ANN-assisted forecasting of adsorption efficiency to remove heavy metals

ANN-assisted forecasting of adsorption efficiency to remove heavy metals

In wastewater treatment, scientific and practical models utilizing numerical computational techniques suchas artificial neural networks (ANNs) can significantly help to improve the process as a whole through adsorption systems.In the modeling of the adsorption efficiency for heavy metals from wastewater, some kinetic models have been used such as pseudo first-order and second-order. The present work develops an ANN model to forecast the adsorption efficiency of heavy metals such as zinc, nickel, and copper by extracting experimental data from three case studies. To do this, we apply trial-and-error to find the most ideal ANN settings, the efficiency of which is determined by mean square error (MSE) and coefficient of determination (R2). According to the results, the model can forecast adsorption efficiency percent (AE%) with a tangent sigmoid transfer function (tansig) in the hidden layer with 10 neurons and a linear transferfunction (purelin) in the output layer. Furthermore, the Levenberg–Marquardt algorithm is seen to be most ideal for training the algorithm for the case studies, with the lowest MSE and high R2 . In addition, the experimental results and the results predicted by the model with the ANN were found to be highly compatible with each other.

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  • 1. Fergusson JE. Heavy Elements: Chemistry, Environmental Impact and Health Effects. ffOxford, UK: Pergamon, 1990.
  • 2. Dean JG, Bosqui FL, Lannouette KL. Removing heavy metals from waste water. Environmental Science Technology 1977; 6: 518-524.
  • 3. Pai TY, Wang SC, Lo HM, Chiang CF, Liu MH et al. Novel modeling concept for evaluating the effects of cadmium and copper on heterotrophic growth and lysis rates in activated sludge process. Hazardous Materials 2009; 166: 200-206.
  • 4. Juliastuti S, Baeyens J, Creemers C, Bixio D, Lodewyckx E. The inhibitory effects of heavy metals and organic compounds on the net maximum specific growth rate of the autotrophic biomass in activated sludge. Hazardous Materials 2003; 100: 271-283.
  • 5. Wang X, Guo Y, Yang L, Han M, Zhao J et al. Nanomaterials as sorbents to remove heavy metal ions in wastewater treatment. Journal of Environmental Analysis and Toxicology 2012; 2: 100-154.
  • 6. Tyagi I, Gupta VK, Sadegh H, Ghoshekandi RS, Makhlouf ASH. Nanoparticles as adsorbent; a positive approach for removal of noxious metal ions. Science, Technology and Development 2017; 34: 195-214.
  • 7. Rosenberg E. Heavy metals in water: presence, removal and safety. Johnson Matthey Technology 2015; 59: 293-297.
  • 8. Gautam RK, Chattopadhyaya MC. Advanced Nanomaterials for Wastewater Remediation. New York, NY, USA: CRC Press, 2016.
  • 9. Shirsath DS, Shirivastava VS. Adsorptive removal of heavy metals by magnetic nanoadsorbent: an equilibrium and thermodynamic study. Applied Nanoscience 2015; 5: 927-935.
  • 10. Neeraj G, Krishnan S, Kumar PS, Shriaishvarya KR, Kumar VV. Performance study on sequestration of copper ions from contaminated water using newly synthesized high effective chitosan coated magnetic nanoparticles. Journal of Molecular Liquids 2016; 214: 335-346.
  • 11. Ilankoon N. Use of iron oxide magnetic nanosorbents for Cr (VI) removal from aqueous solutions: a review. Journal of Engineering Research and Applications 2014; 4: 55-63.
  • 12. Ghaedi AM, Ghaedi M, Pouranfard AR, Ansari A, Avazzadeh Z et al. Adsorption of Triamterene on multi-walled and single-walled carbon nanotubes: artificial neural network modeling and genetic algorithm optimization. Journal of Molecular Liquids 2016; 216: 654-665.
  • 13. Elmolla ES, Chaudhuri M, Eltoukhy MM. The use of artificial neural network (ANN) for modeling of COD removal from antibiotic aqueous solution by the Fenton process. Journal of Hazardous Materials 2010; 179 (1-3): 127-134.
  • 14. Zhang Y, Pan B. Modeling batch and column phosphate removal by hydrated ferric oxide-based nanocomposite using response surface methodology and artificial neural network. Chemical Engineering Journal 2014; 249: 111-120.
