Platinum or nickel nanoparticles decorated on silica spheres by microwave irradiation technique

Supported catalysts are of great interest because of their wide range of application possibilities. In this study, firstly silica spheres were synthesized and then platinum and nickel nanoparticles were incorporated on this silica by microwave irradiation, which is an efficient technique for catalyst preparation. Synthesized silica spheres and catalysts were characterized by BET, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy techniques. Pt or Ni nanoparticles well dispersed over silica support were obtained using microwave irradiation.

Anahtar Kelimeler:

Silica, microwave irradiation, supported catalyst, Pt/SiO2, Ni/SiO2

Platinum or nickel nanoparticles decorated on silica spheres by microwave irradiation technique

Keywords:

Silica, microwave irradiation, supported catalyst, Pt/SiO2, Ni/SiO2,

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Jia, R. L.; Wang, C. Y.; Wang, S. M. J. Mater. Sci. 2006, 41, 6881–6888.
Planeix, J. M.; Coustel, N.; Coq, B.; Brotons, V.; Kumbhar, P. S.; Dutartre R.; Geneste, P.; Bernier, P.; Ajayan, P. M. J. Am. Chem. Soc. 1994, 116, 7935–7936.
Li, Z. X.; Shi, F. B.; Li, L. L.; Zhang, T.; Yan, C. H. Phys. Chem. Chem. Phys. 2011, 13, 2488–2491.
Ogino, I.; Chen, C. Y.; Gates, B. C. Dalton Trans. 2010, 39, 8423–8431.
Min, B. K.; Santra, A. K.; Goodman, D. W. Catal. Today 2003, 85, 113–124.
Moon, D. S.; Lee, J. K. Langmuir 2012, 28, 12341–12347.
Travitsky, N.; Ripenbein, P.; Golodnitsky, D.; Rosenberg, Y.; Burshtein, L.; Peled, E. J. Power Sources 2006, 161, 782–789.
Farrukh, M. A.; Heng, B. T.; Adnan, R. Turk. J. Chem. 2010, 34, 537–550.
Bayrak¸ ceken, A.; T¨ urker, L.; Ero˘ glu, ˙I. Int. J. Hydrogen Energ. 2008, 33, 7527–7537.
Tierney, J. P.; Lidstr¨ om, P. Microwave Assisted Organic Synthesis; CRC Press: Boca Raton, FL, USA, 2005.
Hori, K.; Matsune, H.; Takenaka, S.; Kishida, M. Sci. Tech. Adv. Mater. 2006, 7, 678–684.
Li, A.; Zhao, J. X.; Pierce, D. T. J. Colloid Interface Sci. 2010, 351, 365–371.
Godsell, J. F.; Donegan, K. P.; Tobin, J. M.; Copley, M. P.; Rhen, F. M. F.; Otway, D. J.; Morris, M. A.; O’Donnell, T.; Holmes, J. D.; Roy, S. J. Magn. Magn. Mater. 2010, 322, 1269–1274.
Xu, W.; Liew, K. Y.; Liu, H.; Huang, T.; Sun, C.; Zhao, Y. Mater. Lett. 2008, 62, 2571–2573.
Song, S.; Liu, J.; Shi, J.; Liu, H.; Maragou, V.; Wang, Y.; Tsiakaras, P. Appl. Catal. B Environ. 2011, 103, 287–293. Tsai, C. H.; Yang, F. L.; Chang, C. H.; Chen-Yang, Y. W. Int. J. Hydrogen Energ. 2012, 37, 7669–7676.
Liu, Z.; Gan, L. M.; Hong, L.; Chen, W.; Lee, J. Y. J. Power Sources 2005, 139, 73–78.
Fı¸ cıcılar, B.; Bayrak¸ ceken, A.; Ero˘ glu, ˙I. Int. J. Hydrogen Energ. 2010, 35, 9924–9933.
Ramesh, S.; Koltypin, Y.; Prozorov, R.; Gedanken, A. Chem. Mater. 1997, 9, 546–551.
Singho, N. D.; Johan, M. R. Int. J. Electrochem. Sci. 2012, 7, 5604–5615.
Wang, W.; Song, M.; Zhang, Z. Y.; Richardson, M. J. Non-Cryst. Solids 2006, 352, 2180–2186.
Hernandez, C.; Pierre, A. C. Langmuir 2000, 16, 530–536.
Beganskien´ e, A.; Sirutkaitis, V.; Kurtinaitien´ e, M.; Juˇ sk´ enas, R.; Kareiva, A. Mater. Sci. (Medˇ ziagotyra) 2004, 10, 287–290.
Ramimoghadam, D.; Bin Hussein, M. Z.; Taufiq-Yap, Y. H. Int. J. Mol. Sci. 2012, 13, 13275–13293.
Liu, K.; Feng, Q.; Yang, Y.; Zhang, G.; Ou, L.; Lu, Y. J. Non-Cryst. Solids 2007, 353, 1534–1539.