Determination of the Thermodynamic Properties of Poly [2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] at Infinite Dilution by Inverse Gas Chromatography

Some thermodynamic quantities were obtained for the interactions of poly [2-(3-phenyl -3- methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] Poly (PCHEMA-co-MA) with alcohols, ketones, acetates, aromatics and n-alkanes by inverse gas chromatography in the temperature range of 150-180oC. The specific retention volumes, Vgo, weight fraction activity coefficients of solute probes at infinite dilution, W1\infty and Flory-Huggins thermodynamic interaction parameters, c12\infty between polymers and solvents were determined. The partial molar free energy, DG1\infty , the partial molar heat of mixing, DH1\infty , at infinite dilution and the solubility parameters of the polymer, d2 , were calculated. The copolymer was characterized by 1 H-NMR, FT-IR and DSC analyses

Determination of the Thermodynamic Properties of Poly [2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] at Infinite Dilution by Inverse Gas Chromatography

Some thermodynamic quantities were obtained for the interactions of poly [2-(3-phenyl -3- methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] Poly (PCHEMA-co-MA) with alcohols, ketones, acetates, aromatics and n-alkanes by inverse gas chromatography in the temperature range of 150-180oC. The specific retention volumes, Vgo, weight fraction activity coefficients of solute probes at infinite dilution, W1\infty and Flory-Huggins thermodynamic interaction parameters, c12\infty between polymers and solvents were determined. The partial molar free energy, DG1\infty , the partial molar heat of mixing, DH1\infty , at infinite dilution and the solubility parameters of the polymer, d2 , were calculated. The copolymer was characterized by 1 H-NMR, FT-IR and DSC analyses
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Voltammetric and polarographic studies of Ericochrome Back T- nickel (II) complex

Osman ÇAKIR, Ender BİÇER, Semiha ÇAKIR, Emine COŞKUN

The Isolation of Carboxylic Acids from the Flowers of Delphinium formosum

Nedime DÜRÜST, Yaşar DÜRÜST, Esra UMUR, Seçkin ÖZDEN, Mustafa KÜÇÜKİSLAMOĞLU

A Comparative Study on the Recovery of EcoRI Endonuclease from Two Different Genetically Modified Strains of Escherichia coli

Candan TAMERLER, İlsen ÖNSAN, Betül KIRDAR

Spectrophotometric Determination of Cobalt, Nickel Palladium, Copper, Ruthenium and Molybdenum Using Sodium Isoamylxanthate in Presence of Surfactants

A. K. MALIK, K. N. KAUL, B. S. LARK, W. FAUBEL, A. L. J. RAO

Synthesis and structure of systems containing pyramidalized and strained double bond: An investigation on the cycloaddition reactions of cis and trans-3,8-dicarbomethoxy-3,8-dihydroheptalene

Nurullah SARAÇOĞLU, Metin BALCI, Abdullah MENZEK

Unusual Chemical Constituents of Lotus garcinii (Fabaceae)

Muhammad Shaiq ALI, Viqar Uddin AHMAD, Farman AHMAD, Iqbal AZHAR, Khan USMANGHANI

Photocuring of Acrylate Oligomers in the Presence of Vinyl Phosphonic Acids as a Flame Retarding Monomer and the Properties of the Cured Films

Tülin İMAMOĞLU, Yusuf YAĞCI

Electrorheological properties of suspensions prepared from polystyrene-block-polyisoprene copolymer

Mustafa YAVUZ, Yılmaz YILDIRIR, Halil İbrahim ÜNAL

Fluorimetric detection of insulin in the presence of Eu (III) - { Pyridine-2,6-Dicarboxylate } tris complex

Serdar ATEŞ, Elmas GÖK

Determination of Hydrochlorothiazide and Enalapril Maleate in Tablet Formulations by Reversed-Phase HPLC

Idress F. AL-MOMANI