  • 15. Assefi P, Ghaedi M, Ansari A, Habibi MH, Momeni MS. Artificial neural network optimization for removal of hazardous dye Eosin Y from aqueous solution using Co 2 O3 -NP-AC: Isotherm and kinetics study. Journal of Industrial and Engineering Chemistry 2014; 20 (5): 2905-2913.
  • 16. Zhu J, Zurcher J, Rao M, Meng MQH. An online wastewater quality predication system based on a time-delay neural network. Engineering Applications of Artificial Intelligence 1998; 11 (6): 747-758.
  • 17. Gontarski CA, Rodrigues PR, Mori M, Prenem LF. Simulation of an industrial wastewater treatment plant using artificial neural networks. Computers & Chemical Engineering 2000; 24 (2-7): 1719-1723.
  • 18. Pai TY, Tsai YP, Lo HM, Tsai C, Lin C. Grey and neural network prediction of suspended solids and chemical oxygen demand in hospital wastewater treatment plant effluent. Computers & Chemical Engineering 2007; 31 (10): 1272-1281.
  • 19. Sahoo GB, Ray C. Predicting flux decline in crossflow membranes using artificial neural networks and genetic algorithms. Journal of Membrane Science 2006; 283 (1-2): 147- 157.
  • 20. Chen H, Kim AS. Prediction of permeate flux decline in crossflow membrane filtration of colloidal suspension: a radial basis function neural network approach. Desalination 2006; 192 (1-3): 415-428.
  • 21. Shetty GR, Shankararaman C. Predicting membrane fouling during municipal drinking water nanofiltration using artificial neural networks. Journal of Membrane Science 2003; 217 (1-2): 69-86.
  • 22. Guadix A, Zapata JE, Almecija MC, Guadix EM. Predicting the flux decline in milk cross-flow ceramic ultrafiltration by artificial neural networks. Desalination 2010; 250 (3): 1118-1120.
  • 23. Libotean D, Giralt J, Giralt F, Rallo R, Wolfe T et al. Neural network approach for modeling the performance of reverse osmosis membrane desalting. Journal of Membrane Science 2009; 326 (2): 408-419.
  • 24. Prakash N, Manikandan SA, Govindarajan L, Vijayagopal V. Prediction of biosorption efficiency for the removal of copper (II) using artificial neural networks. Journal of Hazardous Materials 2008; 152 (3): 1268-1275.
  • 25. Fagundes-Klen MR, Ferri P, Martins TD, Tavares CRG, Silva EA. Equilibrium study of the binary mixture of cadmium–zinc ions biosorption by the Sargassum filipendula species using adsorption isotherms models and neural network. Biochemical Engineering Journal 2007; 34 (2): 136-146.
  • 26. Yetilmezsoy K, Demirel S. Artificial neural network (ANN) approach for modeling of Pb(II) adsorption from aqueous solution by Antep pistachio (Pistacia vera L.) shells. Journal of Hazardous Materials 2008; 153 (3): 1288-1300.
  • 27. Sadrzadeh M, Mohammadi T, Ivakpour J, Kasiri N. Neural network modeling of Pb 2+ removal from wastewater using electrodialysis. Chemical Engineering and Processing Process Intensification 2009; 48 (8): 1371-1381.
  • 28. Mandal S, Mahapatra SS, Sahu MK, Patel RK. Artificial neural network modelling of As(III) removal from water by novel hybrid material. Process Safety and Environmental Protection 2015; 93: 249-64.
  • 29. Kashaninejad M, Dehghani AA, Kashiri M. Modeling of wheat soaking using two artificial neural networks (MLP and RBF). Journal of Food Engineering 2009; 91 (3): 602-607.
  • 30. Singh KP, Basant A, Malik A, Jain G. Artificial neural network modeling of the river water quality-A case study. Ecological Modelling 2009; 220 (6): 888-895.
  • 31. Balku S. Magnetic removal of iron from fireclays: optimum conditions. Industrial Ceramics 2009; 29: 83-89.
  • 32. Fanaie VR, Karrabi M, Amin MM. Biosorption of 4-chlorophenol by dried anaerobic digested sludge: artificial neural network modeling, equilibrium isotherm, and kinetic study. International Journal of Environmental Science and Technology 2017; 14: 37-48.
