Erdal ŞENOCAK, Yavuz TAŞKESENLİGİL

7376

Bromination of Benzonorbornadiene Using a Mixture of Sodium Bromide and Sodium Perborate at High Temperatures

Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.

Anahtar Kelimeler:

Bromination, benzonorbornadiene, high temperature bromination, sodium perborate.

Bromination of Benzonorbornadiene Using a Mixture of Sodium Bromide and Sodium Perborate at High Temperatures

Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.

Keywords:

Bromination, benzonorbornadiene, high temperature bromination, sodium perborate.,

Turkish Journal of Chemistry-Cover

ISSN: 1300-0527
Yayın Aralığı: 6
Yayıncı: TÜBİTAK

Arşiv

Sayıdaki Diğer Makaleler

New Triterpenic Saponins from Cephalaria transsylvanica

Süheyla Kirmizigül And Hüseyin ANIL

Poly (methacrylic) acid and $gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization

Yunus ÖNAL, Ahmet GÜLTEK, M. Galip İÇDUYGU, Turgay SEÇKİN

Spectrophotometric Determination of Mexiletine Hydrochloride in Capsules Using Bromothymol Blue

Zeynep AYDOĞMUŞ, S. Müge ÇETİN, Sedat TOSUNOĞLU

Bromination of Benzonorbornadiene Using a Mixture of Sodium Bromide and Sodium Perborate at High Temperatures

Erdal ŞENOCAK, Yavuz TAŞKESENLİGİL

Anodic behavior of tungsten in $H_3PO_4-K_2SO_4-H_2SO_4$/KOH solutions

The Selective Protection and Deprotection of Ambident Nucleophiles with Parent and Substituted Triarylmethyls

İbrahim DEMİRTAŞ, Bülent BÜYÜKKIDAN and Mahfuz ELMASTAŞ

Trace Element Accumulation in Selected Bioindicators Exposed to Emissions along the Industrial Facilities of Danube Lowland

Modeling of TaqI Endonuclease Purification by HPLC

Mehmet DÜZENLİ and Kutlu Ö. ÜLGEN

Pyridine and Benzene Templated Potential Peptidomimetics

Poly(methacrylic) Acid and g-methacryloxypropyltrimethoxy Silane/Clay Nanocomposites Prepared by In-Situ Polymerization

Ahmet GÜLTEK, Turgay SEÇKİN