Zehra DURMUŞ, Abdulhadi BAYKAL, Hüseyin KAVAS, Nermin KASAPOĞLU, Muhammet S. TOPRAK, Yüksel KÖSEOĞLU

8894

CTAB-assisted hydrothermal synthesis and magnetic characterization of $Ni_x Co_{1-x}Fe_2O_4$ nanoparticles (x = 0.0, 0.6, 1.0)

CTAB-assisted hydrothermal synthesis and magnetic characterization of $Ni_x Co_{1-x}Fe_2O_4$ nanoparticles (x = 0.0, 0.6, 1.0)

Nickel ferrite, $Ni_x Co_{1-x}Fe_2O_4$ , NPs (where x = 0.0, 0.6 and 1.0) were successfully synthesized by a rapid and reproducible CTAB-assisted hydrothermal route. The influence of different hydrolyzing agents on the particle size and magnetic behavior of $Ni_x Co_{1-x}Fe_2O_4$ NPs was investigated. Particles showed very high phase purity and crystallinity in powder XRD analysis. Compositions of Co, Fe, and Ni in fabricated powders were also determined by AAS and results are in very good agreement with the targeted compositions. Samples hydrolyzed using NH3 showed no significant changes in the particle size and morphology. NH3 hydrolyzed samples were much smaller than their NaOH hydrolyzed counterparts, which was attributed to the strength and concentration of the hydrolyzing agents, NH3 being about 6 times more concentrated than NaOH. This in turn influenced the nucleation rate thus the size of each nucleus formed. Strong temperature and Ni concentration dependence of magnetic parameters was observed. These samples are considered as promising materials for high density magnetic recording media.
PDF

___

  • 1. Alivisatos, A.P.; Science 1996, 271, 933-937.
  • 2. Sugimoto, M. J. Am. Ceram. Soc. 1999, 82, 269-280.
  • 3. Rondinone, A.J.; Samia, A.C.S.; Zhang, Z.J. Appl. Phys. Lett. 2000, 76, 3624-3626.
  • 4. Pallai, V.; Shah, D.O. J. Magn. Magn. Mater. 1996, 163, 243-248.
  • 5. Skomski, R. J. Phys. Condens. Matter. 2003, 15, R841-934.
  • 6. Ramankutty, C.G.; Sugunan, S. Appl. Catal. A 2001, 218, 39-51.
  • 7. Reddy, C.V.G.; Manorama, S.V.; Rao,V.J. Sens. Actuators B:Chemical 1999, 55, 90-95.
  • 8. Zhou, Z.H.; Wang, J,M,; Chan, H.S.O.; Yu T., Shen, Z.X. J. Appl.Phys. 2002, 91, 6015-6020.
  • 9. Candlish, I.E.; Kear, B.H.; Kim, B.K. Nanostuct. Mater 1992, 1, 119-124.
  • 10. Skandan, G.; Hahn, H.; Roddy, M.; Cannon, W.R. J Am. Ceram. Soc. 1994, 77, 1706-1710.
  • 11. Kishimoto, M.; Sakurai, Y.; Ajima, T. J. Appl. Phys. 1994, 76, 7506-7509.
  • 12. Chen, Q.; Zhang, Z.J. Appl. Phys. Lett. 1998, 73, 3156-3158.
  • 13. Music, S.; Popovic, S.; Dalipi, S. J. Mat. Sci. 1993, 28, 1793-1798.
  • 14. Liu, X.M.; Yang, G.; Fu, S.Y. Mater. Sci. Eng. C 2007, 27(4), 750-755.
  • 15. Li, F.; Liu, J.J.; Evans, D.G.; Duan, X. Chem. Mater. 2004, 16, 1597-1602.
  • 16. Goya, G.F.; Rechenberg, H.R. J. Magn. Magn. Mater. 1999, 196, 191-192.
  • 17. Kasapoğlu N., “Synthesis, Characterization and ESR Studies of Magnetic Spinel Compounds, Master Thesis, Fatih Univ., 2008, İstanbul-TURKEY.
  • 18. Kasapoğlu, N.; Birsöz, B.; Baykal, A.; Köseoğlu, Y.; Toprak, M.S. Cent. Eur.J. Chem. 2007, 5(2), 570-580.
  • 19. Baykal, A.; Kasapoğlu, N.; Köseoğlu, Y.; Toprak, M.S.; Bayrakdar, H. J. Alloys Compounds 2008, 464, 514-518.
  • 20. Sertkol, M., “Preparation and Magnetic Characteization of Microwave Absorbing Magnetic Materials”, Master Thesis, Fatih Univ., 2008, İstanbul-TURKEY.
  • 21. Sertoğlu, M.; Köseoğlu, Y.; Baykal, A.; Kavas, H.; Ba¸saran, A.C. J. Magn. Magn. Mater. 2009, 321, 157-162.
  • 22. Ozkaya, T., “Synthesis and Characterization of M3O4 (M:Fe,Mn,Co) Magnetic Nanoparticles”, Master Thesis, Fatih Univ., 2008, ˙Istanbul-TURKEY.
  • 23. Baykal, A.; Kasapoğlu, N.; Köseoğlu, Y.; Başaran, A.C.; Kavas, H.; Toprak, M.S. Cent. Eur.J. Chem. 2008, 6(1), 125-130.
  • 24. Kasapoğlu, N.; Baykal, A.; Köseoğlu, Y.; Toprak, M.S. Scripta Mater 2007, 57, 441-444.
  • 25. Lee, Y.; Lee, J.; Bae, C.J.; Park, J.G.; Noh, H.J.; Park, J.H.; Hyeon, T. Adv. Funct. Mater. 2005, 15, 503-509.
  • 26. Ozkaya, T.; Toprak, M.S.; Baykal, A.; Kavas H.; K¨oseo˘glu Y.; Akta¸s, B. J.Alloys and Compounds 2008, doi:10.1016/j.jallcom.2008.04.101.
  • 27. Ozkaya, T.; Baykal, A.; Kavas, H.; Köseoğlu, Y.; Toprak, M.S. Physica B. 2008, 403, 3760-3764.
  • 28. Liu, X.M.; Fu, S.Y.; Huang, J. Mater. Sci. Eng. B 2005, 121, 255-260.
  • 29. Chae, K.P.; Lee, J.; Kweon, H.S.; Lee, Y.B. J. Magn. Magn. Mater. 2004, 283, 103-108.
  • 30. Kasapoğlu, N.; Baykal, A.; Toprak, M.S.; Köseoğlu, Y.; Bayraktar H. Turk.J. Chemistry 2007, 6, 659-666.
  • 31. Sertkol, M.; Köseoğlu, Y.; Baykal A.; Kavas, H.; Başaran, A.C. J. Magn. Magn. Mater. 2009, 321, 157-162.
  • 32. Köseoğlu, Y.; Baykal, A.; Toprak, M.S.; G¨oz¨uak, F.; Başaran, A. C.; Aktaş, B. J. Alloys Compounds 2008, 462, 209-213.
  • 33. Özkaya T.; Baykal A.; Toprak M.S. Cent. Eur. J. Chem. 2008, 6(3), 465-469.
  • 34. El Sayed, A.M. Ceram. Int. 2002, 28, 363-367.
  • 35. Sousa, M.H.; Tourinho, F.A. J. Phys. Chem. B 2001, 105, 1168-1175.
  • 36. Gupta, N.; Verna, A.; Kashyap, S.C.; Dube, D.C. J. Magn. Magn. Mater. 2007, 308, 137-142.
  • 37. Cullity, B.D. Elements of X-ray Diffraction, 3rd Edition, Prentice Hall, New York, 2001.
  • 38. Brabers. V.A.M. Phys. Status Solidi (a) 1972, 12, 629-636.
  • 39. Hanh, N.; Quy, O.K.; Thuy, N.P.; Tung, L.D.; Spinu. L. Physica B 2003, 327, 382.
  • 40. T. Kim, and M. Shima, J. Appl. Phys. 2007, 101 09M516.
  • 41. Kools, F.; Hanket, B. Proc ICF-5 1989, 1, 417.
  • 42. Wohlfarth, E.P. Ferromagnetic Materials, Wiley-VCH, Amsterdam, 1980.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: 6
  • Yayıncı: TÜBİTAK
Arşiv
Sayıdaki Diğer Makaleler

