Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds

Novel ferrocenyl substituted aziridinyl methanol (FAM) ligands were synthesized and successfully used in metal-promoted catalytic enantioselective azomethine ylide cycloadditions, diethylzinc additions to enones, alkynylzinc additions to aldehydes, diethylzinc additions to aldehydes, and Henry reactions. These reactions are summarized in this report.

Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds

Novel ferrocenyl substituted aziridinyl methanol (FAM) ligands were synthesized and successfully used in metal-promoted catalytic enantioselective azomethine ylide cycloadditions, diethylzinc additions to enones, alkynylzinc additions to aldehydes, diethylzinc additions to aldehydes, and Henry reactions. These reactions are summarized in this report.

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  • Dogan, O.; Koyuncu, H.; Garner, P. P.; Bulut, A.; Youngs, W. J.; Panzner, M. Org. Lett. 2006, 8, 4687.
  • Isleyen, A.; Dogan, O. Tetrahedron: Asymmetry 2007, 18, 679.
  • Koyuncu, H.; Dogan, O. Org. Lett. 2007, 9, 3477.
  • Reviews: a) Noyori, R.; Kitamura, M. Angew. Chem. Int. Ed. Engl. 1991, 30, 49. b) Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wiley: New York, 1994; Chapter 5. c) Soai, K.; Niva, S. Chem. Rev. 1992, 92, 833. d) Pu, L.; Yu, H.-B. Chem Rev. 2001, 101, 757.
  • Bulut, A.; Aslan, A.; Dogan, ¨O. J. Org. Chem. 2008, 73, 7373.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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