  • 33. Khataee A, Khani A. Modeling of nitrate adsorption on granular activated carbon (GAC) using artificial neural network (ANN). International Journal of Chemical Reactor Engineering 2009; 7: 1-16.
  • 34. Allahkarami E, Igder A, Fazlavi A, Rezai B. Prediction of Co (II) and Ni (II) ions removal from wastewater using artificial neural network and multiple regression models. Physicochemical Problems of Mineral Processing 2017; 53 (2):1105-1118.
  • 35. Esmaeili A, Khoshnevisan N. Optimization of process parameters for removal of heavy metals by biomass of Cu and Co-doped alginate-coated chitosan nanoparticles. Bioresource Technology 2016; 218: 650-658.
  • 36. Bishop CM. Neural Networks for Pattern Recognition. New York, NY, USA: Oxford University Press, 1995.
  • 37. Maier HR, Morgan N, Chow CW. Use of artificial neural networks for predicting optimal alum doses and treated water quality parameters. Environmental Modelling & Software 2004; 19: 485-494.
  • 38. Hornik K, Stinchcombe M, White H. Multilayer feedforward networks are universal approximators. Neural Networks 1989; 2: 359-366.
  • 39. Madić MJ, Radovanović MR. Optimal selection of ANN training and architectural parameters using Taguchi method: a case study. FME Transactions 2011; 39 (2): 79-86.
  • 40. Panchal FS, Panchal M. Review on methods of selecting number of hidden nodes in artificial neural network. International Journal of Computer Science and Mobile Computing 2014; 3 (11): 455-464.
  • 41. Abbasi H, Seyedain ASM, Mohammadifar MA, Emam-Djomeh Z. Comparison of trial and error and genetic algorithm in neural network development for estimating farinograph properties of wheat-flour dough. Nutrition and Food Sciences Research 2015; 2 (3): 29-38.
  • 42. Laosiritaworn W, Chotchaithanakorn N. Artificial neural networks parameters optimization with design of experiments: an application in ferromagnetic materials modeling. Chiang Mai Journal of Science 2009; 36 (1): 83-91.
  • 43. Gazi, M, Oladipo AA, Ojoro ZE, Gulcan HO. High-performance nanocatalyst for adsorptive and photo-assisted Fenton-like degradation of phenol: modeling using artificial neural networks. Chemical Engineering Communications 2017; 204 (7): 729-738.
  • 44. Oladipo AA, Vaziri R, Abureesh MA. Highly robust AgIO3 /MIL-53 (Fe) nanohybrid composites for degradation of organophosphorus pesticides in single and binary systems: application of artificial neural networks modelling. Journal of the Taiwan Institute of Chemical Engineers 2018; 83: 133-142.
  • 45. Muhsin WA, Zhang J, Lee J. Modelling and optimization of a crude oil hydrotreating process using neural networks. Chemical Engineering Transactions 2016; 52: 211-216.
  • 46. Cenk N, Budak G, Dayanik S, Sabuncuoglu I. Artificial neural network modeling and simulation of in-vitro nanoparticle-cell interactions. Journal of Computational and Theoretical Nanoscience 2014; 11 (1): 272-282.
  • 47. Xu S, Chen L. A novel approach for determining the optimal number of hidden layer neurons for FNN’s and its application in data mining. In: ICITA 2008 5th International Conference on Information Technology and Applications; 2008. pp. 683-686.
  • 48. Pourzangbar A, Saber A, Yeganeh-Bakhtiary A, Ahari LR. Predicting scour depth at seawalls using GP and ANNs. Journal of Hydroinformatics 2017; 19 (3): 349-363.
  • 49. Ahmed FE. Artificial neural networks for diagnosis and survival prediction in colon cancer. Molecular Cancer 2005; 4 (1): 29-40.
  • 50. Shojaee SA, Hezave AZ, Lashkarbolooki M, Shafipour ZS. Prediction of the binary density of the ionic liquids+ water using back-propagated feed forward artificial neural network. Chemical Industry & Chemical Engineering Quarterly 2014; 20 (3): 325-338.
  • 51. Mao R, Zhu H, Zhang L, Chen A. A new method to assist small data set neural network learning. In: ISDA’06 Sixth International Conference on Intelligent Systems Design and Application; 2006. pp. 17-22.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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