Porselen Atık Takviyeli Epoksi Kompozitlerinin Tribolojik Özelliklerine Vakum Uygulamasının Etkisi

Bu çalışma, vakum uygulamasının atık porselen katkılı epoksi matrisli kompozit malzemelerin mekanik ve tribolojik özelliklerine etkisini değerlendirmektedir. Tribolojik karakterizasyon; tungsten karbür aşındırıcı bilye kullanılarak oda sıcaklığında yağlayıcı olmadan bilye-disk (ball-on-disk) konfigürasyonunda triboloji testleri gerçekleştirilerek sürtünme, aşınma oranları ve aşınma davranışları belirlenmiştir. Vakum uygulamasının; aşınma mekanizmaları, aşınma yüzeylerinde tribo-kimyasal tabaka oluşumu, sürtünme özellikleri ve tribolojik performans üzerindeki rolü araştırılmıştır. Mikroyapı, mekanik ve fiziksel özellikler ile aşınma davranışı ilişkisi ayrıntılı incelenmiştir. Vakum uygulaması partiküllerin daha iyi ıslatılmasına, matris ve partikül arasında daha kuvvetli bağ mukavemeti oluşmasına sebebiyet vermiştir. Vakum uygulamasıyla üretilmiş kompozitler, vakumsuz üretilmiş kompozitlere göre daha düşük sürtünme katsayısı ve daha düzgün tribokimyasal tabakanın oluşmasına sebebiyet vererek daha iyi aşınma dayanımı sergilemişlerdir.

INFLUENCE OF VACUUM APPLICATION ON THE TRIBOLOGICAL PROPERTIES OF PORCELAIN WASTE REINFORCED EPOXY COMPOSITES

This study evaluates the effect of employment of vacuum application on the mechanical and tribological properties of porcelain waste added epoxy matrix composites. Tribological characterization was determined by friction, wear rate and mechanisms using ball-on-disk test by tungsten carbide counter-part without lubrication at room temperature. It is investigated the role of vacuum application on the wear mechanisms, tribo-chemical layer formation on the wear surfaces, frictional property and tribological performance. The microstructure, mechanical and physical properties and wear behavior correlation were discussed comprehensively. Vacuum application provided fully embedded and well wetted particles, and strong bonding strength between matrix and filler. It is demonstrated that well bonded particle reinforced composites have higher wear resistance, by resulting lower friction coefficient, and more smoother tribochemical layer than compared with the unvacuumed composites.

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  • Acikbas, G., Ozcan, S., Calis Acikbas, N., 2017, “Production and Characterization of a Hybrid Polymer Matrix Composite”, Polymer Composites, DOI: 10.1002/pc.24471
  • Acikbas, G., Calis Acikbas, N., Ikizek, E., Ozel, M., Eker, A. S., 2014a, “Characterization of Green Epoxy Matrix Composites Filled with Ceramic Wastes”, Caglar, N., ISITES2014 2nd International
  • Symposium on Innovative Technologies in Engineering and Science, Karabük, Turkey, 597-606, 18-20 June, 2014, pp. Academic Platform, available at:
  • http://www.isites.info/pastconferences/isites2014/isites2014/papers/A16-ISITES2014ID96.pdf Acikbas, G., Calis Acikbas, N., Keskin, A., Ari, O. K., Ucer, D., 2014b, “ Effect of Graphite Filler Loading
  • Concentration on Physical and Mechanical Properties of Epoxy Matrix Composites”, SERES’14 ‘III. International Ceramic, Glass, Porcelain Enamel, Glaze and Pigment Congress, Eskisehir, Turkey, 15-17 October 2014.
  • Acikbas, G. and Göçmez, H., 2015, “Polyester Matrix Composites Containing Marble Waste”, International Porous And Powder Materials Symposium And Exhibition, İzmir, Turkey, 15-18 September 2015, available at: http://www.ppm2015.org/metin.aspx?ID=1420
  • Acikbas, G., Göçmez, H., 2016, “Effect of Glass Fiber Waste Content on Polyester Matrix Composites”, paper presented at the 1st International Black Sea Congress on Environmental Sciences, Giresun-Turkey, 31 August- 3 September, 2016, available at: http://muhendislik.giresun.edu.tr/fileadmin/user_upload/BOLUMLER/Cevre/IBCESS_Abstract _Book.pdf.
  • Acikbas, G., Göçmez, H., 2016, “Effect of Vitreous China Sanitaryware Waste Amount on Polyester Matrix Composite Properties”, 3.International Symposium on Environment and Morality, Alanya-Turkey, 4-6 November 2016, available at: http://isem.info/PastConferences/ISEM2016/ISEM2016/papers/1-ISEM2016ID342.pdf.
  • Alajmi, M., Shalwan, A., 2015, “Correlation between Mechanical Properties with Specific Wear Rate and the Coefficient of Friction of Graphite/Epoxy Composites”, Materials, Vol. 8, pp. 4162-4175; doi:10.3390/ma8074162.
