Cross coupling reactions catalyzed by (NHC)Pd(II) complexes

This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC--Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald--Hartwig aminations, which are extremely powerful in the formation of C--C and C--heteroatom bonds. Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide for chemists interested in these reactions. The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.

Cross coupling reactions catalyzed by (NHC)Pd(II) complexes

This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC--Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald--Hartwig aminations, which are extremely powerful in the formation of C--C and C--heteroatom bonds. Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide for chemists interested in these reactions. The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.

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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Synthesis, characterization, and microwave-assisted catalytic activity in Heck, Suzuki, Sonogashira, and Buchwald--Hartwig cross-coupling reactions of novel benzimidazole salts bearing N-phthalimidoethyl and benzyl moieties

Hasan KÜÇÜKBAY, Ülkü YILMAZ, Kemal YAVUZ, Nesrin BUĞDAY

A simple approach to bis-spirocycles and spiroindole derivatives via greenmethods such as Fischer indolization, ring-closing metathesis, andSuzuki{Miyaura cross-coupling

Rashid ALI, Sambasivarao KOTHA

Copper-free Sonogashira cross-coupling reactions catalyzed by an efficient dimericC,N-palladacycle in DMF/H2O

Kazem KARAMI, Nasrin HAGHIGHAT NAEINI

Synthesis of new thiol-derivatized aminophosphines and their catalytic activities in C{C coupling reactions

Nermin BİRİCİK, Nermin MERİÇ, Cezmi KAYAN, Bahattin GÜMGÜM, Zeynep ÖZGEN, Sevil ŞEKER AZİZOĞLU

New Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: use of Pd(II) complexes as precatalyst in Mizoroki--Heck and Suzuki--Miyaura cross-coupling reactions

Murat AYDEMİR, Feyyaz DURAP, Akin BAYSAL

Contribution of heterobifunctional ligands to transition metal-catalysed C--C coupling reactions

Agnes LABANDE, Eric DEYDIER, Eric MANOURY, Jean-claude DARAN, Catherine AUDIN, Rinaldo POLI

Substituted 2-(2'-pyridyl)benzimidazole palladium(II) complexes as an efficient catalytic system for Suzuki{Miyaura cross-coupling reactions

Mahmut ULUSOY, Nurdal ÖNCEL, Emine AYTAR

Resorcinarene-mono-benzimidazolium salts as NHC ligands for Suzuki--Miyaura cross-couplings catalysts

ÜMİT İŞCİ, MUHİTTİN AYGÜN, RESUL SEVİNCEK, YUNUS ZORLU, FABIENNE DUMOULIN

Efficient C{C cross-coupling reactions by (isatin)-Schiff base functionalized magnetic nanoparticle-supported Cu(II) acetate as a magnetically recoverable catalyst

Seyedeh Simin MIRI, Fatemeh ASHOURI, Farnaz JAFARPOUR, Parviz RASHIDI RANJBAR, Abbas SHAFIEE, Mehdi KHOOBI

Monodisperse palladium nanoparticles supported on chemically derived graphene: highly active and reusable nanocatalysts for Suzuki{Miyaura cross-coupling reactions

Feyyaz DURAP, Önder METİN