Göktürk AVŞAR, Hakan ARSLAN

7488

Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)

In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, b = 93.90(1)°, and Dcalc = 1.616 g cm-1 for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

Anahtar Kelimeler:

Complex, X-ray structure, single crystal, N, N-dimethyl-N'- benzoylthiourea

Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)

In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, b = 93.90(1)°, and Dcalc = 1.616 g cm-1 for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

Keywords:

Complex, X-ray structure, single crystal, N, N-dimethyl-N'- benzoylthiourea,

Turkish Journal of Chemistry-Cover

ISSN: 1300-0527
Yayın Aralığı: 6
Yayıncı: TÜBİTAK

Arşiv

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