  • Alok, S., Amar, P., 2008, “Analysis of Dry Sliding Wear Behaviour of Red Mud Filled Polyethylene Composites Using Taguchi Method”, Journal of Reinforced Plastics and Composites, Vol. 29, (24).
  • Baptista, R., Mendão, A., Rodrigues, F., Figueiredo-Pina, C.G., Guedes, M., Marat-Mendes R., 2016, “Effect of High Graphite Filler Contents on the Mechanical And Tribological Failure Behavior of Epoxy Matrix Composites”, Theoretical and Applied Fracture Mechanics, Vol. 85, pp. 113– 124.
  • Basavarajappa, S., Arun, K.V., Paulo Davim, J., 2009, “Effect of Filler Materials on Dry Sliding Wear Behavior of Polymer Matrix Composites – A Taguchi Approach”, Journal of Minerals & Materials Characterization & Engineering, Vol. 8, No.5, pp 379-391.
  • Bhushan, B., 2000, Modern Tribology Handbook, Two Volume Set, CRC Press, ISBN 9780849384035, December 28, Pages 1760 .
  • Bobby S., Abdul Samad, M., 2016, “Enhancement of Tribological Performance of Epoxy Bulk Composites and Composite Coatings Using Micro/Nano Fillers: A Review”, Polymers for Advanced Technologies, October 2016, DOI: 10.1002/pat.3961.
  • Calis Acikbas N., Acikbas, G., 2017, “Epoxy Matrix Composites Containing Urea Formaldehyde Waste Particulate Filler”, Waste and Biomass Valorization, Vol.8, pp. 669–678.
  • Chowdhury, M. A., Khalil, M. K., Nuruzzaman, D. M., Rahaman, M. L. 2011, “The Effect of Sliding Speed and Normal Load on Friction and Wear Property of Aluminum”, Int. J. Mech. Mechatron. Eng, Vol. 11 (01), pp. 53-57.
  • Cubeta, Richard A., 2013, “Utilizing Recycled Fiberglass for Affordable”, Green Composite Technology, COMPOSITES 2013, American Composite Manufacturers Association, January 29-31, 2013 Orlando, FL-USA.pp. 1-5.
  • E, S.F., Shi, L., Guo, Z.G., Liu, W.M., 2015, “The Recent Progress of Tribological Biomaterials”, Biosurface and Biotribology, Vol. 1,pp.81–97.
  • Esteves, M., Ramalho, A., Ferreira, M. A. J., Nobre, P. J. 2013, “Tribological and Mechanical Behaviour of Epoxy/Nanoclay Composites”, Tribology Letters, Vol. 52 (1), pp.1 –10.
  • Garcia, F.G., Leyva, M. E., Alencar de Queiroz, A. A., Higa, O. Z., 2009, “Epoxy Networks for Medicine Applications: Mechanical Properties and In Vitro biological Properties”, Journal of Applied Polymer Science, Vol. 112, pp.1215–1225.
  • Gill C.S and Sidhu, J.S., 2016, “Dry Sliding Wear Behavior of Epoxy Based Composites Filled With WS2 and B4C”, International Journal of Material Sciences and Technology, Vol 6, No. 1, pp. 21-32.
  • Gu, J., Zhang, Q., Dang, J., Xie, C., 2012, “Thermal Conductivity Epoxy Resin Composites Filled with Boron Nitride”, Polymers for Advanced Technologies, Vol. 23(6), pp. 1025–1028.
  • Harris, B., 1999, Engineering Composite Materials, The Institute of Materials, London
  • Katz H.S., Mileski, J.V., 1987, Handbook of Fillers For Plastics, Springer Science&Business Media, Technology & Engineering .
  • Khun, N. W., Zhang, H., Lim, L. H., Yang, J., 2015, “Mechanical and Tribological Properties of Graphene Modified Epoxy Composites”, International Journal of Applied Science and Technolog, Vol. 8(2), pp. 101–109.
  • Koleva, M., Zheglova, Fidancevska, A., Vassilev,, E. V., 2011, “Composites Containing Waste Materials”, INTECH Open Access Publisher.
  • Kumar, V., Sinha S. K. and Agarwal, A. K. , 2015, “Tribological Studies of Epoxy and Its Composite Coatings on Steel in Dry and Lubricated Sliding”, Tribology, Vol 9, No 3, pp.144-153.
  • Kumar, R., Calis Acikbas, N., Kara, F., Mandal, H., Basu, B., 2009, “Microstructure - Mechanical Properties - Wear Resistance Relationship of SiAlON Ceramics”, Metallurgical and Materials Transactions A, pp.2319-2332.
  • Kumar Mallik, A., Calis Acikbas N., Kara, F., Mandal, H., Basu, D., 2012, “A Comparative Study of SiAlON Ceramics”, Ceramics International, pp.5757–5767.
  • Kumar Mallik, A., Reddy, M., Calis Acikbas, N., Kara, F., Mandal, H., Basu, D., Basu, B., 2011, “Influence of SiC addition on tribological properties of SiAlON”, Ceramics International, pp.2495–2504.
