Isolation of bis(1,4-diphenyl-1,4-bis(2-pyridyl)-2,3-diaza-1,3-butadiene) disilver with bridging (N-N) dinucleating subunits: formation of a 6-membered chelate ring
A novel Ag(I) dinuclear complex {[(C6H5)(C5H4N)-C=N-N=C- (C5H4N)(C6H5)]Ag}2.ClO4(ClO4) (1/2CH3CN) (1) that was derived under mild conditions, during the course of combination of AgClO4 with a polymorphic azine ligand, 1,4-diphenyl-1,4-bis(2-pyridyl)-2,3- diaza-1,3-butadiene (L) (condensed product of phenyl 2-pyridyl ketone and hydrazine monohydrate) is reported. The aforementioned complex is based on a central rotationally flexible diazine subunit (N-N). The azine ligand, L, having the N2 dinucleating fragment, provides a coordination focus for pairs of metal centres and ultimately leads to the formation of a 6-membered chelate ring in 1.
Anahtar Kelimeler:
Turk. J. Chem., 34, (2010), 277-284. Full text: pdf Other articles published in the same issue: Turk. J. Chem., vol.34, iss.2.
Isolation of bis(1,4-diphenyl-1,4-bis(2-pyridyl)-2,3-diaza-1,3-butadiene) disilver with bridging (N-N) dinucleating subunits: formation of a 6-membered chelate ring
A novel Ag(I) dinuclear complex {[(C6H5)(C5H4N)-C=N-N=C- (C5H4N)(C6H5)]Ag}2.ClO4(ClO4) (1/2CH3CN) (1) that was derived under mild conditions, during the course of combination of AgClO4 with a polymorphic azine ligand, 1,4-diphenyl-1,4-bis(2-pyridyl)-2,3- diaza-1,3-butadiene (L) (condensed product of phenyl 2-pyridyl ketone and hydrazine monohydrate) is reported. The aforementioned complex is based on a central rotationally flexible diazine subunit (N-N). The azine ligand, L, having the N2 dinucleating fragment, provides a coordination focus for pairs of metal centres and ultimately leads to the formation of a 6-membered chelate ring in 1.
Keywords:
Turk. J. Chem., 34, (2010), 277-284. Full text: pdf Other articles published in the same issue: Turk. J. Chem., vol.34, iss.2.,
- ISSN: 1300-0527
- Yayın Aralığı: Yılda 6 Sayı
- Yayıncı: TÜBİTAK
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