Silver Ion-Assisted Ring Expansions in Different Solvent Systems

Mesut BOZ, Hafize ÇALIŞKAN, Ömer ZAİM

Synthesis and Antimicrobial and Antitumor Activity of Some New [1,2,4] Triazole-5-one Derivatives

Yasemin ÜNVER, Esra DÜĞDÜ, Kemal SANCAK

A Convenient Synthesis of 2-Azido and 2-Thiocyanato-2,3-Unsaturated Cyclic Ketones

Mesut BOZ, Ömer Zaim And Hilal ESEN, Ömer ZAİM, Hilal ESEN

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Nevin KARABÖCEK, Pınar EKMEKÇİOĞLU

Nitric Oxide Releasing Derivatives of [(2-Chloroethyl)ureido] Benzoic Acid Esters as Potential Antineoplastic Agents

Hülya AKGÜN, Barkın BERK, Dilek Demir EROL

Bromination of Tetrachlorobenzobarrelene: Polyhalogenated Benzobicyclics

Mehmet Emin ŞENGÜL, Demet Demirci GÜLTEKİN, Selçuk EŞSİZ, Arif DAŞTAN

CTAB-Assisted Hydrothermal Synthesis and Magnetic Characterization of NixCo1-xFe2O4 Nanoparticles (x = 0.0, 0.6, 1.0)

Abdulhadi BAYKAL, Nermin KASAPOĞLU, Zehra DURMUŞ, Hüseyin KAVAS

6-Ketomethyl Phenanthridine as a New Carrier in the Construction of a Highly Selective Fe(III) Ion-Selective Membrane Electrode

Ramin MALEKI, Reza HOSSEINZADEH, Hossein MEHRABI, Ali HASSANZADEH, Khalil FARHADI

Synthesis and antimicrobial and antitumor activitiy of some new (1,2,4) triazole-5-one derivatives

Kemal SANCAK, Alpay Şengül KARAOĞLU, Mustafa ER, Yasemin ÜNVER, Esra DÜĞDÜ

Quantitative Structure--Retention Study of Some 2,4-dioksotetrahydro- 1,3--thiazole Derivatives Using the Partial Least Squares Method

Tatjana DJAKOVIC SEKULIC, Costel SRBU, Nada PERISIC JANJIC