  • Luo, Y., Yu, X. Y., Dong, X. M., Rong, M. Z., Zhang, M. Q. 2010, “Effect of nano-Si3N4 Surface Treatment on the Tribological Performance of Epoxy Composite”, Express Polymer Letters, Vol.4, No.3, pp. 131-140
  • McCook, N. L., Boesl, B., Burris, D. L., Sawyer, W. G. 2006, “Epoxy, ZnO, and PTFE Nanocomposite: Friction and Wear Optimization”, Tribology Letters, Vol. 22 (3), pp. 253–257.
  • Mohanty, A., Srivastava, K. V., 2012, “Effect of Alumina Nanoparticles on the Enhancement of Impact and Flexural Properties of the Short Glass/Carbon Fiber Reinforced Epoxy Based Composites”, Int. J. Sci. Eng. Res. Vol. 3(11), pp. 1–7.
  • Myshkin, N.K., Petrokovets, M.I., Kovalev, A.V. , 2005, “Tribology of Polymers: Adhesion, Friction, Wear, and Mass-Transfer”, Tribology International, Vol. 38, pp. 910–921.
  • Qi, H., Zhang, G., Wetzel, B., Österle, W., Wang, T., Wang, Q., 2016, “Exploring the Influence of Counterpart Materials on Tribological Behaviors of Epoxy Composites”, Tribology International, Vol.,103, pp. 566–573.
  • Pan, G., Guo, Q., Ding, J., Zhang, W., Wang, X., 2010, “Tribological Behaviors of Graphite/Epoxy Two-Phase Composite Coatings”, Tribology International, Vol.43, pp.1318–1325.
  • Pervaiz, M.R., Mohanthy, S., Nayak, S.K., Mahanwar, P.A. , 2010 , “Composites Reinforced with Fly Ash and Mica”, Journal of Minerals & Materials Characterization & Engineering, Vol. 9, pp. 25-41.
  • Raju, B. R., Suresha, B., Swamy, R. P., Kanthraju, B. S. G. , 2013, “Investigations on Mechanical and Tribological Behaviour of Particulate Filled Glass Fabric Reinforced Epoxy Composites”, Journal of Minerals and Materials Characterization and Engineering, Vol.1, pp.160-167.
  • Sagsoz, O., Ilday, N. O., Sagsoz, N. P., Bayindir, Y. Z., Alsaran, A., 2014, “Investigation of Hardness and Wear Behavior of Dental Composite Resins”, International Journal of Composite Materials, Vol.4(4), pp. 179-184.
  • Srinivas, K., Bhagyashekar, M.S., 2014, “Wear Behaviour of Epoxy Hybrid Particulate Composites”, Procedia Engineering, Vol. 97, pp. 488 – 494.
  • Shi G., Zhang M.Q., Rong M.Z., Wetzel B., Friedrich K., 2004, “Sliding Wear Behavior of Epoxy Containing nano-Al2O3 Particles with Different Pretreatments”, Wear, Vol. 256, pp. 1072–1081.
  • Suresha B., Chandramohan G., Prakash J.N., Balusamy V., Sankaranarayanasamy K., 2006, “The Role of Fillers on Friction and Slide Wear Characteristics in Glass-Epoxy Composite Systems”, Journal of Minerals and Materials Characterization and Engineering, Vol. 5, pp. 87-101.
  • Tai, Y.-Y., Hsu, S.-H., Chen, R.-S., Su, W.-F., Chen, M.-H. , 2015, “Liquid Crystalline Epoxy Nanocomposite Material for Dental Application”, Journal of the Formosan Medical Association, Vol.114, pp.46-51.
  • Vasconcelos P.V., Lino F.J., Baptista A.M., Neto R.J.L., 2006, “Tribological Behavior of Epoxy Based Composites for Rapid Tooling”, Wear, Vol. 260, pp. 30–39.
  • Yaman, B., Mandal, H. , 2014, “ Wear Performance of Spark Plasma Sintered Co/WC and cBN/Co/WC Composites”, International Journal of Refractory Metals and Hard Materials, Vol.42, pp. 9–16.
  • Seramik Kalkınma Raporu, available at: http://www.kalkinma.gov.tr/Lists/zel%20htisas%20Komisyonu%20Raporlar/Attachments/266/ Seramik%20%C3%87al%C4%B1%C5%9Fma%20Grubu%20Raporu.pdf
  • Zhang, Z., Breidt, C., Chang, L., Haupert, F., Friedrich, K., 2004, “Enhancement of the Wear Resistance of Epoxy: Short Carbon Fibre, Graphite, PTFE and nano-TiO2”, Composites Part A: Applied Science and Manufacturing, Vol. 35, pp. 1385–1392.
  • Zhou, Y. X., Wu, P. X., Cheng, Z. Y., Ingram, J. , Jeelani, S. 2008, “Improvement in Electrical, Thermal and Mechanical Properties of Epoxy by Filling Carbon Nanotube”, Express Polymer Letters, Vol. 2(1), pp. 40–48.