Demirel Ayça ÖZEL, Esma KILIÇ, Sevcan ERDEN, Esin CANEL, Sahahabuddin MEMON, Mustafa YILMAZ

A hydrogen ion-selective poly (vinyl chloride mebrane electrode based on calix (4)arene as a perchlorate ion-selective electrode

A hydrogen ion-selective electrode was prepared using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracya-nometoxy-calix[4]arene and the possibility of its use as a perchlorate ion-selective electrode was investigated using its characteristic of becoming perchlorate sensitive in acidic regions. The electrode of the optimum characteristic had a composition of 1% ionophore, 66% o-NPOE, and 33% PVC. This electrode exhibited a linear response over the range 1.0 x $10^{-1}$-1.0 x $10^{-5}$ M of perchlorate with a slope of 48.7. ± 0.5- mV per p[Cl04]. The effects of the pH and the membrane composition were also investigated. The lifetime of the electrode was at least 4 months and its response time was 10-15 s. The selectivity coefficients of some anions were calculated by the matched potential method.

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