Necla YAMAN, Esen ÖZDOGAN, İ.Cengiz KOCUM, Hakan AYHAN, Tülin ÖKTEM, Necdet SEVENTEKIN

ATMOSFERİK GLOW DEŞARJ PLAZMA SİSTEMİ İLE POLİPROPİLEN VE POLİESTER KUMAŞLARIN YÜZEY ÖZELLİKLERİNİN İYİLEŞTİRİLMESİ

Atmosferik plasma işlemi uygulanmış poliester (PES) ve polipropilen (PP) dokuma kumaşların kir iticilik özelliği ve ıslanabilirliği incelenmiştir. Bu çalışmada, argon ve hava plazma PES ve PP kumaşların modifikasyonu için kullanılmıştır. PES ve PP kumaşların hidrofilliklerini değerlendirmek için, işlem görmemiş ve plazma işlemi görmüş materyallere kapilarite ve temas açısı ölçümleri uygulanmıştır. Plazma işlemi sonunda kumaş yüzeyinde meydana gelen kimyasal değişim Fourier Transform Infrared (FTIR) and XPS ile belirlendi. Yüzey morfolojisi SEM ile değerlendirilmiştir

Anahtar Kelimeler:

Atmosferik plazma, Poliester, Polipropilen, Lif, Hidrofillik

IMPROVEMENT SURFACE PROPERTIES OF POLYPROPYLENE AND POLYESTER FABRICS BY GLOW DISCHARGE PLASMA SYSTEM UNDER ATMOSPHERIC CONDITION

In order to raise wettability and to improve soil release of polyester (PES) and polypropylene (PP) woven fabrics, atmospheric pressure plasma were applied. In this study, argon and air plasma were used for modification of PES and PP fabrics. The capillary method and contact angle measurements of plasma treated and untreated textile materials were applied to evaluate the improvement in water uptake of PES and PP fabrics. Chemical changes in the fabric surface after atmospheric plasma treatments were determine by Fourier Transform Infrared (FTIR) and XPS. Their surface morphologies were evaluated by SEM

Keywords:

Atmospheric plasma, Polyester, Polypropylene, Fiber, Hydrophilicity,

PDF

___

1. Shishoo R. (Ed.), 2007, Plasma Technologies For Textiles, Woodhead Publ., Cambridge, 352.
2. Ferrero F., 2003, “Wettability Measurements on Plasma Treated Synthetic Fabrics by Capillary Rise Measurement”, Polymer Testing, Vol. 22, 571-578.
3. Costa T.H.C., Feitor M.C., Alves Jr. C., 2006, “Effects of Gas Composition During Plasma Modification of Polyester Fabrics”, Journal of Materials Processing Technology, Vol. 173, Issue 1, pp. 40-43.
4. Arefi F., Andre V., Montazer-Rahmati P., 1992, “Plasma Polymerisation and Surface Treatment of Polymer, Pure & Appl. Chem, Vol. 64, Issue 5, pp. 715-723.
5. Canup L.K., 2000, “Non Aqueous Treatment of Fabr›cs Utilizing Plasmas”, A Thesis Submitted to The Graduate Faculty of North Carolina State University, pp.108.
6. Oktem T., Ayhan H., Seventekin N., 1999, “Modification of Polyester Fabrics by in Situ Plasma or Post-Plasma Polymerization of Acrylic Acide”, JSDC, Vol.115, 274-279.
7. Koçum C., Ayhan H., 2007, “Design and Construction of Uniform Glow Discharge Plasma System Operating Under Atmospheric Condition”, Rewiev of Scientific Instruments, Vol. 78, pp. 063501-063501.5.
8. Borcia G., Anderson C. A, Brown N.M.D., 2003, “Dielectric Barrier Discharge for Surface Treatment: Application to Selected Polymers in Film and Fibre Form, Plasma Sources Science Technology”, Vol.12, 335-344
9. Kwon O.J., Tang S., Myung S.W., 2005, “Surface Characteristics of Polypropylene Film Treated by An Atmospheric Pressure Plasma”, Surface & Coatings Technology, Vol. 192, pp.1– 10
10. Krump H., Hudec I., Jaššo M., 2006, “Physical-Morpholgy and Chemical Changes Leading To An Increase In Adhesion Between Plasma Treated Polyester Fibres and a Rubber Matrix”, Applied Surface Science, Vol. 252, 4261-4278.
11. Tomasino C., Cuomo J., Vernon P., Radzimski Z., Salama M., Oehrlein G., Smith C., 1995, Plasma Treatment-Textiles, Annual Report 1/9/94 to 30/6/95, NC State, p:7
12. N.V. Bhat, D.J. Upadhyay, 2002, “Plasma-Induced Surface Modification and Adhesion Enhancement of Polypropylene Surface”, J. Appl. Polym. Sci. Vol. 86, 925-936.
13. Muller M., Rieser T., Lunkwitz K., 1996, “An in-situ ATR-FTIR-Study on Polyelectrolyte Multilayer Assemblies on Solid Surfaces and Their Susceptibiliy to Fouling”, Macromol. Rapid Commun., Vol. 19, No. 7, 333-336.
14. N. Sakudo, D. Mizutani, Y. Ohmura, 2003, “Surface Modification of PET Film by Plasma-Based Ion Implantation”, Nucl. Instrum. Methods Phys. Res., B Beam Interact. Mater. Atoms, Vol. 206, pp. 687.
15. Yuen C. W. M., Jiang S. Q., Kan C. W., 2007, “Effect of Low Temperature Plasma Treatment on the Electroless Nickel Plating of Polyester Fabric”, Journal of Applied Polymer Science, Vol. 105, 2046–2053.
16. Qi K., Xin J.H., Daoud W.A., 2007, “Functionalizing Polyester Fiber with a Self-Cleaning Property Using Anatase TiO2 and LowTemperature Plasma Treatment”, Int. J. Appl. Ceram. Technol., Vol. 4, No. 6, pp. 554–563.