Nermin Şimşek KUŞ

2917

Photochemical bromination of substituted indan-1-one derivatives: synthesis of new polybromoindan-1-one derivatives

The photobromination of substituted indan derivatives was studied. Four products, 2,3-dibromo-inden-1-one (5), trans-2,3-dibromoindan-1-one (6), 2,2-dibromoindan-1,3-dione (7) and 2,2-dibromoindan-1-one (8), were obtained by the bromination of indan-1-one (4). The bromination of 2-methyl indanone (9) and 3-methyl-indanone (13) gave the corresponding monobromo, dibromo, and tribromo compounds in high yield. 4-Nitro indan (16) was tribrominated under same condition reaction. The structures of these products were determined from 1H-NMR, 13C-NMR, MS, and IR data.
Anahtar Kelimeler:

Indan-1-one, 2-methyl-1-indanone, 3-methly-1-indanone, 4-nitro indan.

Photochemical bromination of substituted indan-1-one derivatives: synthesis of new polybromoindan-1-one derivatives

The photobromination of substituted indan derivatives was studied. Four products, 2,3-dibromo-inden-1-one (5), trans-2,3-dibromoindan-1-one (6), 2,2-dibromoindan-1,3-dione (7) and 2,2-dibromoindan-1-one (8), were obtained by the bromination of indan-1-one (4). The bromination of 2-methyl indanone (9) and 3-methyl-indanone (13) gave the corresponding monobromo, dibromo, and tribromo compounds in high yield. 4-Nitro indan (16) was tribrominated under same condition reaction. The structures of these products were determined from 1H-NMR, 13C-NMR, MS, and IR data.
Keywords:

Indan-1-one, 2-methyl-1-indanone, 3-methly-1-indanone, 4-nitro indan.,

PDF
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

Photochemical bromination of substituted indan-1-one derivatives: synthesis of new polybromoindan-1-one derivatives

Nermin Şimşek KUŞ

Comparative study of selective CO oxidation over Pt-Co-M/ $Al_2O_3$ catalysts (M=Ce, Mg, Mn, Zr, Fe) in hydrogen-rich streams: effects of a second promoter

Ramazan YILDIRIM, K. Erdem UĞUZ

Chemical constituents and mushroom tyrosinase inhibition activity of Chloroxylon swietenia leaves

Gottumukkala Venkateswara RAO, Kolisetty Sambasiva RAO

Pregnane steroids from the heartwood of Azadirachta indica

Bina Shaheen SIDDIQUI, Syed Kashif ALI, Syed Tariq ALI, Fayyaz AHMED

Comparative study of selective CO oxidation over Pt-Co-M/Al2O3 catalysts (M=Ce, Mg, Mn, Zr, Fe) in hydrogen-rich streams: effects of a second promoter

K. Erdem Uğuz And Ramazan YILDIRIM

2,2'-binaphthylene phosphorochloridite (BINOL-PCI) as a bulky and efficient reagent for the conversion of primary and secondary alcohols into iodides, and tertiary alcohols stereo-and /or regioselectively into olefin(s)

Jabbar KHALAFY, Hossein KHANI-MEINAGH, Nader Noroozı PESYAN

Performance analysis for direct 2-propanol fuel-cell based on Pt containing anode electrocatalysts

Niyazi Alper TAPAN, Ezgi ÖZTÜRK

Synthesis and characterization of new optically active and heat resistant poly (amide-imide)s derived from N,N'-bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic)-bis-L-leucine and aromatic diamines

Hossein Nasr ISFAHANI, Atena IZADKHAH, Khalil FAGHIHI, Meisam SHABANIAN

Study of binary complexes of nickel(II), copper(II), and vanadium(V) with acetazolamide in aqueous medium by voltammetry

İclal BULUT

2,2'-Binaphthylene phosphorochloridite (BINOL-PCl) as a bulky and efficient reagent for the conversion of primary and secondary alcohols into iodides, and tertiary alcohols stereo- and/or regioselectively into olefin(s)

Nader Noroozi PESYAN, Jabbar Khalafy And Hossein KHANI-MEINAGH