Host/guest inclusion system of surfactants with -cyclodextrin as a viable catalyst for one-pot synthesis of mono - and bis (indolyl)methylmalononitriles in H 2 O
In this study, encapsulation processes of cetyltrimethylammonium bromide
(CTAB) or sodium dodecyl sulfate (SDS) monomers
into the cavity of ββ\beta -cyclodextrin (ββ\beta -CD) were applied to
synthesize mono - and bis (indolyl)methylmalononitrile derivatives by a one-pot
three-component reaction of an aldehyde, malononitrile, and indole in an
aqueous solution. These two inclusion complexes proved to be superior to
CTAB or SDS individually, as cationic or anionic surfactants, respectively,
for accessing high yields of pure products within shorter reaction times. In
addition, simple isolation of products and mild reaction conditions are the
other advantages of this green procedure.
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- ISSN: 1300-0527
- Yayın Aralığı: Yılda 6 Sayı
- Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler
Ghulam ABBAS, Zahid HASSAN, Ahmed AL-HARRASI, Syed Aun MUHAMAAD, Ahood Juma AL-QURAINI, Zahra Khamis AL-MAANI, Ahmed Mohammed AL-ADAWAI
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Özlem ÖTER, Akif Cihan AYDIN, Merve ZEYREK ONGUN, Erdal ÇELİK
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Mahdieh TABIBIAN, Razieh MOHEBAT, Masoumeh TABATABAEE
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Ayman A. GOUDA, Wael A. ZORDOK