

Khalil FAGHIHI, Morteza Absalar And Mohsen HAJIBEYGI

Radical scavenging potential of compounds isolated from Vitex agnus-castus

Talat MAKHMOOR, - AZIZUDDIN, Muhammad İqbal CHOUDHARY